Jong-n Ha

Effects of oxidized biodiesel on formation of particulate matter and NO x from diesel engine

A test was conducted to investigate the effect of pure biodiesel without additives on formation of particulate matter (PM) and nitrogen oxide (NOx) in the exhaust gas of a diesel engine. Pure biodiesel from waste cooking oil without adding any additive was used. The biodiesel was oxidized at 110 °C for 10 days and blended with commercial automobile diesel oil distributed in the market as a testing fuel. Blended fuels were produced by adding 10% of oxidized biodiesel and un-oxidized biodiesel to automobile diesel oil, respectively. Material properties such as density, kinematic viscosity, oxidation stability, and cetane number were tested. Emission tests were conducted using a large diesel engine of direct injection type, inline six-cylinder, 4 stroke, turbocharger and intercooler. The oxidized and unoxidized biodiesel blends did not show any difference in density and kinematic viscosity. The oxidation stability of the oxidized biodiesel blends was lower than that of the unoxidized biodiesel blends. In the emission test, the two blends showed almost no difference in the total number of concentration of the micro-particles, and also showed almost no difference in particle size distribution such as nucleation mode and accumulation mode. On the other hand, the oxidized biodiesel blends showed less PM and NOx emission than the unoxidized biodiesel blends.

The SIMDIST (Simulated Distillation) Analysis of Distributing Engine Oil

The vehicle lubricant occupies upto 35% in a total lubricant market and engine oil occupies upto 77% in the vehicle lubricant market in Korea. A suitable quality management of the circulating engine oil is necessary for driver and engine protection. But, KS and synthetic engine oil products (involved over 30% synthetic oil) are exempt to any quality management under Petroleum and Alternative Fuel Business Act. It is also known that synthetic oils such as PAO (poly alpha olefin) have excellent properties and performance like anti-wear, varnish control and oxidation stability than those of mineral oils. For this reason, PAO has been used for an engine oil, rotary screw and reciprocating compressor in addition to heavy duty and other extreme service applications. In this study, our research group analyzed the chromatogram pattern for the mineral oil, PAO and mineral oil involved a typical ratio of PAO using SIMDIST (simulated distillation). In the SIMDIST chromatogram, the mineral oil showed a broad peak, while PAO showed a sharp typical peak. Also the oil with a large viscosity grade exhibited a long retention time due to the heavy molecular weight and high boiling point. In particular, the blended mineral oil with 20% PAO sample showed a distinctly different pattern compared to that of using the conventional mineral oil. For monitoring PAO contents in distributing engine oils, we analyzed the SIMDIST for 27 kinds of engine oils which were popularly sold in Korea. The analytic results indicate that all kinds of engine oils showed that PAO contents were below 20% in engine oil products. Moreover, the PAO titled product was found to have a small amount of PAO. Thus, we conclude that the related laws for the proper quality management of synthetic oils are needed to be established.

The Study on Effect of Emissions and Performance of a Conventional Vehicle using the High Concentration Alcohol Blended Petroleum Product

As concern about energy security and global warming many countries have been making effort to reduce fossil fuel. In the case of US, as one of the efforts, the standards of the alcohol vehicle fuels(including blended with gasoline) have been established. Alcohol is known that make some trouble concerning startability, durability and corrosion when using as fuel of a conventional vehicle. For these reason, alcohol usage needs not only the fuel standard, but also a modified car. In the case of Korea, although there are no the standard and the modified vehicle yet, high concentration alcohol blended fuel has being sold at illegal market. In this study, exhaust gas and performance of the conventional vehicle that alcohol(methanol and isopropyl alcohol) blends were fueled were measured to notify danger of using them without preparation of institutional arrangements. Also, to analyze correlation characteristics of the fuels and them, property test of the fuels was conducted. The test result show that bad-startability caused by low RVP and high T10 affected increase in NMOG and CO. NOx was increased under the highest short term fuel trim caused by high Oxygen content and low NHV of alcohol. According to increasing as alcohol content, fuel economy and acceleration ability were decreased but CO2 was not significantly

A study on Property of Emission Gas by the Content Variation of Urea

Abstract - National and international regulations on the exhaust gases of diesel engines are being strengthened, and a study of the combutsion engine and the post-porcessing system are in progress as a variety of ways. There are many techniques for the removal of nitrogen oxide like HC-SCR, LNT, Urea-SCR. And the technical development on the Urea-SCR owing to high conversion efficiency and fuel economy characteristics has being processed. This study investigated the physical/chemical properties of urea according to the change of the urea content, and were analysed the characteristic of exhaust gas. According to the increase of urea content, the contests of biuret aldehyde, phosphate content was increased and the changes of emission quantity of carbon monoxide, hydrocarbons and particulate matter in the exhaust gas was very slight. The emission quantity of NOx was decreased in accordance with increasing the urea content and it was shown to be more than 80 % in the urea solution having more than 30 wt%.

