Luca Aldega

Tectonic burial and 'young' (< 10 Ma) exhumation in the southern Apennines fold and thrust belt (Italy)

In the southern Apennines fold-and-thrust belt, thermal indicators record exhumation of sedimentary units from depths locally in excess of 5 km. The thrust belt is made of allochthonous sedimentary units that overlie a 6–8-km-thick, carbonate footwall succession. The latter, continuous with the foreland Apulian Platform, is deformed by reverse faults involving the underlying basement. Therefore, a switch from thin-skinned to thick-skinned thrusting occurred as the Apulian Platform carbonates—and the underlying thick continental lithosphere—were deformed during the latest shortening stages. Apatite fission track data, showing cooling ages ranging between 9.2 ± 1.0 and 1.5 ± 0.8 Ma, indicate that exhumation marks these late tectonic stages, probably initiating with the buttressing of the allochthonous wedge against the western margin of the Apulian Platform. Pliocene-Pleistocene foreland advancing of the allochthonous units exceeds the total amount of slip that, based on cross-section balancing and restoration, could be transferred to the base of the allochthon from the underlying thick-skinned structures. This suggests that emplacement of the allochthon above the western portion of the Apulian Platform carbonates was followed by gravitational readjustments within the allochthonous wedge, coeval—and partly associated with—thick-skinned shortening at depth. The related denudation processes are interpreted to have played a primary role in tectonic exhumation.

Shallow burial and exhumation of the Peloritani Mountains (NE Sicily, Italy): Insight from paleothermal and structural indicators

We used vitrinite refl ectance and mixedlayered clay minerals to investigate levels of diagenesis of the Oligocene-Miocene basin developed on the nappes of the Alpine orogen exposed in the Peloritani Mountains (NE Sicily). Paleothermal indicators were integrated with stratigraphic and structural analyses and published apatite fi ssion-track and (U-Th-Sm)/He ages to defi ne the late evolutionary stages of the Peloritani Mountains. This multimethod approach allowed us to reconstruct the paleogeothermal gradient of the basin in Oligocene-Miocene times, to constrain its burial evolution, and discriminate between areas where it has been affected by sedimentary and/or tectonic load. In the southern area of the basin, organic and inorganic thermal parameters increase as function of depth, suggesting that their evolution was ruled by sedimentary burial. They record a decrease in paleogeothermal gradient values marking the evolution of the basin from a forearc to a thrust-top setting during the convergence-collision process between the Calabria-Peloritani Arc and the African plate. On the other hand, in the northern edge of the basin, vitrinite refl ectance values (0.46%‐0.58%) indicate that the thermal evolution of this area was controlled by tectonic burial related to late Langhian‐early Serravallian out-of-sequence thrust tec tonics. The tectonic overburden has been totally removed by extensional tectonics and/or erosion since the late Miocene. The short time span at maximum temperature (<2 m.y.) elapsing between thrust stack emplacement and the beginning of tectonic overburden removal has allowed only vitrinite refl ectance and thermochronological indicators to record this compressive reactivation.

Correlation of Diagenetic Data from Organic and Inorganic Studies in the Apenninic‐Maghrebian Fold‐and‐Thrust Belt: A Case Study from Eastern Sicily

Temperature‐dependent clay mineral assemblages and vitrinite reflectance data have been used to investigate levels of diagenesis from the Apenninic‐Maghrebian fold‐and‐thrust belt in eastern Sicily at the footwall of the Peloritani‐Calabride Arc. Data are from units sampled along a regional transect between the Nebrodi Mountains to the north and Mount Judica to the south. These units developed in very different tectonic settings from those of oceanic to passive continental margin domains deformed during the Cenozoic mountain building and related active margin deposits. The integration of organic and inorganic thermal indicators allowed us to distinguish among different tectonic settings, with thermal maturity generally decreasing from hinterland to foreland as a result of progressively less severe thermal evolution and/or tectonic loading during the mountain building. Specifically, the highest vitrinite reflectance (VRo%) values (ca. 0.60%–0.75%) and percentages of illite layers in illite‐smectite (I‐S; 60%–80%) are found in trench‐involved and accreted passive margin units. Lower VRo% values (0.20%–0.47%) and percentages of illite layers in I‐S (30%–60%) are found in thrust‐top and foredeep basin deposits and far‐traveled Sicilide units that have escaped involvement in trench evolution. Furthermore, either sedimentary or long‐lived tectonic burial (at least more than 5 m.yr.) seem to have affected levels of diagenesis of the studied successions. The correlation between organic and inorganic thermal indicators is satisfactory for most of the samples derived from hemipelagic and siliciclastic deposits, whereas it is poor for some proximal siliciclastics. A tentative calculation of paleotemperatures is also proposed for the studied tectonostratigraphic units.

