Jordon Bright

Amino acid geochronology of individual foraminifer (Pulleniatina obliquiloculata) tests, north Queensland margin, Australia: A new approach to correlating and dating Quaternary tropical marine sediment cores

[1] In this study, we demonstrate the utility of amino acid geochronology based on single-foraminiferal tests in Quaternary sediment cores from the Queensland margin, Australia. The large planktonic foraminifer Pulleniatina obliquiloculata is ubiquitous in shelf, slope, and basin sediments of north Queensland as well as pantropical oceans. Fossil tests are resistant to dissolution, and retain substantial concentrations of amino acids (2–4 nmol mg � 1 of shell) over hundreds of thousands of years. Amino acid D and L isomers of aspartic acid (Asp) and glutamic acid (Glu) were separated using reverse phase chromatography, which is sensitive enough to analyze individual foraminifera tests. In all, 462 Pulleniatina tests from 80 horizons in 11 cores exhibit a systematic increase in D/L ratios down core. D/L ratios were determined in 32 samples whose ages are known from AMS 14 C analyses. In all cases, the Asp and Glu D/L ratios are concordant with 14 C age. D/L ratios of equal-age samples are slightly lower for cores taken from deeper water sites, reflecting the sensitivity of the rate of racemization to bottom water temperature. Beyond the range of 14 C dating, previously identified marine oxygen-isotope stage boundaries provide approximate ages of the sediments up to about 500,000 years. For this longer time frame, D/L ratios also vary systematically with isotope-correlated ages. The rate of racemization for Glu and Asp was modeled using power functions. These equations can be used to estimate ages of samples from the Queensland margin extending back at least 500,000 years. This analytical approach provides new opportunities for geochronological control necessary to understand fundamental sedimentary processes affecting a wide range of marine environments. INDEX TERMS: 4267 Oceanography: General: Paleoceanography; 4850 Oceanography: Biological and Chemical: Organic marine chemistry; 3022 Marine Geology and Geophysics: Marine sediments— processes and transport; KEYWORDS: Queensland margin, marine sediment, amino acid racemization, geochronology, foraminifera, Quaternary stratigraphy Citation: Hearty, P. J., M. J. O’Leary, D. S. Kaufman, M. C. Page, and J. Bright (2004), Amino acid geochronology of individual foraminifer (Pulleniatina obliquiloculata) tests, north Queensland margin, Australia: A new approach to correlating and dating Quaternary tropical marine sediment cores, Paleoceanography, 19, PA4022, doi:10.1029/2004PA001059.

Importance of groundwater in propagating downward integration of the 6–5 Ma Colorado River system: Geochemistry of springs, travertines, and lacustrine carbonates of the Grand Canyon region over the past 12 Ma

