John Matthew Ginder

RHEOLOGY OF MAGNETORHEOLOGICAL FLUIDS: MODELS AND MEASUREMENTS

Numerical and analytical models of magnetorheological fluid phenomena that account explicitly for the effects of magnetic nonlinearity and saturation are described. Finite-element analysis was used to calculate the field distribution in chains of magnetizable particles. The field-dependent stress required to shear the chains was then obtained using the Maxwell stress tensor. Three regimes are identified: at low applied fields, the stress increase quadratically, as expected from linear magnetostatics. In intermediate fields, the contact or polar regions of each particle saturate, reducing the rate of increase of the stress with increasing field. At high fields, the particles saturate completely, and the stress reaches its limiting value. Approximate analytical expressions for the yield stress and shear modulus in these regimes are also derived. The predictions of these models are compared to magnetorheological experiments in the literature and from our laboratory. These models predict successfully the magn...

Magnetorheological elastomers: properties and applications

Magnetorhelogical (MR) elastomers are viscoelastic solids whose mechanical properties are controllable by applied magnetic fields. We have developed a family of MR elastomers, comprising micrometer-sized carbonyl iron particles embedded in natural rubber, that can be processed using conventional rubber-mixing techniques. By crosslinking the elastomer in the presence of an applied magnetic field, field-induced interparticle interactions promote the formation of particle chains and columns aligned along the field direction. The resulting composites possess field- dependent of the mechanical properties of MR elastometers enables the construction of controllable elastomeric components, such as suspension bushings, that may prove advantageous in some automotive applications.

MAGNETOSTRICTIVE PHENOMENA IN MAGNETORHEOLOGICAL ELASTOMERS

A host of fascinating and useful magnetic phenomena are found in composites containing magnetizable particles in viscoelastic solids. Embedding magnetically soft iron particles in natural rubber produces a class of magnetostrictive composites sometimes termed magnetorheological (MR) elastomers. We have previously shown that these materials can exhibit viscoelastic moduli that increase substantially in an applied magnetic field. In this paper, we incorporate MR elastomers in a simple resonant structure called a tuned absorber to measure the complex dynamic shear moduli of these materials at high frequencies. We find that the fluid-induced modulus increase in MR elastomers is substantial even at kilohertz mechanical frequencies. As in previous measurements at low frequencies, the moduli are generally found to decrease with strain amplitude. We also report preliminary measurements of the relatively large elongation of these materials in applied magnetic fields.

Behavior of Magnetorheological Fluids

In the absence of an applied magnetic field, magnetorheological (MR) fluids typically behave as nearly ideal Newtonian liquids. The application of a magnetic field induces magnetic dipole and multipole moments on each particle. The anisotropic magnetic forces between pairs of particles promote the head-to-tail alignment of the moments and draws the particles into proximity. These attractive interparticle forces lead to the formation of chains, columns, or more complicated networks of particles aligned with the direction of the magnetic field. When these structures are deformed mechanically, magnetic restoring forces tend to oppose the deformation. Substantial field-dependent enhancements of the rheological properties of these materials result, as demonstrated in Figure 1. The myriad potential applications of MR and electrorheological (ER) fluids provide considerable motivation for research on these materials. The availability of fluids with yield stresses or apparent viscosities that are controllable over many orders of magnitude by applied fields enables the construction of electromechanical devices that are engaged and controlled by electrical signals and that require few or no moving parts. Potential automotive applications include electrically engaged clutches for vehicle powertrains and engine accessories as well as semiactive shock absorbers that can adapt in real time to changing road conditions. Semiactive dampers for rotorcraft control surfaces are among the potential aerospace applications. The critical need to mitigate the structural vibrations of large structures has led to the construction of large, high-force MR-fluid-based dampers. A promising application in manufacturing processes is the computer-aided polishing of precision optics in which abrasive particles are suspended in an MR fluid so that the polishing rate is determined in part by the strength of an applied magnetic field.

