Jingzhi Han

Anisotropic nanocrystalline MnBi with high coercivity at high temperature

Magnetic hard nanocrystalline MnBi has been prepared by melt spinning and subsequent low temperature annealing. A coercivity of 2.5 T can be achieved at 540 K for MnBi with an average grain size of about 20-30 nm. The coercivity iHc, mainly controlled by the coherent magnetization rotation, shows a strong dependence on the time of grinding and exhibits a positive temperature coefficient from 100 up to 540 K. The unique temperature dependent behavior of the coercivity (magnetocrystalline anisotropy) has a relationship with the variations in the crystal lattice ratio of c/a with temperatures. In addition, discontinuity can not be found in the lattice parameters of a, c, and c/a ratio at the magnetostructural transition temperature. The nanocrystalline MnBi powder fixed in an epoxy resin and under an applied magnetic field of 24 kOe shows a maximum energy product of 7.1 MGOe at room temperature and shows anisotropic characteristics with high Mr/Ms ratio up to 560 K.

Improvement of coercivity and thermal stability of anisotropic Nd13Fe79.4B7Nb0.3Ga0.3 powders by diffusion of Pr-Cu alloys

Highly anisotropic Nd13Fe79.4B7Nb0.3Ga0.3 powders from a self-organized rod-like disproportionation microstructure and room temperature magnetic properties of μ0Mr = 1.4 T, iHc = 13 kOe, and (BH)max = 41 MGOe are obtained by optimizing hydrogenation disproportionation desorption recombination (HDDR) process. Diffusion of Pr68Cu32 alloy into the HDDR powders further increases the coercivity of the powders to 18 kOe. This enhancement in coercivity is mainly attributed to the modification of grain boundaries including the decrease of Fe content and the increase of boundary thickness. The modified boundaries can work as effective pinning layers for domain walls. The thermal stability of magnetic properties of HDDR powders is also improved after the diffusion treatment.

Coercivity enhancement in Dy-free Nd–Fe–B sintered magnets by using Pr-Cu alloy

The grain boundary phase of Dy-free sintered Nd-Fe-B magnets is modified by using Pr68Cu32 eutectic alloy. The coercivity of the modified magnets reaches 21 kOe, which is the highest value in Dy-free Nd-Fe-B sintered magnets. Microstructural investigations show that a smooth and thick grain boundary layer is formed, and the content of the ferromagnetic elements in the grain boundary layer decreases from 65 at. % to 9 at. %. In addition, the mean grain size (4.5 μm) in the doped sintered magnets is smaller than that (6.5 μm) in the original sintered magnets. The modification in grain boundary and grain size reduces the magnetic interactions among grains and hinders nucleation of reversed magnetic domains, resulting in a coercivity enhancement.

τ-MnAl with high coercivity and saturation magnetization

In this paper, high purity τ-Mn54Al46 and Mn54−xAl46Cxalloys were successfully prepared using conventional arc-melting, melt-spinning, and heat treatment process. The magnetic and the structural properties were examined using x-ray diffraction (XRD), powder neutron diffraction and magnetic measurements. A room temperature saturation magnetization of 650.5 kAm-1, coercivity of 0.5 T, and a maximum energy product of (BH)max = 24.7 kJm-3 were achieved for the pure Mn54Al46 powders without carbon doping. The carbon substituted Mn54−xAl46Cx, however, reveals a lower Curie temperature but similar saturation magnetization as compared to the carbon-free sample. The electronic structure of MnAl shows that the Mn atom possesses a magnetic moment of 2.454 μB which results from strong hybridization between Mn-Al and Mn-Mn. We also investigated the volume and c/a ratio dependence of the magnetic moments of Mn and Al. The results indicate that an increase in the intra-atomic exchange splitting due to the cell volume ex...

Anisotropic ternary Pr13Fe80B7 powders prepared by hydrogenation disproportionation desorption recombination process

High-purity ternary Pr13Fe80B7 magnetic powder with high anisotropy is obtained by a modified hydrogenation disproportionation desorption recombination (HDDR) process in this work. This powder exhibits a record-high Br of 1.05T, and has a good crystal texture along the c axis. It is found that the formation of HDDR Pr13Fe80B7 anisotropy is related to a rodlike disproportionation microstructure. We also show that by changing the HDDR conditions, an intrinsic coercivity of 800kA∕m and an energy product of 144kJ∕m3 are obtained on this powder. The details of the modified HDDR process are also presented in this paper.