Sedimentary and tectonic burial evolution of the Northern Apennines in the Modena-Bologna area: constraints from combined stratigraphic, structural, organic matter and clay mineral data of Neogene thrust-top basins

Vitrinite reflectance and mineralogical data from 55 samples collected from the Mt. Cervarola Sandstones and the Granaglione Sandstones (thrust-top basin Cervarola Successions) testify the severe thermal maturity of the present-day outcropping successions. This is due to the deep tectonic burial the successions underwent during Miocene chain building. Lower levels of thermal maturity are recorded in the Mt. Cervarola Sandstones. They form a thick upper thrust sheet (Ro% ranging between 1.0 and 1.2%; I% in I/S mixed layers ranging between 80 and 85%). Higher levels of thermal maturity characterise the structurally lower thrust sheets, made up mainly of Granaglione Sandstones (Ro% ranging between 1.2 and 1.5%; and I% in I/S mixed layers between 85 and 90%). Maturity generally decreases from hinterland to foreland. Integration of Ro% and I% in I/S data with published low-temperature indicators allowed to reconstruct a maximum tectonic burial ranging between ~3.5 on the upper thrust sheet and ~5 km on the lower ones. Burial was mainly due to the early emplacement of the Ligurian Unit and the Modino Unit on top of the studied units and to later piggy-back thrusting of the Mt. Cervarola Sandstones onto the Granaglione Sandstones.

Structural evolution of the sedimentary accretionary wedge of the alpine system in Eastern Sicily: Thermal and thermochronological constraints

Temperature-dependent clay-mineral assemblages, vitrinite reflectance, and apatite fission-track data have been used to investigate levels of diagenesis and time of exhumation of the double-verging Sicilide-Antisicilide accretion-ary wedge in Eastern Sicily. The integration of organic and inorganic thermal indicators allowed us to distinguish parts of the accre-tionary wedge with different thermal signature and evolution. We recognize a warmer core made up of the Mount Soro and Troina units and two colder rims (Antisicilide and far-traveled Sicilide units). The Antisicilide unit was thrust back toward the hinterland, and the far-traveled Sicilide units were gravity-driven toward the Hyblean Plateau. In detail, the highest percentages of vitrinite reflectance (VR o ) values (0.60%–0.96%) and percentages of illite layers in illite-smectite (I-S; 60%–85%) are found in the Mount Soro and Troina units. Apatite fission-track data, together with the paleotemperature estimates from vitrinite-reflectance data and clay-mineral–based geothermometers, indicate that fission tracks were partially to totally annealed during wedge accretion and that the subsequent exhumation occurred mainly in Burdigalian times. Low VR o values (0.35%–0.50%) and percentages of illite layers in I-S (30%–60%) occur in early thrust-top deposits (Reitano Flysch) that unconformably overlie the Sicilide Complex, as well as the far-traveled Sicilide and Antisicilide units. Apatite fission-track data for the Antisicilide unit confirm low paleo-temperature values. Thus the far-traveled Sicilide and Antisicilide units were probably at higher structural levels in the original accretionary prism and were remobilized since late Aquitanian–Burdigalian times.

Clay mineral assemblages and vitrinite reflectance in the laga basin (Central Apennines, Italy) : What do they record?

