Jieyang Jia

Solar water splitting by photovoltaic-electrolysis with a solar-to-hydrogen efficiency over 30.

Hydrogen production via electrochemical water splitting is a promising approach for storing solar energy. For this technology to be economically competitive, it is critical to develop water splitting systems with high solar-to-hydrogen (STH) efficiencies. Here we report a photovoltaic-electrolysis system with the highest STH efficiency for any water splitting technology to date, to the best of our knowledge. Our system consists of two polymer electrolyte membrane electrolysers in series with one InGaP/GaAs/GaInNAsSb triple-junction solar cell, which produces a large-enough voltage to drive both electrolysers with no additional energy input. The solar concentration is adjusted such that the maximum power point of the photovoltaic is well matched to the operating capacity of the electrolysers to optimize the system efficiency. The system achieves a 48-h average STH efficiency of 30%. These results demonstrate the potential of photovoltaic-electrolysis systems for cost-effective solar energy storage.

Bias-dependence of luminescent coupling efficiency in multijunction solar cells

In this work we describe the dependence of luminescent coupling efficiency on the bias-voltage in multijunction solar cells. We combine a theoretical derivation and Sentaurus simulations to show that the luminescent coupling efficiency has a significant dependence on the bias voltage, and such dependence is mainly due to the change in the ratio between radiative and non-radiative recombination currents at different bias voltage. We further show that such change is due to the variation in the recombination rate distribution in the cell. In addition to showing the necessity of including bias-dependence in luminescent coupling modeling, this work also demonstrates the importance of including a bias-dependent luminescent coupling efficiency to accurately model multijunction solar cells.

GaAs thin film nanostructure arrays for III-V solar cell applications

State of art III-V multi-junction solar cells have demonstrated a record high efficiency of 43.5%. However, these cells are only applicable to high concentration systems due to their high cost of substrates and epitaxial growth. We demonstrate thin film flexible nanostructure arrays for III-V solar cell applications. Such nanostructure arrays allow substrate recycling and much thinner epitaxial layer thus could significantly reduce the cost of traditional III-V solar cells. We fabricate the GaAs thin film nanostructure arrays by conformally growing GaAs thin film on nanostructured template followed by epitaxial lift-off. We demonstrate broadband optical absorption enhancement of a film of GaAs nanostructure arrays over a planar thin film with equal thickness. The absorption enhancement is about 300% at long wavelengths due to significant light trapping effect and about 30% at short wavelengths due to antireflection effect from tapered geometry. Optical simulation shows the physical mechanisms of the absorption enhancement. Using thin film nanostructure arrays, the III-V solar system cost could be greatly reduced, leading to low

3-D modeling of luminescent coupling effects in multijunction concentrator solar cells

/W and high kW/kg flexible solar systems.

Ultra-thin film nanostructured gallium arsenide solar cells

In this work, we demonstrate an improved 3-D distributed circuit model to analyze the luminescent coupling effects in multijunction concentrator solar cells. We implemented the 3-D distributed circuit model and compared the simulation results with experimental data measured on GaAs/GaInNAsSb solar cells. The results from simulations implementing this 3-D model match well with the experimental data under different illumination conditions. In addition, with the 3-D model simulation results we visualized the space-variant luminescent coupling current under different spectral profiles. We demonstrate the effects of luminescent coupling on I-V characteristics and current density distributions in the cells. Our 3-D model will enable more precise modeling and more detailed performance analysis of concentrator solar cells.

Titanium oxide contact passivation layer for thin film crystalline silicon solar cells

State-of-the-art III-V cells have reached the highest energy conversion efficiency among all types of solar cells. However, these cells are not applicable to widespread terrestrial solar energy system yet due to the high cost of epitaxial growth. Ultra-thin film absorbers with advanced light management is one of the most promising solutions to drive down the cost. In this paper, we present an ultra-thin film nano-window gallium arsenide (GaAs) solar cell design. This ultrathin cell consists of a nano-structured Al0.8Ga0.2As window layer on the front side to reduce the reflection and to trap the light, and a metal reflector on the back side to further increase the light path. The 300 nm thick GaAs cell with Al0.8Ga0.2As nano-window shows a broad band absorption enhancement from visible to near infrared (NIR), achieving a spectrally averaged absorption of 94% under normal incidence. In addition, this cell shows excellent angular absorption properties, achieving over 85% spectral averaged absorption at up to 60 degree off normal incidence. Meanwhile, this structure with planar junction and nano-window has solved the issue of low fill factor and low open-circuit voltage in nano-structured GaAs solar cell. A nano-window cell with a 3 μm thick GaAs junction demonstrated an open circuit voltage of 0.9V.

