John H. Lehman

Gold-black coatings for freestanding pyroelectric detectors*

We describe the process of depositing gold-black on thin, freestanding pyroelectric detector substrates and compare this with previous work documented in the literature. We have evaluated gold-black coatings on thin, freestanding pyroelectric detector substrates by means of scanning electron microscope, Fourier transform infrared spectrophotometer reflectance, and spectral responsivity measurements. Spectrophotometric measurements indicate that reflectance at normal incidence varies by less than 1% at wavelengths shorter than 2.5 µm and by less than 10% at 10 µm. These results are correlated with the spectral responsivity of the detector and demonstrate that radiation not reflected by the gold-black is absorbed by the detector element. We have evaluated gold-black coatings as a function of position at two wavelengths and found variations of less than 1% at 1.25 µm and less than 5% at 10.3 µm, which demonstrates that spatial uniformity can be coating dependent. Gold-black coatings exposed to a 193 nm wavelength excimer laser were evaluated by visual inspection for damage and determined to have a damage threshold of approximately 38 mJ cm−2.

Single-wall carbon nanotube coating on a pyroelectric detector

Carbon single-wall nanotubes (SWNTs) are studied as the thermal-absorption coating on a large area pyroelectric detector. The SWNTs were produced by a laser vaporization method and dispersed onto the detector surface by use of a simple airbrush technique. The detector was based on a 1-cm-diameter, 60-microm-thick lithium tantalate disk having nickel electrodes. We report the spectral responsivity of the detector ranging from 600 to 1800 nm, as well as the spatial and directional uniformity at 850 nm. Using Drude and Lorentzian dielectric functions and an effective medium approximation to obtain the indices of refraction of semiconductor and metallic SWNTs, we compared the expected theoretical relative responsivity for the two types of tube with the measured relative responsivity of the detector. Values of thermal conductivity, specific heat, and damage threshold obtained from the literature are compared with properties of alternatives for thermal coatings such as gold-black and carbon-based paint.

Very high laser-damage threshold of polymer-derived Si(B)CN-carbon nanotube composite coatings.

We study the laser irradiance behavior and resulting structural evolution of polymer-derived silicon-boron-carbonitride (Si(B)CN) functionalized multiwall carbon nanotube (MWCNT) composite spray coatings on copper substrate. We report a damage threshold value of 15 kWcm(-2) and an optical absorbance of 0.97 after irradiation. This is an order of magnitude improvement over MWCNT (1.4 kWcm(-2), 0.76), SWCNT (0.8 kWcm(-2), 0.65) and carbon paint (0.1 kWcm(-2), 0.87) coatings previously tested at 10.6 μm (2.5 kW CO2 laser) exposure. Electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy suggests partial oxidation of Si(B)CN forming a stable protective SiO2 phase upon irradiation.

Evaluation of a pyroelectric detector with a carbon multiwalled nanotube black coating in the infrared

The performance of a pyroelectric detector with a carbon multiwalled nanotube coating was evaluated in the 0.9-14 microm wavelength range. The relative spectral responsivity of this detector was shown to be flat over most of the wavelength range examined, and the spectral flatness was shown to be comparable to the best infrared black coatings currently available. This finding is promising because black coatings with spectrally flat absorbance profiles are usually associated with the highest absorbance values. The performance of the detector (in terms of noise equivalent power and specific detectivity) was limited by the very thick (250 microm thick) LiNbO3 pyroelectric crystal onto which the coating was deposited. The responsivity of this detector was shown to be linear in the 0.06-2.8 mW radiant power range, and its spatial uniformity was comparable to that of other pyroelectric detectors that use different types of black coating. The carbon nanotube coatings were reported to be much more durable than other infrared black coatings, such as metal blacks, that are commonly used to coat thermal detectors in the infrared. This, in combination with their excellent spectral flatness, suggests that carbon nanotube coatings appear extremely promising for thermal detection applications in the infrared.

Far infrared thermal detectors for laser radiometry using a carbon nanotube array

We present a description of a 1.5 mm long, vertically aligned carbon nanotube array (VANTA) on a thermopile and separately on a pyroelectric detector. Three VANTA samples, having average lengths of 40 μm, 150 μm, and 1.5 mm were evaluated with respect to reflectance at a laser wavelength of 394 μm(760 GHz), and we found that the reflectance decreases substantially with increasing tube length, ranging from 0.38 to 0.23 to 0.01, respectively. The responsivity of the thermopile by electrical heating (98.4 mA/W) was equal to that by optical heating (98.0 mA/W) within the uncertainty of the measurement. We analyzed the frequency response and temporal response and found a thermal decay period of 500 ms, which is consistent with the specific heat of comparable VANTAs in the literature. The extremely low (0.01) reflectance of the 1.5 mm VANTAs and the fact that the array is readily transferable to the detectors surface is, to our knowledge, unprecedented.