Neutron powder diffraction study on the structures of LaNi5−xAlxDy compounds

Abstract The structures of LaNi5−xAlxDy ( x=0.75, 0.25, y=1.01, 1.10, 1.91 and 3.1) were systematically investigated by neutron and X-ray diffraction. D atoms are found to enter the 6m site of the α-phase but not the reported 12n site, while the 6m and 12n sites of the β-phase. In the case of LaNi4.75Al0.25Dy with lower Al content and symmetry, D atoms do not enter the α-phase but occupy the 4h site besides the 6m and 12n sites of the β-phase. The relationship between structures and properties is also discussed.

Coercivity enhancement in Pr9.5Fe83Zr2B5.5 magnetic nanomaterials

The coercivity of Pr2Fe14B/α-Fe magnetic nanomaterial has been drastically improved from 6.8 kOe to 26 kOe by the diffusion of the Pr68Cu32 alloy. Pr68Cu32 alloy reacts with α-Fe to form boundary phases among Pr2Fe14B grains. The boundary phases have weak magnetic properties and have a thickness comparable to the domain wall thickness of Pr2Fe14B phase. So boundary layers are very effective in pinning the motion of domain walls, leading to an increased coercivity. The coercivity of this material at 160 °C is improved from 2.7 kOe to 10 kOe by diffusion treatment.

Valley Pseudospin with a Widely Tunable Bandgap in Doped Honeycomb BN Monolayer

Valleytronics is a promising paradigm to explore the emergent degree of freedom for charge carriers on the energy band edges. Using ab initio calculations, we reveal that the honeycomb boron nitride (h-BN) monolayer shows a pair of inequivalent valleys in the vicinities of the vertices of hexagonal Brillouin zone even without the protection of the C3 symmetry. The inequivalent valleys give rise to a 2-fold degree of freedom named the valley pseudospin. The valley pseudospin with a tunable bandgap from deep ultraviolet to far-infrared spectra can be obtained by doping h-BN monolayer with carbon atoms. For a low-concentration carbon periodically doped h-BN monolayer, the subbands with constant valley Hall conductance are predicted due to the interaction between the artificial superlattice and valleys. In addition, the valley pseudospin can be manipulated by visible light for high-concentration carbon doped h-BN monolayer. In agreement with our calculations, the circularly polarized photoluminescence spectra of the B0.92NC2.44 sample show a maximum valley-contrasting circular polarization of 40% and 70% at room temperature and 77 K, respectively. Our work demonstrates a class of valleytronic materials with a controllable bandgap.

Magnetic frustration and magnetocaloric effect in AlFe2-xMnxB2 (x = 0-0.5) ribbons

The crystal structure and magnetic properties of AlFe2−x Mn x B2 (x = 0–0.5) compounds were investigated. With increasing Mn content, the magnetic properties of these compounds evolve gradually and the lattice parameters change continuously: Curie temperature (T c) decreases from 312 K (x = 0) to 220 K (x = 0.5) and a new phase transition from the ferromagnetic state (FM) to spin-glass state (SPG) appears upon cooling. The lattice shrinks in the ab plane while it expands in the c direction. The formation of re-entrant SPG around 50 K was studied via temperature dependent ac and dc magnetization as well as the initial magnetization curves in 5 K. The reason for this glass state is the triangular configuration of magnetic atoms and the antiferromagnetic interactions introduced by Mn substitutions. The Curie transition leads to a conventional magnetocaloric effect (MCE). The Mn doping leads to a decrease in the MCE near room temperature, but there is a plane in entropy change (ΔS) for the x = 0.1 compound under low field which makes these compounds good candidates to produce composites used for magnetic refrigeration application in a wide temperature span.

Magnetic and transport properties of cobalt doped La0.7Sr0.3MnO3

The magnetic and transport properties of La0.7Sr0.3Mn1−xCoxO3 (0 ≤ x ≤ 1) samples were systematically studied. A magnetic phase diagram was constructed according to the observed results. At the two ends (x ≤ 0.3 and x > 0.9), the samples exhibit the conventional ferromagnetism with the metallic conducting behavior, which can be interpreted in terms of the double exchange coupling between Mn (Co) ions. As for the intermediate Co-doping region (0.3 < x ≤ 0.9), the samples enter a mixed magnetic phase state, which displays the characteristics of the glassy states. According to the frequency-dependent results from the ac susceptibility, a representative frequency sensitivity factor K was calculated to be ∼0.1 for the typical La0.7Sr0.3Mn0.6Co0.4O3 sample, corresponding to the coexistence of superparamagnetic-like free spins and the reentrant spin glass. The results of the Curie-Weiss fitting of the dc magnetization suggest that the Co3+ ions are in the intermediate spin state with the increase of Co-doping le...