K. Demyk

Change in the chemical composition of infalling gas forming a disk around a protostar.

IRASu200904368+2557 is a solar-type (low-mass) protostar embedded in a protostellar core (L1527) in the Taurus molecular cloud, which is only 140 parsecs away from Earth, making it the closest large star-forming region. The protostellar envelope has a flattened shape with a diameter of a thousand astronomical units (1u2009au is the distance from Earth to the Sun), and is infalling and rotating. It also has a protostellar disk with a radius of 90u2009au (ref. 6), from which a planetary system is expected to form. The interstellar gas, mainly consisting of hydrogen molecules, undergoes a change in density of about three orders of magnitude as it collapses from the envelope into the disk, while being heated from 10u2009kelvin to over 100u2009kelvin in the mid-plane, but it has hitherto not been possible to explore changes in chemical composition associated with this collapse. Here we report that the unsaturated hydrocarbon molecule cyclic-C3H2 resides in the infalling rotating envelope, whereas sulphur monoxide (SO) is enhanced in the transition zone at the radius of the centrifugal barrier (100u2009±u200920u2009au), which is the radius at which the kinetic energy of the infalling gas is converted to rotational energy. Such a drastic change in chemistry at the centrifugal barrier was not anticipated, but is probably caused by the discontinuous infalling motion at the centrifugal barrier and local heating processes there.

Low-temperature FIR and submillimetre mass absorption coefficient of interstellar silicate dust analogues

Context. Cold dust grains are responsible for the far-infrared and submillimetre (FIR/submm) emission observed by Herschel and Planck. Their thermal emission is usually expressed as a modified black body law in which the FIR/submm dust opacity, or mass absorption coefficient (MAC), is described by the MAC at a given wavelength κλ0 and the temperature- and wavelength-independent emissivity spectral index β. However, numerous data from previous space and balloon-borne missions and recently from Herschel and Planck show that the dust emission is not well understood, as revealed for example by the observed anti-correlation of β with the grain temperature. Aims. The aim of this work is to measure the optical properties of interstellar dust analogues at low temperatures to give astronomers the necessary data for interpreting FIR/submm observations such as those from the Herschel and Planck satellites. Methods. We synthesised, via sol-gel methods, analogues of interstellar amorphous silicate grains, rich in Mg and Ca, and having stoichiometry of olivine and pyroxene. The samples are characterised by various techniques to determine their composition, size, amorphisation degree. All the amorphous samples are annealed at 1100 ◦ C to study the crystallised materials for comparison. We measured the MAC of all the samples in the 2–25 μm range at room temperature and in the 100–1000/1500 μm range for grain temperatures varying from 300 to 10 K. Results. The experimental results show that, for all the amorphous samples, the grain MAC decreases when the grain temperature decreases and that the local spectral index, β, defined as the slope of the MAC curve, is anti-correlated with the grain temperature. These variations, which are not observed in the crystallised samples, are related to the amorphous nature of the samples. In addition, the spectral shape of the MAC is complex and cannot be described by a single spectral index over the 100–1500 μm range. At short wavelengths (λ ≤ 500/700 μm), β is in the range 1.6–2.1 for all grain temperature and grain composition. However, at longer wavelengths (λ ≥ 500/700 μm), β ≤ 2 for samples with a pyroxene stoichiometry and β ≥ 2 for samples with an olivine stoichiometry. Conclusions. The dust properties in the FIR/submm domain and at low temperature are more complicated than expected. The simplifying asymptotic expression based on a single temperature- and wavelength-independent spectral index used by astronomers is not appropriate to describe the dust MAC, hence the dust emission, and may induce significant errors on the derived parameters, such as the dust mass and the dust physical and chemical properties. Instead, dust emission models should use the dust MAC as a function of wavelength and temperature.