Synthesis of polymer-derived ceramic Si(B)CN-carbon nanotube composite by microwave-induced interfacial polarization.

We demonstrate synthesis of a polymer-derived ceramic (PDC)-multiwall carbon nanotube (MWCNT) composite using microwave irradiation at 2.45 GHz. The process takes about 10 min of microwave irradiation for the polymer-to-ceramic conversion. The successful conversion of polymer coated carbon nanotubes to ceramic composite is chemically ascertained by Fourier transform-infrared and X-ray photoelectron spectroscopy and physically by thermogravimetric analysis and transmission electron microscopy characterization. Frequency dependent dielectric measurements in the S-Band (300 MHz to 3 GHz) were studied to quantify the extent of microwave-CNT interaction and the degree of selective heating available at the MWCNT-polymer interface. Experimentally obtained return loss of the incident microwaves in the specimen explains the reason for heat generation. The temperature-dependent permittivity of polar molecules further strengthens the argument of internal heat generation.

High-performance carbon nanotube coatings for high-power laser radiometry

Radiometry for the next generation of high-efficiency, high-power industrial lasers requires thermal management at optical power levels exceeding 10 kW. Laser damage and thermal transport present fundamental challenges for laser radiometry in support of common manufacturing processes, such as welding, cutting, ablation, or vaporization. To address this growing need for radiometry at extremely high power densities, we demonstrate multiwalled carbon nanotube (MWCNT) coatings with damage thresholds exceeding 15 000 W/cm2 and absorption efficiencies over 90% at 1.06 μm. This result demonstrates specific design advantages not possible with other contemporary high-power laser coatings. Furthermore, the results demonstrate a performance difference between MWCNTs and single-walled carbon nanotube coatings, which is attributed to the lower net thermal resistance of the MWCNT coatings. We explore the behavior of carbon nanotubes at two laser wavelengths (1.06 and 10.6 μm) and also evaluate the optical-absorption ef...

Domain-engineered pyroelectric radiometer

We built a large-area domain-engineered pyroelectric radiometer with high spatial and spectral response uniformity that is an excellent primary transfer standard for measurements in the near- and the mid-infrared wavelength regions. The domain engineering consisted of inverting the spontaneous polarization over a 10-mm-diameter area in the center of a uniformly poled, 15.5 mm x 15.5 mm square, 0.25-mm-thick LiNbO(3) plate. Gold black was used as the optical absorber on the detector surface, and an aperture was added to define the optically sensitive detector area. Our results indicate that we significantly reduced the acoustic sensitivity without loss of optical sensitivity. The detector noise equivalent power was not exceptionally low but was nearly constant for different acoustic backgrounds. In addition, the detectors spatial-response uniformity variation was less than 0.1% across the 7.5-mm-diameter aperture, and reflectance measurements indicated that the gold-black coating was spectrally uniform within 2%, from 800 to 1800 nm. Other detailed evaluations of the detector include detector responsivity as a function of temperature, electrical frequency response, angular response, and field of view.

Atomic clock with 1×10(-18) room-temperature blackbody Stark uncertainty.

The Stark shift due to blackbody radiation (BBR) is the key factor limiting the performance of many atomic frequency standards, with the BBR environment inside the clock apparatus being difficult to characterize at a high level of precision. Here we demonstrate an in-vacuum radiation shield that furnishes a uniform, well-characterized BBR environment for the atoms in an ytterbium optical lattice clock. Operated at room temperature, this shield enables specification of the BBR environment to a corresponding fractional clock uncertainty contribution of 5.5×10(-19). Combined with uncertainty in the atomic response, the total uncertainty of the BBR Stark shift is now 1×10(-18). Further operation of the shield at elevated temperatures enables a direct measure of the BBR shift temperature dependence and demonstrates consistency between our evaluated BBR environment and the expected atomic response.

Pyroelectric Trap Detector for Spectral Responsivity Measurements

We have designed and built a pyroelectric optical detector for use as a transfer standard for the calibration of optical power meters. The pyroelectric element is made from lithium tantalate (LiTaO3). Gold black is used as the optical absorber in a multiple reflection wedge-shaped trap structure, with a 5-mm diameter input aperture and an f/4 field-of-view. The detector’s spatial responsivity varies less than 1%. The responsivity as a function of wavelength varies less than 1% over a range from 0.45–1.55 µm and less than 4% from 1.55–10.6 µm. The measured noise equivalent power (NEP) is 5 × 10−8 W/Hz1/2. For this wavelength range and detector area, the measured NEP and spatial uniformity represents a significant improvement over comparable predecessors.