Luca Fiorani

New ground-based lidar enables volcanic CO2 flux measurements.

There have been substantial advances in the ability to monitor the activity of hazardous volcanoes in recent decades. However, obtaining early warning of eruptions remains challenging, because the patterns and consequences of volcanic unrests are both complex and nonlinear. Measuring volcanic gases has long been a key aspect of volcano monitoring since these mobile fluids should reach the surface long before the magma. There has been considerable progress in methods for remote and in-situ gas sensing, but measuring the flux of volcanic CO2—the most reliable gas precursor to an eruption—has remained a challenge. Here we report on the first direct quantitative measurements of the volcanic CO2 flux using a newly designed differential absorption lidar (DIAL), which were performed at the restless Campi Flegrei volcano. We show that DIAL makes it possible to remotely obtain volcanic CO2 flux time series with a high temporal resolution (tens of minutes) and accuracy (<30%). The ability of this lidar to remotely sense volcanic CO2 represents a major step forward in volcano monitoring, and will contribute improved volcanic CO2 flux inventories. Our results also demonstrate the unusually strong degassing behavior of Campi Flegrei fumaroles in the current ongoing state of unrest.

Lidar fluorosensor calibration of the SeaWiFS chlorophyll algorithm in the Ross Sea

Surface chlorophyll-a concentrations were measured in the Ross Sea and in the Antarctica-New Zealand transect by the lidar fluorosensor aboard the research vessel Italica during the 13th Italian Antarctic Oceanographic Campaign (December 1997-January 1998). The lidar measurements were compared to the data collected by the Sea-viewing Wide Field-of-view Sensor (SeaWiFS). The study area contained four distinct regions: coastal waters located east of Terra Nova Bay (chlorophyll-a 0.2-9 mg m m 3 ), offshore waters of the Ross Sea (chlorophyll-a 0.03-7 mg m m 3 ), offshore waters of the Ross Sea-New Zealand transect (chlorophyll-a 0.1-2 mg m m 3 ) and coastal waters located south of New Zealand (chlorophyll-a 0.2-9 mg m m 3 ). In coastal waters, lidar values were significantly higher than those of SeaWiFS. In offshore waters the discrepancy was lower and the experimental points were enough to calibrate the SeaWiFS chlorophyll-a algorithm against the lidar fluorosensor measurements in the Ross Sea.

Measurement of Mount Etna plume by CO 2 -laser-based lidar

The CO2 laser-based agile tuner lidar for atmospheric sensing has been used to profile the volcanic plume of Mount Etna during its most recent eruption. Owing to the transmitted wavelength, this system is practically insensitive to air molecules while it detects aerosol loads, and thus the path attenuation of the laser beam is strongly affected by volcanic particulate. Vertical profiles of extinction coefficient were retrieved up to an altitude above ground level of 5000 m. The observed extinction coefficient ranges from 10(-5) to 5x10(-4) m(-1). The lidar was able to accurately track the spatiotemporal evolution of the volcanic plume thanks to a spatial resolution of 15 m and a temporal resolution of 1 min.

Remotely sensed primary production in the western Ross Sea: results of in situ tuned models

The Southern Ocean plays an important role in the global carbon cycle and, as a consequence, in the planetary climate equilibrium. The Ross Sea is one of the more productive regions in the Southern Ocean, due to strong phytoplankton blooms occurring during summer. Satellite remote sensing is a powerful tool for investigating such phenomena, especially if the bio-optical algorithms are tuned with in situ data. In this paper, after having compared the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) and the ENEA Lidar Fluorosensor (ELF), the SeaWiFS chlorophyll a (Chl a) algorithm is tuned in the Ross Sea by means of the ELF measurements. The Chl a concentrations obtained in this way have been the basis for estimating productivity values and their evolution during summer 1997–98. Three primary production models have been used, providing information on their accuracy and performance in the Antarctic environment. Our investigations suggest that the primary production was lower than usual during the period 3 December 1997–16 January 1998.

Laser methods for the atmospheric correction of marine radiance data sensed from a satellite

Satellite remote sensing of sea color is a powerful instrument to perform oceanic studies. Unfortunately, the present data processing algorithms are not exempt from uncertainties, especially because the marine radiance must be separated from the atmospheric contributions, which typically represent about 80% of the total. In this paper we suggest the development of observation methods based on the optical radar or lidar. In fact, the numerical simulation of a sea-level optical radar demonstrates that, if applied to restricted areas, such system is a precise and versatile tool for the atmospheric correction of marine radiance data sensed from satellite (accuracy better than 10% for typical conditions). Moreover, the lidar is effective even in environments that would be severe for the standard corrective schemes. Finally, the feasibility of a spaceborne system is discussed.