IR spectroscopic study of olivine, enstatite and diopside irradiated with low energy H + and He + ions

In this article we investigate the interaction of silicate grains with light atoms ionized and accelerated during the propagation of shock waves in the diffuse interstellar medium (ISM). Such an interaction which is equivalent to the irradiation of the grains with accelerated ions, is a potentially important process for silicate grain evolution in the ISM. We present the results of irradiation experiments aimed at simulating this process. The same crystalline silicates as those identified around evolved stars before their injection in the ISM, forsterite, enstatite and diopside, were irradiated with light ions (H + ,H e + )a t low energies (10-50 keV). The IR spectroscopic characteristics of the samples were analyzed before and after the irradiation in the 2-35 µm range allowing us to study the structural modifications in the irradiated minerals. The experiments show that low energy H + (10 keV) and He + (≤50 keV) ions efficiently amorphize crystalline silicates with fluence ≤10 18 ions/cm 2 .S ince these experimental conditions are compatible with interstellar environments, the interaction of grains with high velocity shock waves may be responsible for the absence of crystalline silicates in the ISM. The comparison of the IR spectra of the irradiated silicates with observations of the Galactic Center is presented. This comparison calls into question the classical assignment of the interstellar amorphous silicate bands.

Deuterated water in the solar-type protostars NGC 1333 IRAS 4A and IRAS 4B

Aims. The aim of this paper is to study deuterated water in the solar-type protostars NGC1333 IRAS4A and IRAS4B, compare their HDO abundance distribution with other star-forming regions and constrain their HDO/H2O ratios. Methods. Using the Herschel/HIFI instrument as well as ground-based telescopes, we observed several HDO lines covering a large excitation range (Eup/k=22-168 K) towards these protostars and an outflow position. Non-LTE radiative transfer codes were then used to determine the HDO abundance profiles in these sources. Results. The HDO fundamental line profiles show a very broad component, tracing the molecular outflows, in addition to a narrower emission component as well as a narrow absorbing component. In the protostellar envelope of NGC1333 IRAS4A, the HDO inner (T>100 K) and outer (T<100 K) abundances with respect to H2 are estimated at 7.5x10^{-9} and 1.2x10^{-11} respectively, whereas, in NGC1333 IRAS4B, they are 1.0x10^{-8} and 1.2x10^{-10} respectively. Similarly to the low-mass protostar IRAS16293-2422, an absorbing outer layer with an enhanced abundance of deuterated water is required to reproduce the absorbing components seen in the fundamental lines at 465 and 894 GHz in both sources. This water-rich layer is probably extended enough to encompass the two sources as well as parts of the outflows. In the outflows emanating from NGC1333 IRAS4A, the HDO column density is estimated at about (2-4)x10^{13} cm^{-2}, leading to an abundance of about (0.7-1.9)x10^{-9}. An HDO/H2O ratio between 7x10^{-4} and 9x10^{-2} is derived in the outflows. In the warm inner regions of these two sources, we estimate the HDO/H2O ratios at about 1x10^{-4}-4x10^{-3}. This ratio seems higher (a few %) in the cold envelope of IRAS4A, whose possible origin is discussed in relation to formation processes of HDO and H2O.

Heavy water stratification in a low-mass protostar

Context. Despite the low elemental deuterium abundance in the Galaxy, enhanced molecular deuterium fractionation has been found in the environments of low-mass star-forming regions and, in particular, the Class 0 protostar IRAS 16293-2422. Aims: The key program Chemical HErschel Surveys of Star forming regions (CHESS) aims at studying the molecular complexity of the interstellar medium. The high sensitivity and spectral resolution of the Herschel/HIFI (Heterodyne Instrument for Far-Infrared) instrument provide a unique opportunity to observe the fundamental 11,1-00,0 transition of ortho-D2O at 607 GHz and the higher energy 21,2-10,1 transition of para-D2O at 898 GHz, both of which are inaccessible from the ground. Methods: The ortho-D2O transition at 607 GHz was previously detected. We present in this paper the first tentative detection for the para-D2O transition at 898 GHz. The spherical Monte Carlo radiative transfer code RATRAN was used to reproduce the observed line profiles of D2O with the same method that was used to reproduce the HDO and H218O line profiles in IRAS 16293-2422. Results: As for HDO, the absorption component seen on the D2O lines can only be reproduced by adding an external absorbing layer, possibly created by the photodesorption of the ices at the edges of the molecular cloud. The D2O column density is found to be about 2.5 × 1012 cm-2 in this added layer, leading to a D2O/H2O ratio of about 0.5%. At a 3σ uncertainty, upper limits of 0.03% and 0.2% are obtained for this ratio in the hot corino and the colder envelope of IRAS 16293-2422, respectively. Conclusions: The deuterium fractionation derived in our study suggests that the ices present in IRAS 16293-2422 formed on warm dust grains (~15-20 K) in dense (~104-5 × 104 cm-3) translucent clouds. These results allow us to address the earliest phases of star formation and the conditions in which ices form. Based on Herschel/HIFI observations. Herschel is an ESA space observatory with scientific instruments provided by European-led principal Investigator consortia and with important participation from NASA.

