John N. Hahladakis

Sequential application of chelating agents and innovative surfactants for the enhanced electroremediation of real sediments from toxic metals and PAHs.

This study focused on the sequential application of a chelating agent (citric acid) followed by a surfactant in the simultaneous electroremediation of real contaminated sediments from toxic metals and Polycyclic Aromatic Hydrocarbons (PAHs). Furthermore, the efficiency evaluation of two innovative non-ionic surfactants, commercially known as Poloxamer 407 and Nonidet P40, was investigated. The results indicated a removal efficacy of approximately 43% and 48% for the summation of PAHs (SUM PAHs), respectively for the aforementioned surfactants, much better than the one obtained by the use of Tween 80 (nearly 21%). Individual PAHs (e.g. fluorene) were removed in percentages that reached almost 84% and 92% in the respective electrokinetic experiments when these new surfactants were introduced. In addition, the combined-enhanced sequential electrokinetic treatment with citric acid improved dramatically the removal of Zn and As, compared to the unenhanced run, but did not favor the other toxic metals examined. Since no improvement in metal removal percentages occurred when Tween 80 was used, significant contribution to this matter should also be attributed to the solubilization capacity of these innovative, in electrokinetic remediation, non-ionic surfactants.

Qualitative and quantitative determination of heavy metals in waste cellular phones.

Twenty four waste cellular phones, manufactured between 2002 and 2011, were selected in order to determine the total heavy metal content in each of their parts (printed circuit boards (PCBs), plastic housing (PH) and liquid crystal display monitors (LCDs)) and compare the results with the permissible limits set by the 2003 Directive on Restriction of Hazardous Substances (RoHS). All the selected samples were pulverized and digested with strong acids. Inductively coupled plasma-mass spectrometry was used to measure the heavy metal content in each sample. The results revealed that concentration levels of the examined heavy metals were higher in PCBs, followed by PH and LCD in that particular order (PCB>PH>LCD). With the exception of Pb and Cr present in PCBs of mobile phones released before the year 2006, all the other metal concentrations were according to the Directive. Concentration levels of Cd, Hg were lower than the permissible limits set by the EU, either before or after the validity of the 2003 RoHS Directive. Considering their significant heavy metal content, coupled with their large quantities produced worldwide in an annual rate, waste cellular phones need to be treated under an environmentally sound management scheme, prioritizing recycling and at the same time eliminating the possibility of any harm.

Technical properties of biomass and solid recovered fuel (SRF) co-fired with coal: Impact on multi-dimensional resource recovery value

The power plant sector is adopting the co-firing of biomass and solid recovered fuel (SRF) with coal in an effort to reduce its environmental impact and costs. Whereas this intervention contributes to reducing carbon emissions and those of other pollutants related with the burning of fossil fuel, it may also result in hidden impacts that are often overlooked. When co-firing, the physical and chemical properties of the mixed fuels and the subsequent technical implications on the process performance and by-products are significant. Interconnections between multiple values nested within four domains of value, i.e. environmental, economic, technical and social, mean that changes in the one domain (in the co-firing case, the technical one) can have considerable implications in the other domains as well. In this study, using a systematic and flexible approach to conceptualising multi-dimensional aspects associated with the co-firing of biomass and SRF with coal, we unveil examples of such interconnections and implications on overall value delivered through the use and recovery of waste resources. Such an analysis could underpin the selection of useful metrics (quantitative or semi-quantitative descriptors) for enabling a systemic multi-dimensional value assessment, and values distribution amongst interconnected parts of resource recovery systems; key in enabling sound analysis and decision-making.

Closing the loop on plastic packaging materials: What is quality and how does it affect their circularity?

While attention on the importance of closing materials loops for achieving circular economy (CE) is raging, the technicalities of doing so are often neglected or difficult to overcome. These technicalities determine the ability of materials, components and products (MCPs) to be properly recovered and redistributed for reuse, recycling or recovery, given their remaining functionality, described here as the remaining properties and characteristics of MCPs. The different properties of MCPs make them useful for various functions and purposes. A transition, therefore, towards a CE would require the utmost exploitation of the remaining functionality of MCPs; ideally, enabling recirculation of them back in the economy. At present, this is difficult to succeed. This short communication article explains how the remaining functionality of MCPs, defined here as quality, is perceived at different stages of the supply chain, focusing specifically on plastic packaging, and how this affects their potential recycling. It then outlines the opportunities and constraints posed by some of the interventions that are currently introduced into the plastic packaging system, aimed at improving plastic materials circularity. Finally, the article underpins the need for research that integrates systemic thinking, with technological innovations and policy reforms at all stages of the supply chain, to promote sustainable practices become established.