We applied multiple geochemical tracers ( 87 Sr/ 86 Sr, [Sr], δ 13 C, and δ 18 O) to waters and carbonates of the lower Colorado River system to evaluate its paleohydrology over the past 12 Ma. Modern springs in Grand Canyon reflect mixing of deeply derived (endogenic) fluids with meteoric (epigenic) recharge. Travertine ( 87 Sr/ 86 Sr and δ 13 C and δ 18 O values that overlap with associated water values, providing justification for use of carbonates as a proxy for the waters from which they were deposited. The Hualapai Limestone (12–6 Ma) and Bouse Formation (5.6–4.8 Ma) record paleohydrology immediately prior to and during integration of the Colorado River. The Hualapai Limestone was deposited from 12 Ma (new ash age) to 6 Ma; carbonates thicken eastward to ∼210 m toward the Grand Wash fault, suggesting that deposition was synchronous with fault slip. A fanning-dip geometry is suggested by correlation of ashes between subbasins using tephrochronology. New detrital-zircon ages are consistent with the “Muddy Creek constraint, ” which posits that Grand Wash Trough was internally drained prior to 6 Ma, with limited or no Colorado Plateau detritus, and that Grand Wash basin was sedimentologically distinct from Gregg and Temple basins until after 6 Ma. New isotopic data from Hualapai Limestone of Grand Wash basin show values and ranges of 87 Sr/ 86 Sr, δ 13 C, and δ 18 O that are similar to Grand Canyon springs and travertines, suggesting a long-lived springfed lake/marsh system sourced from western Colorado Plateau groundwater. Progressive up-section decrease in 87 Sr/ 86 Sr and δ 13 C and increase in δ 18 O in the uppermost 50 m of the Hualapai Limestone indicate an increase in meteoric water relative to endogenic inputs, which we interpret to record progressively increased input of high-elevation Colorado Plateau groundwater from ca. 8 to 6 Ma. Grand Wash, Hualapai, Gregg, and Temple basins, although potentially connected by groundwater, were hydrochemically distinct basins before ca. 6 Ma. The 87 Sr/ 86 Sr, δ 13 C, and δ 18 O chemostratigraphic trends are compatible with a model for downward integration of Hualapai basins by groundwater sapping and lake spillover. The Bouse Limestone (5.6–4.8 Ma) was also deposited in several hydrochemically distinct basins separated by bedrock divides. Northern Bouse basins (Cottonwood, Mojave, Havasu) have carbonate chemistry that is nonmarine. The 87 Sr/ 86 Sr data suggest that water in these basins was derived from mixing of high- 87 Sr/ 86 Sr Lake Hualapai waters with lower- 87 Sr/ 86 Sr, first-arriving “Colorado River” waters. Covariation trends of δ 13 C and δ 18 O suggest that newly integrated Grand Wash, Gregg, and Temple basin waters were integrated downward to the Cottonwood and Mojave basins at ca. 5–6 Ma. Southern, potentially younger Bouse basins are distinct hydrochemically from each other, which suggests incomplete mixing during continued downward integration of internally drained basins. Bouse carbonates display a southward trend toward less radiogenic 87 Sr/ 86 Sr values, higher [Sr], and heavier δ 18 O that we attribute to an increased proportion of Colorado River water through time plus increased evaporation from north to south. The δ 13 C and δ 18 O trends suggest alternating closed and open systems in progressively lower (southern) basins. We interpret existing data to permit the interpretation that the southernmost Blythe basin may have had intermittent mixing with marine water based on δ 13 C and δ 18 O covariation trends, sedimentology, and paleontology. [Sr] versus 87 Sr/ 86 Sr modeling suggests that southern Blythe basin 87 Sr/ 86 Sr values of ∼0.710–0.711 could be produced by 25%–75% seawater mixed with river water (depending on [Sr] assumptions) in a delta– marine estuary system. We suggest several refinements to the “lake fill-and-spill” downward integration model for the Colorado River: (1) Lake Hualapai was fed by western Colorado Plateau groundwater from 12 to 8 Ma; (2) high-elevation Colorado Plateau groundwater was progressively introduced to Lake Hualapai from ca. 8 to 6 Ma; (3) Colorado River water arrived at ca. 5–6 Ma; and (4) the combined inputs led to downward integration by a combination of groundwater sapping and sequential lake spillover that first delivered Colorado Plateau water and detritus to the Salton Trough at ca. 5.3 Ma. We propose that the groundwater sapping mechanism strongly influenced lake evolution of the Hualapai and Bouse Limestones and that groundwater flow from the Colorado Plateau to Grand Wash Trough led to Colorado River integration.

Chronology, sedimentology, and microfauna of groundwater discharge deposits in the central Mojave Desert, Valley Wells, California

During the late Pleistocene, emergent groundwater supported persistent and long-lived desert wetlands in many broad valleys and basins in the American Southwest. When active, these systems provided important food and water sources for local fauna, supported hydrophilic and phreatophytic vegetation, and acted as catchments for eolian and alluvial sediments. Desert wetlands are represented in the geologic record by groundwater discharge deposits, which are also called spring or wetland deposits. Groundwater discharge deposits contain information on the timing and magnitude of past changes in water-table levels and, thus, are a source of paleohydrologic and paleoclimatic information. Here, we present the results of an investigation of extensive groundwater discharge deposits in the central Mojave Desert at Valley Wells, California. We used geologic mapping and stratigraphic relations to identify two distinct wetland sequences at Valley Wells, which we dated using radiocarbon, luminescence, and uranium-series techniques. We also analyzed the sediments and microfauna (ostracodes and gastropods) to reconstruct the specifi c environments in which they formed. Our results suggest that the earliest episode of high water-table conditions at Valley Wells began ca. 60 ka (thousands of calendar yr B.P.), and culminated in peak discharge between ca. 40 and 35 ka. During this time, cold (4‐12 °C) emergent groundwater supported extensive wetlands that likely were composed of a wet, sedge-rush-tussock meadow mixed with mesic riparian forest. After ca. 35 ka, the water table dropped below the ground surface but was still shallow enough to support dense stands of phreatophytes through the Last Glacial Maximum (LGM). The water table dropped further after the LGM, and xeric conditions prevailed until modest wetlands returned briefl y during the Younger Dryas cold event (13.0‐11.6 ka). We did not observe any evidence of wet conditions during the Holocene at Valley Wells. The timing of these fl uctuations is consistent with changes in other paleowetland systems in the Mojave Desert, the nearby Great Basin Desert, and in southeastern Arizona, near the border of the Sonoran and Chihuahuan Deserts. The similarities in hydrologic conditions between these disparate locations suggest that changes in groundwater levels during the late Pleistocene in desert wetlands scattered throughout the American Southwest were likely driven by synopticscale climate processes.