Galactic cold cores

Context. The Galactic Cold Cores project has carried out Herschel photometric observations of 116 fields where the Planck survey has found signs of cold dust emission. The fields contain sources in different environments and different phases of star formation. Previous studies have revealed variations in their dust submillimetre opacity. n nAims. The aim is to measure the value of dust opacity spectral index and to understand its variations spatially and with respect to other parameters, such as temperature, column density, and Galactic location. n nMethods. The dust opacity spectral index β and the dust colour temperature T are derived using Herschel and Planck data. The relation between β and T is examined for the whole sample and inside individual fields. n nResults. Based on IRAS and Planck data, the fields are characterised by a median colour temperature of 16.1 K and a median opacity spectral index of β = 1.84. The values are not correlated with Galactic longitude. We observe a clear T–β anti-correlation. In Herschel observations, constrained at lower resolution by Planck data, the variations follow the column density structure and β_(FIR) can rise to ~2.2 in individual clumps. The highest values are found in starless clumps. The Planck 217 GHz band shows a systematic excess that is not restricted to cold clumps and is thus consistent with a general flattening of the dust emission spectrum at millimetre wavelengths. When fitted separately below and above 700 μm, the median spectral index values are β_(FIR) ~ 1.91 and β(mm) ~ 1.66. nConclusions. The spectral index changes as a function of column density and wavelength. The comparison of different data sets and the examination of possible error sources show that our results are robust. However, β variations are partly masked by temperature gradients and the changes in the intrinsic grain properties may be even greater.

TIMASSS: the IRAS16293-2422 millimeter and submillimeter spectral survey: tentative detection of deuterated methyl formate (DCOOCH3)

Context. High deuterium fractionation is observed in various types of environments such as prestellar cores, hot cores, and hot corinos. It has proven to be an efficient probe for studying the physical and chemical conditions of these environments. The study of the deuteration of different molecules helps us to understand their formation. This is especially interesting for complex molecules like methanol and bigger molecules for which it may allow differentiation of gas-phase and solid-state formation pathways. Aims. Methanol exhibits a high deuterium fractionation in hot corinos. Since CH 3 OH is thought to be a precursor of methyl formate we expect that deuterated methyl formate is produced in such environments. We searched for the singly-deuterated isotopologue of methyl formate, DCOOCH 3 , in IRAS 16293-2422, a hot corino well-known for its high degree of methanol deuteration. Methods. We used the IRAM/JCMT unbiased spectral survey of IRAS 16293-2422, which allowed us to search for the DCOOCH 3 rotational transitions within the survey spectral range (80-280 GHz, 328-366 GHz). The expected emission of deuterated methyl formate is modelled at LTE and compared with the observations. Results. We have tentatively detected DCOOCH 3 in the protostar IRAS 16293-2422. We assign eight lines detected in the IRAM survey to DCOOCH3. Three of these lines are affected by blending problems, and one is affected by calibration uncertainties; nevertheless, the LTE emission model is compatible with the observations. A simple LTE modelling of the two cores in IRAS 16293-2422, based on a previous interferometric study of HCOOCH 3 , allows us to estimate the amount of DCOOCH 3 in IRAS 16293-2422. Adopting an excitation temperature of 100 K and a source size of 2and 15 for the A and B cores, respectively, we find that N A,DCOOCH3 = N B,DCOOCH3 ∼6 × 10 14 cm ―2 . The derived deuterium fractionation is ∼ 15%, consistent with values for other deuterated species in this source and much greater than expected from the deuterium cosmic abundance. Conclusions. If its tentative detection is confirmed, DCOOCH 3 should now be considered in theoretical models that study complex molecule formation and their deuteration mechanisms. Experimental work is also needed to investigate the different chemical routes leading to the formation of deuterated methyl formate.