Temperature-dependent clay mineral assemblages and vitrinite reflectance data have been used to investigate levels of diagenesis from the Messinian Laga Basin in the Central Apennines developed at the footwall of the Sibillini Mts. and the Gran Sasso Massif. Data are from stratigraphic units forming the main siliciclastic basin fill up to Middle Messinian gypsum-arenites and its pre-orogenic substratum. Specifically, the largest Rom% values and percentages of illite layers in illite-smectie (I-S) are found in the basin depocenter and at the footwall of the main carbonate thrust sheets. Smaller Rom% values, and percentage of illite layers in I-S characterize less subsided sectors surrounding the depocenter.The X-ray diffraction data were treated using decomposition methods and the peaks identified were rationalized in terms of discrete and/or mixed-layer phases. Complex clay mineral assemblages were found in the Laga Fm. including three sub-populations of illitic material corresponding to authigenic and detrital components. I-S mixed layers record the maximum paleotemperature the Laga Fm. experienced, which is directly related to its burial history. Kübler index (KI) data, however, suggest higher temperatures related to detrital K-micas inherited from the uplift of the Alpine-Apennines chain.A tentative calculation of paleotemperatures from selected data of organic and inorganic parameters is also proposed and compared with recent sedimentological, stratigraphic and structural data. We conclude that the Laga Basin fill never experienced temperatures of >100–110°C, generally due to variable sedimentary loading, whereas localized anomalous heating is due to the effect of the tectonic emplacement and subsequent local erosion of the Sibillini and Gran Sasso thrust sheets.

Fluid flow within the damage zone of the Boccheggiano extensional fault (Larderello–Travale geothermal field, central Italy): structures, alteration and implications for hydrothermal mineralization in extensional settings

The Neogene extensional province of southern Tuscany in central Italy provides an outstanding example of fossil and active structurally controlled fluid flow and epithermal ore mineralization associated with post-orogenic silicic magmatism. Characterization of the hydrodynamic regime leading to the genesis of the polysulphide deposit (known as Filone di Boccheggiano) hosted within the damage zone of the Boccheggiano Fault is a key target to assess modes of fossil hydrothermal fluid circulation in the region and, more generally, to provide inferences on fault-controlled hydrothermal fluid flow in extensional settings. We provide a detailed description of the fault zone architecture and alteration/mineralization associated with the Boccheggiano ore deposit and report the results of fluid inclusion and stable oxygen isotope studies. This investigation shows that the Boccheggiano ore consists of an adularia/illite-type epithermal deposit and that sulphide ore deposition was controlled by channelling of hydrothermal fluids of dominantly meteoric origin within the highly anisotropic permeability structure of the Boccheggiano Fault. The low permeability structure of the fault core compartmentalized the fluid outflow preventing substantial cross-fault flow, with focused fluid flow occurring at the hangingwall of the fault controlled by fracture permeability. Fluid inclusion characteristics indicate that ore minerals were deposited between 280° and 350°C in the upper levels of the brittle extending crust (lithostatic pressure in the order of 0.1 GPa). Abundant vapour-rich inclusions in ore-stage quartz are consistent with fluid immiscibility and boiling, and quartz ore vein textures suggest that mineralization in the Boccheggiano ore deposit occurred during cyclic fluid flow in a deformation regime regulated by transient and fluctuating fluid pressure conditions. Results from this study (i) predict a strongly anisotropic permeability structure of the fault damage zone during crustal extension, and (ii) indicate the rate of secondary (structural) permeability creation and maintenance by active deformation in the hangingwall of extensional faults as the major factor leading to effective hydraulic transmissivity in extensional terranes. These features intimately link ore-grade mineralization in extensional settings to telescoping of hydrothermal flow along the hangingwall block(s) of major extensional fault zones.

