José Saldanha Matos

In-sewer biodegradation study at the Costa do Estoril interceptor system

Abstract Understanding and quantifying the transformations of wastewater during transport in sewers is an important prerequisite to engineering and improving the performance of the integrated urban wastewater system. This paper describes experiments, which were carried out in a Portuguese interceptor sewer to quantify changes in different water quality determinands as a result of the combined activity of suspended and attached biomass. The focus is on dry weather flows under aerobic conditions. The highest reduction was found for dissolved COD, which includes an important fraction of easily biodegradable matter. The results are not directly applicable to other systems but indicate the range of values that can be expected under similar conditions.

Chloroplast SSR genetic diversity indicates a refuge for Corylus avellana in northern Portugal

The genus Corylus, a member of the birch family Betulaceae, includes several species that are widely distributed throughout temperate regions of the Northern Hemisphere. The development of microsatellites or simple sequence repeats (SSRs) for non-coding regions of the chloroplast genome and their higher sequence variation compared with coding regions has provided a higher resolution tool for the study of cultivars and closely related taxa. Chloroplast polymorphisms provide a marker system to evaluate the genetic structure of plant populations. This study investigated genetic diversity in three cultivars and 32 genotypes of Corylus avellana L. from Portugal: 13 wild genotypes and 19 Portuguese landraces. Four of ten cpSSR loci were polymorphic, with diversity indices ranging from 0.111 to 0.244. Eleven chlorotypes were detected, and their relationships were analyzed using a network model. Haplotype A was most frequent in landraces and cultivars. Four chlorotypes (H, I, J and L) were found only in wild hazelnuts. The diversity of chlorotypes in the wild hazels, and the limited number reported in cultivars, suggests that northern Portugal was a refuge for hazel during the last ice age.

Constructed wetlands for combined sewer overflow treatment in a Mediterranean country, Portugal.

The use of constructed wetlands as a valuable and attractive method for combined sewer overflow (CSO) treatment has been demonstrated in several studies. In Portugal, a Mediterranean country having usually a long dry period, there are still no applications of this technology. The purpose of this research is to gather information and know-how required for the design and management of this type of infrastructure. A pilot-scale experimental setup for CSO treatment was installed and evaluated in situ, in terms of organic matter, total suspended solids and microorganism removal with emphasis on the results of the start-up. After 1 day of retention average removal efficiencies of 73-79% and 82-89% were obtained in terms of chemical oxygen demand (COD) and total suspended solids (TSS), respectively. During the remaining retention time a slower removal was observed. After 7 days, the COD removal efficiencies reached 86-91% and the TSS removal efficiencies reached 93-97%. On average, after 1 day, reductions of 1.2-2.0 log and 1.9-2.4 log, respectively, for total coliforms and Enterococcus were observed. For a retention time of 7 days these reductions attained 4.0-4.9 log and 4.4-5.3 log, respectively.

Liquid-gas mass transfer of volatile substances in an energy dissipating structure

  Mass transfer of a range of volatile substances was studied under highly turbulent conditions. The applied setup mimicked drop structures, where the release of volatile organic carbons likely occurs at a high rate. The experiments covered several substances in a range of resistances from residing entirely in the liquid film to being fully in the gas film. The two-film theory yielded a good prediction of the whole measured range. This allowed the experimental validation of a method where two reference substances are applied, to determine the transfer of any other substance - independently of where its resistance to mass transfer resides. One finding was that the range of dimensionless Henrys constants, where both films contributed by more than 5%, was 0.0027 to 1.05, which is over five times higher than the accepted rule of thumb (0.0005-0.18). Another finding was that the ratio between the liquid and the gas film mass transfer coefficients of the reference substances was similar for the two drop configurations studied. If this holds true over a wider range of configurations, such a ratio constitutes a valuable shortcut to the current practice of ignoring gas film resistance in the estimation of mass transfer rates.

Assessing the environmental performance of urban wastewater systems using the INSA model: application to the Algés-Alcântara wastewater system, in Portugal.

Although the application of complex integrated models to wastewater systems is useful, it is often difficult to implement and not always suitable for the design of new systems or for their rehabilitation. Integrated simple approaches that allow assessing the environmental performance of urban wastewater systems may be advantageous, especially during the initial phases of the system planning process. This paper presents an original, straightforward approach that can be used for planning, design and operation of urban wastewater systems. The INtegrated Simplified Approach (INSA) combines the concepts of performance indicators with mass balances and can be applied to wastewater systems as a management support tool, particularly in situations where there is lack of data, economic limitations or time constraints. The INSA was applied to the Algés-Alcântara wastewater system to evaluate its environmental performance and to simulate the individual or combined impact of the rehabilitation measures proposed, thus defining their priority. The results clearly indicate that, despite the investment already made upgrading the wastewater treatment plant (WWTP), the proposed interventions must be implemented to ensure an acceptable environmental performance of the system. In addition, the results demonstrate the significant pollution loads present in stormwater, frequently higher than the pollution loads discharged into receiving waters during dry weather.

