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John W. Cran

Florida State University

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Featured researches published by John W. Cran.

Organic and Biomolecular Chemistry | 2011

Gold(I)-catalyzed Claisen rearrangement of allenyl vinyl ethers; synthesis of substituted 1,3-dienes.

Marie E. Krafft; Kassem M. Hallal; Dinesh V. Vidhani; John W. Cran

Synthesis of substituted 1,3-dienes was achieved via gold(I)-catalyzed Claisen rearrangement of allenyl vinyl ethers. The N-heterocyclic carbene gold chloride catalyst (IPrAuCl) was superior in terms of activity and selectivity and afforded the 3,3-product in excellent yields. A proposed cation-π inter-action played a significant role in affecting the reaction rate.

Synlett | 2005

A convenient protocol for the α-iodination of α,β-unsaturated carbonyl compounds with I2 in an aqueous medium

Marie E. Krafft; John W. Cran

Journal of Organic Chemistry | 2013

Gold(I)-Catalyzed Claisen Rearrangement of Allenyl Vinyl Ethers: Missing Transition States Revealed through Evolution of Aromaticity, Au(I) as an Oxophilic Lewis Acid, and Lower Energy Barriers from a High Energy Complex

Dinesh V. Vidhani; John W. Cran; Marie E. Krafft; Mariappan Manoharan; Igor V. Alabugin

Chemical Communications | 2011

Solvent controlled mechanistic dichotomy in a Au(III)-catalyzed, heterocyclization triggered, Nazarov reaction

Marie E. Krafft; Dinesh V. Vidhani; John W. Cran; Mariappan Manoharan

Angewandte Chemie | 2012

Regioselective Cyclizations Utilizing a Gold-Catalyzed [3,3] Propargyl Ester Rearrangement†

John W. Cran; Marie E. Krafft

Organic and Biomolecular Chemistry | 2013

Overriding the alkynophilicity of gold: catalytic pathways from higher energy Au(I)–substrate complexes and reactant deactivation via unproductive complexation in the gold(I)-catalyzed propargyl Claisen rearrangement

Dinesh V. Vidhani; John W. Cran; Marie E. Krafft; Igor V. Alabugin

Tetrahedron | 2011

The intramolecular Morita–Baylis–Hillman-type alkylation reaction

John W. Cran; Marie E. Krafft; Kimberly A. Seibert; Thomas F. N. Haxell; James A. Wright; Chitaru Hirosawa; Khalil A. Abboud

Tetrahedron Letters | 2011

Intermolecular Morita–Baylis–Hillman reactions using dicobalthexacarbonyl complexed acetylenic acetals

Marie E. Krafft; Mark J. Campbell; Sean Kerrigan; John W. Cran

Tetrahedron Letters | 2011

The Darzens condensation of α,β-unsaturated aldehydes and ketones

Marie E. Krafft; Steven J.R. Twiddle; John W. Cran

Synlett | 2014

Copper-Catalyzed N-tert-Butylation of Aromatic Amines under Mild Condi­tions Using tert-Butyl 2,2,2-Trichloroacetimidate

John W. Cran; Dinesh V. Vidhani; Marie E. Krafft

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Marie E. Krafft

Florida State University

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Dinesh V. Vidhani

Florida State University

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Igor V. Alabugin

Florida State University

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Mariappan Manoharan

Florida State University

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James A. Wright

Florida State University

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Kassem M. Hallal

Florida State University

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Khalil A. Abboud

University of Florida

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Kimberly A. Seibert

Florida State University

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Mark J. Campbell

Florida State University

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Sean Kerrigan

Florida State University

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