Yusi Chen

Solar water splitting by photovoltaic-electrolysis with a solar-to-hydrogen efficiency over 30.

Hydrogen production via electrochemical water splitting is a promising approach for storing solar energy. For this technology to be economically competitive, it is critical to develop water splitting systems with high solar-to-hydrogen (STH) efficiencies. Here we report a photovoltaic-electrolysis system with the highest STH efficiency for any water splitting technology to date, to the best of our knowledge. Our system consists of two polymer electrolyte membrane electrolysers in series with one InGaP/GaAs/GaInNAsSb triple-junction solar cell, which produces a large-enough voltage to drive both electrolysers with no additional energy input. The solar concentration is adjusted such that the maximum power point of the photovoltaic is well matched to the operating capacity of the electrolysers to optimize the system efficiency. The system achieves a 48-h average STH efficiency of 30%. These results demonstrate the potential of photovoltaic-electrolysis systems for cost-effective solar energy storage.

High-efficiency nanostructured window GaAs solar cells.

Nanostructures have been widely used in solar cells due to their extraordinary optical properties. In most nanostructured cells, high short circuit current has been obtained due to enhanced light absorption. However, most of them suffer from lowered open circuit voltage and fill factor. One of the main challenges is formation of good junction and electrical contact. In particular, nanostructures in GaAs only have shown unsatisfactory performances (below 5% in energy conversion efficiency) which cannot match their ideal material properties and the record photovoltaic performances in industry. Here we demonstrate a completely new design for nanostructured solar cells that combines nanostructured window layer, metal mesa bar contact with small area, high quality planar junction. In this way, we not only keep the advanced optical properties of nanostructures such as broadband and wide angle antireflection, but also minimize its negative impact on electrical properties. High light absorption, efficient carrier collection, leakage elimination, and good lateral conductance can be simultaneously obtained. A nanostructured window cell using GaAs junction and AlGaAs nanocone window demonstrates 17% energy conversion efficiency and 0.982 V high open circuit voltage.

Two-step growth of high quality Bi2Te3 thin films on Al2O3 (0001) by molecular beam epitaxy

Large-area topological insulator Bi2Te3 thin films were grown on Al2O3 (0001) using a two-temperature step molecular beam epitaxy growth process. By depositing a low temperature nucleation layer to serve as a template for high temperature epitaxial film growth, a high quality terrace-step surface morphology with a significant reduction in three-dimensional defect structures was achieved. X-ray diffraction measurements indicate that high crystalline quality Bi2Te3 layers were grown incoherently by van der Waals epitaxy using this technique. Angle resolved photoemission spectroscopy measurements verified the integrity of this growth method by confirming the presence of metallic surface states on cleaved two-step Bi2Te3 samples.

Magnetic properties of gadolinium substituted Bi2Te3 thin films

Thin film GdBiTe3 has been proposed as a candidate material in which to observe the quantum anomalous Hall effect. As a thermal non-equilibrium deposition method, molecular beam epitaxy (MBE) has the ability to incorporate large amounts of Gd into Bi2Te3 crystal structures. High-quality rhombohedral (GdxBi1−x)2Te3 films with substitutional Gd concentrations of x ≤ 0.4 were grown by MBE. Angle-resolved photoemission spectroscopy shows that the topological surface state remains intact up to the highest Gd concentration. Magnetoresistance measurements show weak antilocalization, indicating strong spin orbit interaction. Magnetometry reveals that the films are paramagnetic with a magnetic moment of 6.93 μB per Gd3+ ion.

On-chip plasmonic waveguide optical waveplate.

Polarization manipulation is essential in almost every photonic system ranging from telecommunications to bio-sensing to quantum information. This is traditionally achieved using bulk waveplates. With the developing trend of photonic systems towards integration and miniaturization, the need for an on-chip waveguide type waveplate becomes extremely urgent. However, this is very challenging using conventional dielectric waveguides, which usually require complex 3D geometries to alter the waveguide symmetry and are also difficult to create an arbitrary optical axis. Recently, a waveguide waveplate was realized using femtosecond laser writing, but the device length is in millimeter range. Here, for the first time we propose and experimentally demonstrate an ultracompact, on-chip waveplate using an asymmetric hybrid plasmonic waveguide to create an arbitrary optical axis. The device is only in several microns length and produced in a flexible integratable IC compatible format, thus opening up the potential for integration into a broad range of systems.