Modelling energy costs for different operational strategies of a large water resource recovery facility

The main objective of this paper is to demonstrate the importance of applying dynamic modelling and real energy prices on a full scale water resource recovery facility (WRRF) for the evaluation of control strategies in terms of energy costs with aeration. The Activated Sludge Model No. 1 (ASM1) was coupled with real energy pricing and a power consumption model and applied as a dynamic simulation case study. The model calibration is based on the STOWA protocol. The case study investigates the importance of providing real energy pricing comparing (i) real energy pricing, (ii) weighted arithmetic mean energy pricing and (iii) arithmetic mean energy pricing. The operational strategies evaluated were (i) old versus new air diffusers, (ii) different DO set-points and (iii) implementation of a carbon removal controller based on nitrate sensor readings. The application in a full scale WRRF of the ASM1 model coupled with real energy costs was successful. Dynamic modelling with real energy pricing instead of constant energy pricing enables the wastewater utility to optimize energy consumption according to the real energy price structure. Specific energy cost allows the identification of time periods with potential for linking WRRF with the electric grid to optimize the treatment costs, satisfying operational goals.

Redesigning water distribution networks using a guided evolutionary approach

AbstractThe paper describes and discusses the application of a guided evolutionary approach for the optimization of water distribution networks. Initially developed for the Battle of the Water Networks II (BWN-II), the approach was adapted and improved for competing in the Battle of Background Leakage Assessment for Water Networks (BBLAWN). The proposed evolutionary approach operates in an exclusively discrete solution space and is intended to require as little engineering judgment and time as possible while attaining acceptable and informative results that are useful for decision making. Its main features are custom crossover and mutation operators specific for water distribution network optimization tasks. A simple postprocessing greedy algorithm to locally refine pipe replacements is introduced as a means of complementing the evolutionary approach.

Calibration Transfer Between a Bench Scanning and a Submersible Diode Array Spectrophotometer for In Situ Wastewater Quality Monitoring in Sewer Systems

Online monitoring programs based on spectroscopy have a high application potential for the detection of hazardous wastewater discharges in sewer systems. Wastewater hydraulics poses a challenge for in situ spectroscopy, especially when the system includes storm water connections leading to rapid changes in water depth, velocity, and in the water quality matrix. Thus, there is a need to optimize and fix the location of in situ instruments, limiting their availability for calibration. In this context, the development of calibration models on bench spectrophotometers to estimate wastewater quality parameters from spectra acquired with in situ instruments could be very useful. However, spectra contain information not only from the samples, but also from the spectrophotometer generally invalidating this approach. The use of calibration transfer methods is a promising solution to this problem. In this study, calibration models were developed using interval partial least squares (iPLS), for the estimation of total suspended solids (TSS) and chemical oxygen demand (COD) in sewage from Ultraviolet-visible spectra acquired in a bench scanning spectrophotometer. The feasibility of calibration transfer to a submersible, diode array equipment, to be subsequently operated in situ, was assessed using three procedures: slope and bias correction (SBC); single wavelength standardization (SWS) on mean spectra; and local centering (LC). The results showed that SBC was the most adequate for the available data, adding insignificant error to the base model estimates. Single wavelength standardization was a close second best, potentially more robust, and independent of the base iPLS model. Local centering was shown to be inadequate for the samples and instruments used.

Hydrogen sulfide gas emission under turbulent conditions - an experimental approach for free-fall drops.

Odor nuisance and sulfide corrosion in sewers carrying septic wastewater are accelerated at points of turbulence such as drops in manholes, but accurate methods or empirical expressions to evaluate the gas stripping rate at those particular sites are still missing. With the aim of improving the current knowledge on the influence of free-fall drops on the release of hydrogen sulfide gas, an experimental set-up was built allowing different free-fall drops heights and flows. Three types of experiments were carried out: reaeration tests without sulfide; sulfide oxidation tests; and hydrogen sulfide release tests. With the increase of the free-fall drop height or of the flow, a higher rate of air-to-water mass oxygen transfer was observed. Results regarding sulfide oxidation tests with reaeration through the free-fall have shown that the oxidation rate was correlated with flow. In the hydrogen sulfide release tests, the maximum concentration in the atmosphere reached 500 ppm. Results also showed that increasing the flow rate decreased the time at which the maximum concentrations in the atmosphere were observed.

Urban sanitation technology decision-making in developing countries: a critical analysis of process guides

Planning for urban sanitation in developing contexts is one of the major development challenges of this century. Particularly, the relevance of a broad perspective in sanitation decision-making processes has been increasingly discussed. One possible contribution to achieve comprehensive decisions is through the use of planning guidelines, also called process guides. The present work first identified categories of relevant decision elements, namely: (a) the multi-sectoral approach, (b) the multiplicity of sustainable dimensions, (c) the system analysis perspective and (d) the co-existence of planning scales. Then, for each category, a comparative analysis of urban sanitation process guides was conducted with a focus on technology decision-making. It was found that the importance of considering those categories is increasingly reflected in process guides, although not always in a detailed supportive way. Recommendations are provided to increase the added value of process guides regarding technology selection, as well as, to better integrate them into urban planning.