Feasibility Test of LPG Vehicles by Using DME-LPG Blends

Abstract - Dimethyl ether (DME) can be used as a clean diesel alternative fuel due to the high cetane number and low emission, it can also be applied to automotive fuel as a blended liquefied petroleum gas (LPG) because physical properties are similar to those of LPG. In this study, feasibility test of LPG vehicle using blended DME-LPG fuel was investigated. Three types of fuel supply such as LPLi (Liquid phase LPG injection), LPGi (Liquid phase gas injection) and mixer type were selected to consider the LPG fuel-injection system. The performance characteristics of LPG vehicle were examined by using LPG and blended DME-LPG fuel in order to compare the exhaust emissions (CO, THC, NO X ) and fuel economy. The emissions and fuel economy of DME-LPG blend fuel were comparable to those of LPG with increasing driving distance. Key words : DME, LPG, Alternative fuel, Emission, Fuel economy 1. 서 론 디메틸에테르(DME, dimethyl ether)는 구조식이 CH 3 OCH 3 인 함산소물질로 천연가스, 석탄 및 바이오매스로부터 합성되며 인체에 독성이 없고 친환경적이기 때문에 석유대체연료로 주목받고 있다. 전 세계적으로 석유대체연료에 대한 관심이 높아지는 상황에서 DME는 에너지원 다변화, 에너지안보 및 친환경적 측면에서 보급중이거나 도입을 위해 연구 중에 있다[1-3].DME 연료의 표준화 작업도 전 세계적으로 이루어져 , 일본은 2013년 3월 JIS K 2180-1을 제정하여 연료용 DME의 품질기준과 시험방법을 마련하였다. 미국은

A Study on the Property and Performance Characteristics of Different Kind Engine Oil by Endurance Test of Heavy-duty Diesel Engine

Abstract : Engine oil is an oil used for lubrication of various internal combustion engines. The main function is to reduce wear on moving parts; it also cleans, inhibits corrosion, improves sealing, and cools the engine by carrying heat away from moving parts. In engines, there are parts which move against each other. Otherwise, the friction wastes the useful power by converting the kinetic energy to heat. Those parts were worn away, which could lead to lower efficiency and degradation of the engine. It increases fuel consumption, decreases power output, and can induce the engine failure. This study was conducted to evaluate the relation between engine oil property changes and engine performance for the diesel engine. This test was performed by using 12L, 6 cylinder, heavy duty engines. Low SAPS 10W30 engine oil (two type engine oils) was used. Test procedure and method was in accordance with the modified CEC L-57-T97 (OM441LA) method. In this study, TAN, TBN, KV and metal components, engine power, blowby gas, A_F were presented to evaluate the relation with engine oil property changes and engine performance. TAN, TBN, KV and metal We found that the components were generally increased but engine performance did not change. This results mean that property changes did not affect on engine performance because those were not enough to affect engine performance.

Development of Calorific Values and Carbon Emission Factors for Petroleum Energy in Korea from 2012 to 2013

Country-specific data for net calorific values and carbon emission factors requires for a higher tier estimate of greenhouse gas emissions in the energy sector. The objective of this study is to develop country-specific net calorific values and carbon emission factors for petroleum energy produced in Korea. Calorific values and carbon contents of the fuels were measured using the oxygen bomb calorimeter method and the CHN elemental analysis method, respectively. Sulfur and hydrogen contents, which were used to calculate the net calorific value, were also measured and then net calorific values and carbon emission factors were determined based on the measurement results. The net calorific values and carbon emission factors determined for the petroleum produced in Korea 2012 and 2013 were compared to those in the 2006 IPCC Guidelines. Most of the values were different compared with the default values of the 2006 IPCC Guidelines although those were placed within their upper and lower limits. Time series analysis results showed inconsistent seasonal variation for the net calorific values and carbon emission factors.

A study on Property and CO 2 Emission Factor of Domestic Transportation Fuel

Intergovernmental Panel on Climate Change(IPCC) suggested the three methodology, Tier 1/2/3, considering with the accuracy and difficulty of greenhouse gas emission statistics according to the report determined as the international criterion. In Korea, the existing inventory building was made by the Top-down approach applying with the emission factors for transportation in the entire energy consumption, the emission factors were investigated under the domestic traffic situation which did not reflect by the continuing increase of vehicle and the change of road section. From the suggestion of IPCC, which it is estimated that the emission estimation of CO 2 in greenhouse gas emission could be calculated more accurate by the carbon content according to the fuel, the establishment of measures to respond to climate change from the latest greenhouse gas emissions statistics will be able to improve the accuracy of national statistics using monthly or seasonally the analysis of carbon content about the transportation fuels.