Bias-dependence of luminescent coupling efficiency in multijunction solar cells

In this work we describe the dependence of luminescent coupling efficiency on the bias-voltage in multijunction solar cells. We combine a theoretical derivation and Sentaurus simulations to show that the luminescent coupling efficiency has a significant dependence on the bias voltage, and such dependence is mainly due to the change in the ratio between radiative and non-radiative recombination currents at different bias voltage. We further show that such change is due to the variation in the recombination rate distribution in the cell. In addition to showing the necessity of including bias-dependence in luminescent coupling modeling, this work also demonstrates the importance of including a bias-dependent luminescent coupling efficiency to accurately model multijunction solar cells.

Design and fabrication of nano-pyramid GaAs solar cell

We demonstrate a genetic method to fabricate large-area nano-structure III-V solar cells with conformal epitaxial growth on pre-patterned substrate. The design, simulation, fabrication, and characterization of a nano-structure gallium arsenide (GaAs) solar cell device are presented. The optical simulation illustrates that the nano-pyramid array is able to suppress the reflection and enhance the absorption in a wide spectrum range. The IV characterization shows that the short circuit current of the nano-pyramid GaAs solar cell with 200 nm thick junction is as high as 18.5 mA/cm2, which is more than triple of the planar cell. Our results suggest this nano-structure thin film absorber could significantly reduce epitaxial growth cost and increase yield, thus provides a pathway towards high-efficiency and low-cost solar cells.

Ultra-thin film nanostructured gallium arsenide solar cells

State-of-the-art III-V cells have reached the highest energy conversion efficiency among all types of solar cells. However, these cells are not applicable to widespread terrestrial solar energy system yet due to the high cost of epitaxial growth. Ultra-thin film absorbers with advanced light management is one of the most promising solutions to drive down the cost. In this paper, we present an ultra-thin film nano-window gallium arsenide (GaAs) solar cell design. This ultrathin cell consists of a nano-structured Al0.8Ga0.2As window layer on the front side to reduce the reflection and to trap the light, and a metal reflector on the back side to further increase the light path. The 300 nm thick GaAs cell with Al0.8Ga0.2As nano-window shows a broad band absorption enhancement from visible to near infrared (NIR), achieving a spectrally averaged absorption of 94% under normal incidence. In addition, this cell shows excellent angular absorption properties, achieving over 85% spectral averaged absorption at up to 60 degree off normal incidence. Meanwhile, this structure with planar junction and nano-window has solved the issue of low fill factor and low open-circuit voltage in nano-structured GaAs solar cell. A nano-window cell with a 3 μm thick GaAs junction demonstrated an open circuit voltage of 0.9V.

Tensile-strained Ge/SiGe multiple quantum well microdisks

An efficient monolithically integrated laser on Si remains the missing component to enable Si photonics. We discuss the design and fabrication of suspended and tensile-strained Ge/SiGe multiple quantum well microdisk resonators on Si for laser applications in Si photonics using an all-around SiNx stressor. An etch-stop technique in the Ge/SiGe system is demonstrated and allows the capability of removing the defective buffer layer as well as providing precise thickness control of the resonators. Photoluminescence and Raman spectroscopy indicate that we have achieved a biaxial tensile strain shift as high as 0.88% in the microdisk resonators by adding a high-stress SiNx layer. Optical gain calculations show that high positive net gain can be achieved in Ge quantum wells with 1% external biaxial tensile strain.

Titanium oxide contact passivation layer for thin film crystalline silicon solar cells

Thin film crystalline silicon (c-Si) solar cells have been a hot topic of photovoltaic research recently because its lower material consumption could potentially lead to lower capital expenditure. However, contact recombination is more prominent in thin-film c-Si solar cells compared with it in traditional c-Si solar cells due to higher carrier concentration. To address such a challenge, this work presents a design of metal-insulator-semiconductor (MIS) contact, based on thin TiOx layer that is grown by atomic layer deposition (ALD). Transmission line measurement (TLM) was conducted to study the conducting behavior of the TiOx MIS contact structure. Experimental results demonstrate that with the same doping density in silicon, the TiOx MIS contact forms an Ohmic contact to n-type silicon with good conductivity while cannot form Ohmic contact with p-silicon. This result demonstrates that the ALD TiOx layer can conduct electrons while blocking holes, thereby potentially reduce the contact recombination for thin-film c-Si solar cells, leading to an improvement of cell efficiency.