Jianxin Yin

Particulate matter in the atmosphere: which particle properties are important for its effects on health?

Whilst epidemiological studies have consistently demonstrated adverse effects of particulate matter exposure on human health, the mechanism of effect is currently unclear. One of the major issues is whether the toxicity of the particles resides in some particular fraction of the particles as defined by chemical composition or size. This article reviews selected data on the major and minor component composition of PM2.5 and PM10 particulate matter showing quite major geographic variations in composition which are not reflected in the exposure-response coefficients determined from the epidemiology which show remarkably little spatial variation. The issue of particle size is more difficult to address due to the scarcity of data. Overall, the data presented provides little support for the idea that any single major or trace component of the particulate matter is responsible for the adverse effects. The issue of particle size is currently unclear and more research is warranted.

Estimation of the Contributions of Brake Dust, Tire Wear, and Resuspension to Nonexhaust Traffic Particles Derived from Atmospheric Measurements

Size-fractionated samples of airborne particulate matter have been collected in a number of campaigns at Marylebone Road, London and simultaneously at background sites either in Regents Park or at North Kensington. Analysis of these samples has enabled size distributions of total mass and of a number of elements to be determined, and roadside increments attributable to nonexhaust emissions arising from traffic activity have been calculated. Taking a novel approach, the combined use of size distribution information and tracer elements has allowed the separate estimation of the contributions of brake dust, tire dust, and resuspension to particle mass in the range 0.9-11.5 μm aerodynamic diameter and mean contributions (± s.e.) at the Marylebone Road sampling site are estimated as resuspended dust 38.1 ± 9.7%, brake dust 55.3 ± 7.0%, and tire dust 10.7 ± 2.3%, (accounting for a total of 104.1% of coarse particle mass in the traffic increment above background).

Measurement of number, mass and size distribution of particles in the atmosphere

Typical size distributions for airborne particles are described and the significance of the ultrafine fraction highlighted. Size distributions may be expressed in terms of either mass (volume), surface area or number, and the interpretation of each is discussed together with appropriate measurement methods. The sources of ultrafine particles in the atmosphere include both primary emissions and secondary particles formed through homogeneous nucleation processes within the atmosphere. Examples of measurements of atmospheric ultrafine particles are given, highlighting situations with high concentrations of primary ultrafine particles and also situations where gas–to–particle conversion through homogeneous nucleation gives rise to bursts of new particle production. Finally, the relationship between particle mass and number within the atmosphere at a polluted site is examined.

Receptor modelling study of polycyclic aromatic hydrocarbons in Jeddah, Saudi Arabia

Measurements of 14 polycyclic aromatic hydrocarbons (PAH) have been made in Jeddah, Saudi Arabia, with a view to establishing the concentrations in this major city, and quantifying the contributions of major sources. Particulate and vapour forms have been sampled and analysed separately. The concentrations are compared to measurements from other sites in the Middle Eastern region and are towards the lower end of the range, being far lower than concentrations reported from Riyadh (Saudi Arabia), Assiut (Egypt) and Tehran (Iran) but broadly similar to those measured in Damascus (Syria) and higher than those measured in Kuwait. The partitioning between vapour and particle phases is similar to that in data from Egypt and China, but with many compounds showing a higher particle-associated percentage than in Birmingham (UK) possibly reflecting a higher concentration of airborne particulate matter in the former countries. Concentrations in Jeddah were significantly higher at a site close to the oil refinery and a site close to a major ring road than at a suburban site to the north of the city. Application of positive matrix factorisation to the pooled data elicited three factors accounting respectively for 17%, 33% and 50% of the measured sum of PAH and these are interpreted as arising from gasoline vehicles, industrial sources, particularly the oil refinery, and to diesel/fuel oil combustion.

Local and regional air pollution in Ireland during an intensive aerosol measurement campaign.

An intensive two month measurement campaign has been performed during a two year study of major component composition of urban PM10 and PM2.5 in Ireland (J. Yin, A. G. Allen, R. M. Harrison, S. G. Jennings, E. Wright, M. Fitzpatrick, T. Healy, E. Barry, D. Ceburnis and D. McCusker, Atmos. Res., 2005, 78(3-4), 149-165). Measurements included size-segregated mass, soluble ions, elemental carbon (EC) distributions, fine and coarse fraction organic carbon (OC) and major gases along with standard meteorological measurements. The study revealed that urban emissions in Ireland had mainly a local character and therefore were confined within a limited area of 20-30 km radius, without significantly affecting regional air quality. Gaseous measurements have shown that urban emissions in Ireland had clear, but fairly limited influence on the regional air quality due to favorable mixing conditions at higher wind speeds, in particular from the western sector. Size-segregated mass and chemical measurements revealed a clear demarcation size between accumulation and coarse modes at about 0.8 microm which was constant at all sites. Carbonaceous compounds at the urban site accounted for up to 90% of the particle mass in a size range of 0.066-0.61 microm. Nss SO4(2-) concentrations in PM2.5 were only slightly higher at the urban site compared to the rural or coastal sites, while NO3- and NH4+ concentrations were similar at the urban and coastal sites, but were a factor of 2 to 3 higher than at the rural site. OC was highly variable between the sites and revealed clear seasonal differences. Natural or biogenic OC component accounted for <10% in winter and up to 30% in summer of the PM2.5 OC at urban sites. A contribution of biogenic OC component to PM2.5 OC mass at rural site was dominant.