R. Khedir

Design and Fabrication of Teflon-Coated Tungsten Nanorods for Tunable Hydrophobicity

The nature of water interaction with tungsten nanorods (WNRs) fabricated by the glancing-angle deposition technique (GLAD)-using RF magnetron sputtering under various Ar pressures and substrate tilting angles and then subsequent coating with Teflon-has been studied and reported. Such nanostructured surfaces have shown strong water repellency properties with apparent water contact angles (AWCA) of as high as 160°, which were found to depend strongly upon the fabrication conditions. Variations in Ar pressure and the substrate tilting angle resulted in the generation of WNRs with different surface roughness and porosity properties. A theoretical model has been proposed to predict the observed high AWCAs measured at the nanostructure interfaces. The unique pyramidal tip geometry of WNRs generated at low Ar pressure with a high oblique angle reduced the solid fraction at the water interface, explaining the high AWCA measured on such surfaces. It was also found that the top geometrical morphologies controlling the total solid fraction of the WNRs are dependent upon and controlled by both the Ar pressure and substrate tilting angle. The water repellency of the tungsten nanorods with contact angles as high as 160° suggests that these coatings have enormous potential for robust superhydrophobic and anti-icing applications in harsh environments.

Controlled growth of self-organized hexagonal arrays of metallic nanorods using template-assisted glancing angle deposition for superhydrophobic applications.

The fabrication of controlled, self-organized, highly ordered tungsten and aluminum nanorods was accomplished via the aluminum lattice template-assisted glancing angle sputtering technique. The typical growth mechanism of traditional glancing angle deposition technique was biased by self-organized aluminum lattice seeds resulting in superior quality nanorods in terms of size control, distribution, and long range order. The morphology, size, and distribution of the nanorods were highly controlled by the characteristics of the template seeds indicating the ability to obtain metallic nanorods with tunable distributions and morphologies that can be grown to suit a particular application. Water wettability of hexagonally arranged tungsten and aluminum nanorods was studied after modifying their surface with 5 nm of Teflon AF 2400, as an example, to exhibit the significance of such a controlled growth of metallic nanorods. This facile and scalable approach to generate nano seeds to guide GLAD, with nano seeds fabricated by anodic oxidization of aluminum followed by chemical etching, for the growth of highly ordered nanorods could have significant impact in a wide range of applications such as anti-icing coating, sensors, super capacitors, and solar cells.

Subcooled Flow Boiling Over Microstructured Plates In Rectangular Minichannels

ABSTRACT Microstructures offer enhancements in boiling heat transfer by increasing bubble departure frequency, active nucleation site density, critical cavity size, and surface area. Integration of microstructures to surfaces alters significant surface parameters such as porosity of the microstructured plates, contact angle, and configuration of microstructures on the surface, which all affect boiling heat transfer. The goal of this study is to investigate boiling heat transfer on different microstructured plates and the effect of various microscale surface morphologies on boiling heat transfer. The microstructured surfaces were formed on aluminum alloy 2024 sheets with the use of a simple and environmentally friendly technique of random mechanical sanding (grits of #36, #60, #400, and #1,000). Distilled water was pumped using a micro gear pump to the rectangular minichannel test section at flow rates of 100, 180, and 290 ml/min, which correspond to mass fluxes of 5.46, 10.58, and 16.15 kg/m2.s, respectively. It was observed that surfaces with low grit (grit #36) showed no considerable enhancement, whereas the use of higher grit counts considerably enhanced boiling heat transfer up to a critical grit count. The results were supported by the images from the performed visualization of flow boiling.

Nucleate boiling heat transfer enhancement using nanostructured al-alloy plates

Bubble departure frequency and active nucleation site density are two main factors that affect the nucleate boiling heat transfer. The potential enhancement of boiling heat transfer can be accomplished by surface modification. This treatment can be realized with changing parameters such as porosity, tilting angle and cavity radius. In this study, effects of different nanostructured Aluminum-Alloy (Al-Alloy) 2024 sheets on subcooled boiling heat transfer are investigated. A simple and environmentally friendly technique is used in order to produce these plates that are immersed into boiling deionized water for 20, 60 and 120 minutes. To examine boiling heat transfer characteristics, nanostructured plates are placed inside a rectangular channel. The channel is heated through four cartridge heaters connected to a DC power supply while deionized water is pumped inside using a micro gear pump at constant mass fluxes of 50 kg/m2s, 75 kg/m2s and 125 kg/m2s. It was found that an increase in nano-structure height leads to higher boiling heat transfer coefficients. Furthermore, a high speed camera system was used to investigate flow patterns in the microchannel. Visualization results indicated that bubbles movde faster the nano-structure height increased.Copyright