A way to hydrothermal paroxysm, Colli Albani volcano, Italy

The main issue addressed in this work is the process leading to fluid subsurface entrapment and pressure increase up to hydrofracturing and, possibly, to paroxysm in a hydrothermal setting, in order to envisage such processes and mitigate their effects in the volcanically active study area and elsewhere. A field and laboratory multidisciplinary approach is used in the fossil (late Pleistocene) portion of an active hydrothermal system (Colli Albani volcano, Rome, Italy). In this area, sulfate and sulfide mineralizations and strongly altered ignimbrites are exposed. The alteration acme occurs on top of a buried normal fault, where abundant degassing is still active, and fades away in 2–3 km. Based on pervasive versus discrete alteration styles, mineral assemblages, and further evidence, proximal and distal alteration domains are recognized. Both domains underwent steam-heated advanced argillic alteration with likely temperatures up to ~400 °C in the proximal domain and less than 150 °C in the distal domain. The process of hydrothermal alteration progressively and severely depleted many elements from the most permeable rock units, whereas the lowest-permeable unit (Tufo Lionato) underwent fracture and porosity healing accompanied by both mass and volume gain. In the proximal domain, the advanced argillic hydrothermal alteration eventually formed a substantial barrier to fluids. The hydrothermal fluids accumulated in and below this barrier, which was then suddenly hydrofractured when heat-driven hydraulic pressure overcame the effective stress, thus possibly leading to hydrothermal paroxysm. The decompression associated with hydrofracturing enhanced gas exsolution and mineral precipitation from the entrapped overpressured fluids. Mineral precipitation contributed, in turn, to fracture healing and to reinitiation of a new cycle of hydrothermal fluid entrapment. The key preconditions for the occurrence of the inferred processes are the contrasting compositions of K-alkaline host rocks and acidic alteration fluids, as also previously documented in other similar settings elsewhere.

Reconstruction of maximum burial along the Northern Apennines thrust wedge (Italy) by indicators of thermal exposure and modeling

A new data set of temperature-dependent clay mineral parameters and vitrinite reflectance of the Tuscan successions in the Northern Apennines (Italy) displays decreasing levels of thermal maturity from hinterland to foreland, and abrupt changes parallel to the strike of the chain which are structurally controlled by northeast-southwest–trending faults (e.g., Marecchia valley lineament). To the southeast of the Marecchia valley lineament, paleothermal indicators show deep diagenetic conditions in the hinterland and early diagenetic conditions in the foreland (R o % ranges from 0.80% to 0.30%; illite content in mixed-layer illite-smectite [I-S] from 86% to 38%). To the northwest of the Marecchia valley lineament, in the hinterland, R o % is up to 0.95% and mixed-layer I-S have an illite content of ~87%–88%, both gradually decreasing toward the northeast (to R o % of 0.33%, and illite in I-S of 50%). Thermal models allowed us to constrain the geometry of the Miocene thrust wedge with special regard to the original thickness and distribution of its allochthonous uppermost structural unit (Ligurian unit) across northeast-southwest–trending tectonic lineaments. The thickness of the Ligurian unit ranges from 1 to 1.5 km to the south of the Marecchia valley lineament, to 3 km to the north-northwest. This tectonic lineament affected wedge geometry, amounts of tectonic transport, and thickness of the uppermost structural unit, and, possibly, Neogene–Quaternary levels of exhumation.

The signature and mechanics of earthquake ruptures along shallow creeping faults in poorly lithified sediments

Seismic slip episodically occurring along shallow creeping faults in poorly lithified sediments represents an unsolved paradox, largely due to our poor understanding of the mechanics governing creeping faults and the lack of documented geological evidence showing how coseismic rupturing overprints creep in near-surface conditions. Here we describe the signature of seismic ruptures propagating along shallow creeping faults affecting unconsolidated forearc sediments. Field observations of deformation band–dominated fault zones show widespread foliated cataclasites in fault cores, locally overprinted by sharp slip surfaces decorated by thin (0.5–1.5 cm) black gouge layers (herein, black gouge). Compared to foliated cataclasites, black gouges have much lower grain size, porosity, and permeability. Moreover, they are characterized by distinct mineralogical assemblages compatible with high temperatures (180–200 °C) due to frictional heating during seismic slip. Foliated cataclasites were also produced by laboratory experiments performed on host sediments at subseismic slip rates (≤0.1 m/s), displaying high residual friction (µf = 0.65) and strain-hardening behavior. Black gouges were produced during experiments performed at seismic (1 m/s) slip rates, displaying low residual friction (µf = 0.3) due to dynamic weakening. Our results show that black gouges represent a potential diagnostic marker for seismic faulting in shallow creeping faults. These findings can help understanding the time-space partitioning between aseismic and seismic behavior of faults at shallow crustal levels.