Modeling and predicting the shape of the far-infrared to submillimeter emission in ultra-compact HII regions and cold clumps

Context. Dust properties are very likely affected by the environment in which dust grains evolve. For instance, some analyses of cold clumps (7-17 K) indicate that the aggregation process is favored in dense environments. However, studying warm (30-40 K) dust emission at long wavelength (λ > 300 µm) has been limited because it is difficult to combine far infrared-to-millimeter (FIR-to-mm) spectral coverage and high angular resolution for observations of warm dust grains. nAims. Using Herschel data from 70 to 500µm, which are part of the Herschel infrared Galactic (Hi-GAL) survey combined with 1.1 mm data from the Bolocam Galactic Plane Survey (BGPS), we compared emission in two types of environments: ultracompact HII (UCHII) regions, and cold molecular clumps (denoted as cold clumps). With this comparison we tested dust emission models in the FIR-to-mm domain that reproduce emission in the diffuse medium, in these two environments (UCHII regions and cold clumps). We also investigated their ability to predict the dust emission in our Galaxy. nMethods. We determined the emission spectra in twelve UCHII regions and twelve cold clumps, and derived the dust temperature (T) using the recent two-level system (TLS) model with three sets of parameters and the so-called T-β (temperature-dust emissivity index) phenomenological models, with β set to 1.5, 2 and 2.5. nResults. We tested the applicability of the TLS model in warm regions for the first time. This analysis indicates distinct trends in the dust emission between cold and warm environments that are visible through changes in the dust emissivity index. However, with the use of standard parameters, the TLS model is able to reproduce the spectral behavior observed in cold and warm regions, from the change of the dust temperature alone, whereas a T-β model requires β to be known.

CHESS, Chemical Herschel surveys of star forming regions:Peering into the protostellar shock L1157-B1

The outflow driven by the low-mass class 0 protostar L1157 is the prototype of the so-called chemically active outflows. The bright bowshock B1 in the southern outflow lobe is a privileged testbed of magneto-hydrodynamical (MHD) shock models, for which dynamical and chemical processes are strongly interdependent. We present the first results of the unbiased spectral survey of the L1157-B1 bowshock, obtained in the framework of the key program Chemical Herschel Surveys of Star Forming Regions (CHESS). The main aim is to trace the warm and chemically enriched gas and to infer the excitation conditions in the shock region. The CO 5-4 and H2O lines have been detected at high-spectral resolution in the unbiased spectral survey of the HIFI-Band 1b spectral window (555-636 GHz), presented by Codella et al. in this volume. Complementary ground-based observations in the submm window help establish the origin of the emission detected in the main-beam of HIFI, and the physical conditions in the shock.}{Both lines exhibit broad wings, which extend to velocities much higher than reported up to now. We find that the molecular emission arises from two regions with distinct physical conditions: an extended, warm (100K), dense (3e5 cm-3) component at low-velocity, which dominates the water line flux in Band~1; a secondary component in a small region of B1 (a few arcsec) associated with high-velocity, hot (> 400 K) gas of moderate density ((1.0-3.0)e4 cm-3), which appears to dominate the flux of the water line at 179mu observed with PACS. The water abundance is enhanced by two orders of magnitude between the low- and the high-velocity component, from 8e-7 up to 8e-5. The properties of the high-velocity component agree well with the predictions of steady-state C-shock models.Context. The outflow driven by the low-mass class 0 protostar L1157 is the prototype of the so-called chemically active outflows. The bright bowshock B1 in the southern outflow lobe is a privileged testbed of magneto-hydrodynamical (MHD) shock models, for which dynamical and chemical processes are strongly interdependent. Aims: We present the first results of the unbiased spectral survey of the L1157-B1 bowshock, obtained in the framework of the key program “Chemical HErschel Surveys of star forming regions” (CHESS). The main aim is to trace the warm and chemically enriched gas and to infer the excitation conditions in the shock region. Methods: The CO 5-4 and o-H2O 110-101 lines have been detected at high-spectral resolution in the unbiased spectral survey of the HIFI-band 1b spectral window (555-636 GHz), presented by Codella et al. in this volume. Complementary ground-based observations in the submm window help establish the origin of the emission detected in the main-beam of HIFI and the physical conditions in the shock. Results: Both lines exhibit broad wings, which extend to velocities much higher than reported up to now. We find that the molecular emission arises from two regions with distinct physical conditions : an extended, warm (100 K), dense (3 × 105 cm-3) component at low-velocity, which dominates the water line flux in Band 1; a secondary component in a small region of B1 (a few arcsec) associated with high-velocity, hot (>400 K) gas of moderate density ((1.0-3.0) × 104 cm-3), which appears to dominate the flux of the water line at 179μm observed with PACS. The water abundance is enhanced by two orders of magnitude between the low- and the high-velocity component, from 8 × 10-7 up to 8 × 10-5. The properties of the high-velocity component agree well with the predictions of steady-state C-shock models. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.

