Jong-Beom Seo

Removal characteristics of CO2 using aqueous MEA/AMP solutions in the absorption and regeneration process

The carbon dioxide (CO2) removal efficiency, reaction rate, and CO2 loading into aqueous blended monoethanolamine (MEA) + 2-amino-2-methyl-1-propanol (AMP) solutions to enhance absorption characteristics of MEA and AMP were carried out by the absorption/regeneration process. As a result, compared to aqueous MEA and AMP solutions, aqueous blended MEA + AMP solutions have a higher CO2 loading than MEA and a higher reaction rate than AMP. The CO2 loading of rich amine of aqueous 18 wt.% MEA + 12 wt.% AMP solution was 0.62 mol CO2/mol amine, which is 51.2% more than 30 wt.% MEA (0.41 mol CO2/mol amine). Consequently, blending MEA and AMP could be an effective way to design considering economical efficiency and used to operate absorber for a long time.

Vaporization reduction characteristics of aqueous ammonia solutions by the addition of ethylene glycol, glycerol and glycine to the CO2 absorption process.

Aqueous ammonia (NH3) solution can be used as an alternative absorption for the control of CO2 emitted from flue gases due to its high absorption capacity, fast absorption rate and low corrosion problem. The emission of CO2 from iron and steel plants requires much attention, as they are higher than those emitted from power plants at a single point source. In the present work, low concentration ammonia liquor, 9 wt.%, was used with various additives to obtain the kinetic properties using the blast furnace gas model. Although a solution with a high ammonia concentration enables high CO2 absorption efficiency, ammonium ions are lost as ammonia vapor, resulting in reduced CO2 absorption due to the lower concentration of the ammonia absorbent. To decrease the vaporization of ammonia, ethylene glycol, glycerol and glycine, which contain more than one hydroxyl radical, were chosen. The experiments were conducted at 313 K similar to the CO2 absorption conditions for the blast furnace gas model.

A Study of the Amount of Fugitive Dust Generated from New Harbor Construction Site and the Prediction of Effect using AERMOD

A new harbor as been constructing in Gadukdo. However, a lot of fugitive dust gas been often generated from construction site reclaiming sea sand, especially when the Northwester is blown strongly. It has resulted insome appeals of residents in Gadukdo. In this study, we estimated the amount of fugitive dust caused by new harbor construction using Fugitive dust formula. Also, the concentration of PM10 for recipient is predicted by AERMOD. The amount of fugitive dust is 26.56 and 11.84 respectively by the Fugitive dust formula. PM10 outlet concentration and the amount of fugitive dust increase according to wind velocity and directions. AERMOD is performed on the basis of weather data and the amount of fugitive dust generated with wind velocity. As a result of AERMOD, the PM10 concentration of Sunchang and Oinul are predicted over 100 . The PM10 concentration of Sunchang and Oinul are predicted over 130 when wind velocity of northwester in winter is over 11 m/s (Air Quality for Particulate Matter (100 for 24 hours)). Also, the measured error between AERMOD and actual measurement is lower than 5%.

Absorption and Regeneration of Carbon Dioxide in Aqueous AMP + AEPD and AMP + TIPA Solutions

Increasing emission of significantly effects the global warming. Chemical absorption is one of separation methods of from the industrial flue gases. In this study, the removal efficiency as well as the absorption amount of aqueous AMP (2-amino-2-methyl-1-propanol) solutions were measured using the continuous absorption and regeneration apparatus. We investigated the effect of aqueous AMP+AEPD(2-amino-2-ethyl-1, 3-propanediol) and AMP+TIPA (triisopropanolamine) solutions to enhance absorption characteristics of AMP. As a result of this study, the absorption amount and removal efficiency were increased with adding TIPA into 30 wt.% AMP. The absorption amount and removal efficiency of aqueous 30 wt.% AMP+5 wt.% TIPA solution were and 91.1%, while those of aqueous 30 wt.% AMP solution were and 89.3%. In addition, aqueous 30 wt.% AMP+5 wt.% TIPA solution used in the study revealed the high stripping efficiency, which was almost 98%, at the temperature of . Thus, the temperature of regenerator should be operated at .