Bouse Formation in the Bristol basin near Amboy, California, USA

Limestone beds underlain and overlain by alluvial fan conglomerate near Amboy, California, are very similar in many respects to parts of the Bouse Formation, suggesting that an arm of the Pliocene Bouse water body extended across a wide part of the southern Mojave Desert. The deposits are north of the town of Amboy at and below an elevation of 290 m, along the northern piedmont of the Bristol “dry” Lake basin. The Amboy outcrops contain the Lawlor Tuff (4.83 Ma), which is also found in an outcrop of the Bouse Formation in the Blythe basin near Buzzards Peak in the Chocolate Mountains, 180 km southeast of Amboy. Bouse exposures near Amboy are ∼3.4 m thick, white, distinctly bedded, with limestone and calcareous sandstone as well as stromatolite mounds; we interpret these as nearshore deposits. The Bouse at Amboy contains ostracodes, diatoms, and mollusks that indicate saline lake or estuarine environments with an admixture of fresh-water forms. Along with wading bird tracks and a spine from a marine fish, these fossils suggest that the deposits formed in saline waters near a fresh-water source such as a perennial stream. Beds of the outcrop dip southward and are 113 m above the surface of Bristol Playa, where similar age sediments are buried 270+ m deep, indicating significant faulting and vertical tectonics in this part of the Eastern California Shear Zone during the past 5 m.y. Confirmation of the Bouse Formation at Amboy strengthens previous assignments to the Bouse Formation for mudstones in driller logs at Danby “dry” Lake, California, and suggests that areally extensive arms of the Bouse water body were west of the Blythe basin. The Bristol basin arm of the lower Bouse basin probably was restricted from the main water body by narrow passages, but Bouse sediment there is similar to that in the Blythe basin, suggesting generally similar water chemistry and environmental conditions. Examining the degree to which Bouse deposits in the western arms differed from Bouse deposits in the Blythe basin offers an approach to test whether the southernmost Bouse water body was deposited in an estuarine or lacustrine setting.

DID A CATASTROPHIC LAKE SPILLOVER INTEGRATE THE LATE MIOCENE EARLY PLIOCENE COLORADO RIVER AND THE GULF OF CALIFORNIA?: MICROFAUNAL AND STABLE ISOTOPE EVIDENCE FROM BLYTHE BASIN, CALIFORNIA-ARIZONA, USA

Abstract The southern Bouse Formation (late Miocene–early Pliocene) in Blythe basin, CA-AZ, contains a controversial record of the events that preceded the integration of the developing Colorado River with the Gulf of California. High resolution microfaunal and stable isotope (δ18O, δ13C; VPDB) data from a key outcrop of marl and claystone record an abrupt change in water chemistry that we interpret to be the result of a catastrophic sill breach. Basal marl contains a mix of brackish-water ostracodes and marine foraminifers. Ostracode δ18O values are slightly negative and 6‰ higher than the host sediment carbonate precipitated in the upper water column, indicating isotopically stratified hydrologic conditions during deposition. Freshwater ostracodes abruptly appear in the overlying sediments in association with marine foraminifers, in conjunction with an abrupt change in the isotopic composition of ostracode and host sediment carbonate. The δ18O values from brackish and freshwater ostracodes and the host sediment carbonate are similar (~ −10‰), indicating an isotopically well-mixed water body during deposition. Sediment δ13C values decrease by 4.5‰ across this transition but ostracode δ13C values remain unchanged. We infer that the transition from stratified to well-mixed conditions likely took less than 300 years. The abruptness of this transition is best explained by catastrophic failure of a paleodam that rapidly altered the isotopic composition and salinity of a lake in Blythe basin. A marine or estuarine environment is unlikely. Our interpretation is consistent with other evidence for catastrophic breaching of another lacustrine Bouse Formation-bearing basin to the north.

Freshwater plumes and brackish lakes: Integrated microfossil and O-C-Sr isotopic evidence from the late Miocene and early Pliocene Bouse Formation (California-Arizona) supports a lake overflow model for the integration of the lower Colorado River corridor

CITATION: Bright, J., Cohen, A.S., Dettman, D.L., and Pearthree, P.A., 2018, Freshwater plumes and brackish lakes: Integrated microfossil and O-C-Sr isotopic evidence from the late Miocene and early Pliocene Bouse Formation (California-Arizona) supports a lake overflow model for the integration of the lower Colorado River corridor: Geosphere, v. 14, no. 4, p. 1875– 1911, https://doi.org/10.1130/GES01610.1.