Controllable-stiffness components based on magnetorheological elastomers

So-called magnetorheological (MR) elastomers, comprising rubbery polymers loaded with magnetizable particles that are aligned in a magnetic field, possess dynamic stiffness and damping that can subsequently be controlled by applied fields. Tunable automotive bushings and mounts incorporating these materials and an embedded magnetic field source have been constructed. In this article, the response of these components to dynamic mechanical loading is described. They behave essentially as elastomeric springs with stiffness and damping that is increased by tens of percent with an applied electrical current. Their time of response to a change in current is less than ten milliseconds. In addition to a tunable spring or force generator, these components may also serve as deflection sensors.

The Materials Science of Field-Responsive Fluids

Scientists and engineers are most familiar with single-crystal or polycrystalline field-responsive or “smart” materials with responses typically occurring while the materials remain in the solid state. This issue of MRS Bulletin focuses on another class of field-responsive materials that exhibits a rapid, reversible, and tunable transition from a liquidlike, free-flowing state to a solidlike state upon the application of an external field. These materials demonstrate dramatic changes in their rheological behavior in response to an externally applied electric or magnetic field and are known as electrorheological (ER) fluids or magnetorheological (MR) fluids, respectively. They are often described as Bingham plastics, and exhibit a strong field-dependent shear modulus and a yield stress that must be overcome to initiate gross material deformation or flow. Prototypical ER fluids consist of linear dielectric particles (such as silica, titania, and zeolites) dispersed in nonconductive liquids such as silicone oils. Homogeneous liquid-crystalline (LC) polymerbased ER fluids have also been recently reported. MR fluids are based on ferromagnetic or ferrimagnetic, magnetically nonlinear particles (e.g., iron, nickel, cobalt, and ceramic ferrites) dispersed in organic or “aqueous liquids. Unlike ER and MR fluids, ferrofluids (or magnetic fluids), which are stable dispersions of nanosized superparamagnetic particulates (~5–10 nm) of such materials as iron oxide, do not develop a yield stress on application of a magnetic field. Applications of ferrofluids are primarily in the area of sealing devices (see Rosensweig for more information). Since ferrofluids are well-known and have been extensively discussed elsewhere in the literature, they will not be treated in detail here.

Synthesis and Properties of Novel Magnetorheological Fluids Having Improved Stability and Redispersibility

A novel class of relatively stable and redispersible MR fluids based on meso-scale magnetic particles of iron or nickel zinc ferrite and nano-scale additives is described. For a flux density B ~ 1 Tesla, the iron based MR fluids exhibited yield stresses of ~100 kPa. For ferrite based fluids the yield stress values were as high as ~15 kPa at B ~ 1T. The yield stresses at the flux density required for magnetic saturation increase quadratically with the saturation magnetization of the particulate material, in good agreement with a model for the yield stress of uniformly saturated particle chains. At lower flux densities, the yield stress was generally observed to increase as B3/2, consistent with models of the role of local saturation of the particle magnetization. The additives were found to enhance the stability and redispersibility of the MR fluids: they appeared to promote a small non-zero yield stress in the absence of a field but were found not to have a substantial effect on the field-dependent yield stresses.

Evanescent-wave scattering by electrophoretic microparticles: a mechanism for optical switching.

The total internal reflection of light occurring at the interface between glass and a low-index liquid containing suspended microparticles can be electrically controlled. The particles are charged and the glass is coated with a thin, transparent conductor. When the conductor is biased to attract the particles, they scatter and absorb light from the evanescent optical field near the interface, thus reducing the reflectivity. When the conductor is biased to repel the particles, total internal reflection is achieved. Experimental results are given for the time, voltage, and angle-of-incidence dependence of the reflectivity at the interface between an In-Sn-oxide-coated glass surface and a suspension of 0.47-µm-diameter silica particles in acetonitrile. The switching is found to be fast (~ 100 ms) and reproducible. In certain conditions the on/off ratio for a single reflection can be as large as 2:1. A simple theoretical model is developed to interpret these experiments. The model gives a reasonable fit to the data and allows one to extract information such as the particle mobility and the particle density in the evanescent-wave region.

Synthesis and Properties of Magnetorheological (MR) Fluids for Active Vibration Control

Magnetorheological (MR) fluids represent an exciting class ofsmart materials for use in active vibration control and other applications. This paper discusses some of the fundamental materials science concepts that define the scientific basis for designing MR fluids. Preliminary experimental data and observations concerning the synthesis as well as the rheological behavior of MR fluids based on carbonyl iron and iron oxide particulates are presented and discussed.