The CHESS spectral survey of star forming regions: peering into the protostellar shock L1157-B1. I. Shock chemical complexity [Letter]

We present the first results of the unbiased survey of the L1157-B1 bow shock, obtained with HIFI in the framework of the key program Chemical Herschel surveys of star forming regions (CHESS). The L1157 outflow is driven by a low-mass Class 0 protostar and is considered the prototype of the so-called chemically active outflows. The bright blue-shifted bow shock B1 is the ideal laboratory for studying the link between the hot (around 1000-2000 K) component traced by H2 IR-emission and the cold (around 10-20 K) swept-up material. The main aim is to trace the warm gas chemically enriched by the passage of a shock and to infer the excitation conditions in L1157-B1. A total of 27 lines are identified in the 555-636 GHz region, down to an average 3 sigma level of 30 mK. The emission is dominated by CO(5-4) and H2O(110-101) transitions, as discussed by Lefloch et al. (2010). Here we report on the identification of lines from NH3, H2CO, CH3OH, CS, HCN, and HCO+. The comparison between the profiles produced by molecules released from dust mantles (NH3, H2CO, CH3OH) and that of H2O is consistent with a scenario in which water is also formed in the gas-phase in high-temperature regions where sputtering or grain-grain collisions are not efficient. The high excitation range of the observed tracers allows us to infer, for the first time for these species, the existence of a warm (> 200 K) gas component coexisting in the B1 bow structure with the cold and hot gas detected from ground.We present the first results of the unbiased survey of the L1157-B1 bow shock, obtained with HIFI in the framework of the key program Chemical HErschel Survey of Star forming regions (CHESS). The L1157 outflow is driven by a low-mass Class 0 protostar and is considered the prototype of the so-called chemically active outflows. The bright blue-shifted bow shock B1 is the ideal laboratory for studying the link between the hot (∼1000‐ 2000 K) component traced by H2 IR-emission and the cold (∼10‐20 K) swept-up material. The main aim is to trace the warm gas chemically enriched by the passage of a shock and to infer the excitation conditions in L1157-B1. A total of 27 lines are identified in the 555‐636 GHz region, down to an average 3σ level of 30 mK. The emission is dominated by CO(5‐4) and H2O(110‐101) transitions, as discussed by Lefloch et al. in this volume. Here we report on the identification of lines from NH3 ,H 2CO, CH3OH, CS, HCN, and HCO + . The comparison between the profiles produced by molecules released from dust mantles (NH3 ,H 2CO, CH3OH) and that of H2O is consistent with a scenario in which water is also formed in the gas-phase in high-temperature regions where sputtering or grain-grain collisions are not efficient. The high excitation range of the observed tracers allows us to infer, for the first time for these species, the existence of a warm (≥200 K) gas component coexisting in the B1 bow structure with the cold and hot gas detected from ground.