Katarzyna Szopka

Mercury accumulation in the surface layers of mountain soils: A case study from the Karkonosze Mountains, Poland

The study was aimed to examine total concentrations and pools of Hg in surface layers of soils in the Karkonosze Mountains, dependent on soil properties and site locality. Soil samples were collected from a litter layer and the layers 0-10 cm and 10-20 cm, at 68 sites belonging to the net of a monitoring system, in two separate areas, and in three altitudinal zones: below 900 m, 900-1100 m, and over 1100 m. Air-borne pollution was the major source of mercury in soils. Hg has accumulated mainly in the litter (where its concentrations were the highest), and in the layer 0-10 cm. Hg concentrations in all samples were in the range 0.04-0.97 mg kg(-1), with mean values 0.38, 0.28, and 0.14 mg kg(-1) for litter and the layers 0-10 cm and 10-20 cm, respectively. The highest Hg concentrations in the litter layer were found in the intermediate altitudinal zone, whereas Hg concentrations in the layer 0-10 cm increased with increasing altitude. Soil quality standard for protected areas (0.50 mg kg(-1)) was exceeded in a few sites. The pools of Hg accumulated in soils were in the range: 0.8-84.8 mg m(-2), with a mean value of 16.5 mg m(-2), and they correlated strongly with the pools of stored organic matter.

Copper, Zinc, and Lead Fractions in Soils Long-Term Irrigated with Municipal Wastewater

Long-term irrigation with municipal wastewater may lead, even in spite of intense farming, to an accumulation of organic matter, nutrient elements, and trace metals in soils. Excessive increases of heavy metals may pose a potential risk to the food chain and provoke restrictions for the further cultivation of sensitive crops. Copper (Cu), zinc (Zn), and lead (Pb) forms in soils under long-term irrigation (for 100–120 years) with treated wastewater of Wroclaw were investigated by using selective seven-step sequential extraction (procedure of Zeien-Bruemmer) for partitioning the metals into operationally defined fractions, likely to be released in solution under various environmental conditions. The largest fraction of Cu, Pb, and particularly Zn in nonirrigated (control) soils was strongly bound in a residual form, while the percentage of exchangeable and the most labile fractions were negligible. Total concentration of metals in irrigated soils was elevated, and significant redistribution of metals among phases was observed. Percentages of residual fraction of Cu and Pb were no more than 25% (Zn < 40%), while significantly increased contribution of fractions occluded on iron (Fe) oxides and organically bound Cu. Exchangeable and readily mobile forms of Zn are predominant zinc fractions in soils irrigated with wastewater.

The pools of soil organic carbon accumulated in the surface layers of forest soils in the Karkonosze Mountains, SW Poland

Abstract Differentiation of soil organic carbon (SOC) concentrations and pools in topsoil horizons of forest soils in the Karkonosze Mountains was examined in relation to environmental and human-induced factors, with special focus on altitudinal gradient, related climatic conditions, and a zonality of vegetation. The samples were collected from the forest litter and soil layers 0–10 cm and 10–20 cm, in 621 plots arranged in a regular network of monitoring established in the Karkonosze National Park. The concentrations of SOC were determined in laboratory and used for calculation of SOC pools. Four elevation zones were distinguished for analysis: 500–750 m, 750–1000 m, 1000–1250 m, and >1250 m. The concentrations of SOC in forest litter (38.3–44.1%) showed an insignificant increasing trend with altitude. The concentrations of SOC in the layers 0–10 cm and 10–20 cm, were in a very broad range 0.27–47.6%, thus indicating a high differentiation, and also tended to insignificantly increase along with altitude. The largest share of accumulated SOC pools was proved to be present in the layer 0–10 cm, except for the highest zone >1250 m in which forest litter contains slightly larger amounts of SOC. The pools of SOC accumulated in the 20 cm thick topsoil and forest litter turned out to vary considerably (3.6–58.2 kg·m−2), but the mean values and medians in particular elevation zones fall in a narrow range 10.5–11.9 kg·m−2, close to the values reported from the Alps. The lack of statistical significance of reported tendencies was explained by a monitoring sites-oriented random soil sampling, i.e. in forest stands of various age, species-composition and degradation degree.

Tailings Impoundments of Polish Copper Mining Industry—Environmental Effects, Risk Assessment and Reclamation

Abstract KGHM Polska Miedź, one of the major world copper mining and processing companies, produces c.30 million m3 of tailings yearly, stored currently in the facility Żelazny Most, the largest European tailings impoundment. Formerly, tailings were disposed in six smaller impoundments that operated in two parts of the Polish Copper Basin: the Old District and LGOM. This chapter presents the main impacts exerted by these facilities on the environment, including a changed landscape, hydrotechnical hazard associated with possible dam failure, adverse effects on natural waters and soils caused by seepage of technological water from the impoundments and pipelines, dust dispersion and associated air, soil and crop contamination, and water erosion on dam slopes. Contrasting effects obtained hitherto in reclamation and revegetation of impoundments are described in the light of legislative, technological and biological factors. The most successful technologies and crucial impediments of revegetation are presented and discussed.