A novel measurement method of luminescence coupling in multijunction solar cells based on small signal method

Thin film crystalline silicon (c-Si) solar cells have been a hot topic of photovoltaic research recently because its lower material consumption could potentially lead to lower capital expenditure. However, contact recombination is more prominent in thin-film c-Si solar cells compared with it in traditional c-Si solar cells due to higher carrier concentration. To address such a challenge, this work presents a design of metal-insulator-semiconductor (MIS) contact, based on thin TiOx layer that is grown by atomic layer deposition (ALD). Transmission line measurement (TLM) was conducted to study the conducting behavior of the TiOx MIS contact structure. Experimental results demonstrate that with the same doping density in silicon, the TiOx MIS contact forms an Ohmic contact to n-type silicon with good conductivity while cannot form Ohmic contact with p-silicon. This result demonstrates that the ALD TiOx layer can conduct electrons while blocking holes, thereby potentially reduce the contact recombination for thin-film c-Si solar cells, leading to an improvement of cell efficiency.

Titanium oxide electron-selective layers for contact passivation of thin-film crystalline silicon solar cells

Luminescent coupling effects are considered crucial for the performance of multijunction solar cells. We report a novel approach based on small signal measurement, which can directly measure the luminescent coupling efficiency of a multijunction solar cell with different voltage bias. In addition, this method demonstrated the light and voltage dependence of the coupling efficiency, and can potentially lead to a deeper understanding of luminescent coupling effects as well as more effective design of multijunction solar cells.

A new electro-absorption modulator structure based on Ge/SiGe coupled quantum wells for on-chip optical interconnects

In crystalline silicon (c-Si) solar cells, carrier selective contacts are among the remaining issues to be addressed in order to reach the theoretical efficiency limit. Especially in ultra-thin-film c-Si solar cells with small volumes and higher carrier concentrations, contact recombination is more critical to the overall performance. In this paper, the advantages of using TiOX as electron-selective layers for contact passivation in c-Si solar cells are analyzed. We characterize the metal/TiOX/n-Si electron-selective contact with the contact recombination factor J0c and the contact resistivity ρc for the first time. Experimental results show that both J0c and ρc decrease after the insertion of TiOX. In addition, the effect of post-deposition rapid-thermal-annealing (RTA) at different temperatures is also evaluated. The best J0c of 5.5 pA/cm2 and the lowest ρc of 13.6 mΩ·cm2 are achieved after the RTA process. This work reveals the potential of TiOX as an electron-selective layer for contact passivation to enable high-efficiency ultra-thin c-Si solar cells with a low cost.

Comprehensive modeling on luminescent coupling dependency in multi-junction solar cells

In this paper, a novel electro-absorption modulation mechanism based on coupled-quantum-wells (CQWs) is proposed and demonstrated. Compared to a quantum-confined-stark-effect (QCSE) modulator with multiple fully decoupled single-QWs, the newly designed CQW modulator has two sub-quantum-wells partially coupled with a small barrier in between. Modulation is based on the change of electron and hole wave-function overlap in the CQWs, which requires a small bias electric field of <10 kV/cm) compared to the operation of a typical QCSE modulator which requires >50 kV/cm bias electrical field. Theoretically, the power consumption of this new CQW modulator can be lower than 20 fJ/bit and the speed can be higher than 10 Gbps, which outperforms the best Ge/SiGe QCSE modulator that has been previously demonstrated. A proof-of-concept Ge/SiGe CQW modulator based on this novel modulation mechanism was designed and fabricated. Instead of a traditional PIN diode structure, the new CQW modulator uses a PIP structure.