Submersible Spectrofluorometer for Real-Time Sensing of Water Quality

In this work, we present a newly developed submersible spectrofluorometer (patent pending) applied to real-time sensing of water quality, suitable for monitoring some important indicators of the ecological status of natural waters such as chlorophyll-a, oil and protein-like material. For the optomechanical realization of the apparatus, a novel conceptual design has been adopted in order to avoid filters and pumps while maintaining a high signal-to-noise ratio. The elimination of filters and pumps has the advantage of greater system simplicity and especially of avoiding the risk of sample degradation. The use of light-emitting diodes as an excitation source instead of Xe lamps or laser diodes helped save on size, weight, power consumption and costs. For sensor calibration we performed measurements on water samples with added chlorophyll prepared in the laboratory. The sensor functionality was tested during field campaigns conducted at Albano Lake in Latium Region of Italy as well as in the Herzliya Harbor, a few kilometers North East of Tel Aviv in Israel. The obtained results are reported in the paper. The sensitivity achieved for chlorophyll-a detection was found to be at least 0.2 µg/L.

Scanning flow cytometer modified to distinguish phytoplankton cells from their effective size, effective refractive index, depolarization, and fluorescence

A laser flow cytometer based on scanning flow cytometry has been assembled. The unpolarized and linearly polarized light-scattering profiles, as well as the side emitted light in different spectral bands, were measured, allowing the simultaneous and real-time determination of the effective size and the effective refractive index of each spherelike particle. Additionally, each particle could be identified from depolarization and fluorescence measured simultaneously. The tests with aqueous samples of polystyrene spheres, fluorescent or nonfluorescent, and phytoplankton cells demonstrate that the system is able to retrieve size and refractive index with an accuracy of 1% and that the depolarization and fluorescence measurements allow the classification of particles otherwise indistinguishable.

Comparison of SeaWiFS, MODIS‐Terra and MODIS‐Aqua in the Southern Ocean

The surface chlorophyll‐a concentrations measured by SeaWiFS, MODIS‐Terra and MODIS‐Aqua are compared in the Southern Ocean in summer 2003. The radiometers generally agree within their estimated accuracy. Residual discrepancies could be reduced by regional calibrations of the bio‐optical algorithms.

First algorithm for chlorophyll‐a retrieval from MODIS‐Terra imagery of Sun‐induced fluorescence in the Southern Ocean

The measurements of in situ samplers, the ENEA Light Detection and Ranging (Lidar) Fluorosensor (ELF) and Moderate Resolution Imaging Spectroradiometer on‐board the Terra satellite (MODIS‐Terra), carried out in the Southern Ocean during the Austral summer 2002–2003, were used to provide the first algorithm for chlorophyll‐a (Chl‐a) retrieval from MODIS‐Terra imagery of Sun‐induced fluorescence in the Southern Ocean. The results of the algorithm indicate that the standard MODIS‐Terra algorithm underestimated Chl‐a. The discrepancy (20%) is below the expected error of MODIS (35%).

Proximal detection of traces of energetic materials with an eye-safe UV raman prototype developed for civil applications

A new Raman-based apparatus for proximal detection of energetic materials on people, was developed and tested for the first time. All the optical and optoelectronics components of the apparatus, as well as their optical matching, were carefully chosen and designed to respect international eye-safety regulations. In this way, the apparatus is suitable for civil applications on people in public areas such as airports and metro or railway stations. The acquisition software performs the data analysis in real-time to provide a fast response to the operator. Moreover, it allows for deployment of the apparatus either as a stand alone device or as part of a more sophisticated warning system architecture made up of several sensors. Using polyamide as substrate, the apparatus was able to detect surface densities of ammonium nitrate (AN), 2-methyl-1,3,5-trinitrobenzene (TNT), 3-nitrooxy-2,2-bis(nitrooxymethyl)propyl] nitrate (PETN) and urea nitrate (UN) in the range of 100–1000 μg/cm2 at a distance of 6.4 m using each time a single laser pulse of 3 mJ/cm2. The limit of detection calculated for AN is 289 μg/cm2. AN and UN provided the highest percentages of true positives (>82% for surface densities of 100–400 μg/cm2 and fingerprints) followed by TNT and PETN (17%–70% for surface densities of 400–1000 μg/cm2 and fingerprints).