Marcello Nuvoli

New ground-based lidar enables volcanic CO2 flux measurements.

There have been substantial advances in the ability to monitor the activity of hazardous volcanoes in recent decades. However, obtaining early warning of eruptions remains challenging, because the patterns and consequences of volcanic unrests are both complex and nonlinear. Measuring volcanic gases has long been a key aspect of volcano monitoring since these mobile fluids should reach the surface long before the magma. There has been considerable progress in methods for remote and in-situ gas sensing, but measuring the flux of volcanic CO2—the most reliable gas precursor to an eruption—has remained a challenge. Here we report on the first direct quantitative measurements of the volcanic CO2 flux using a newly designed differential absorption lidar (DIAL), which were performed at the restless Campi Flegrei volcano. We show that DIAL makes it possible to remotely obtain volcanic CO2 flux time series with a high temporal resolution (tens of minutes) and accuracy (<30%). The ability of this lidar to remotely sense volcanic CO2 represents a major step forward in volcano monitoring, and will contribute improved volcanic CO2 flux inventories. Our results also demonstrate the unusually strong degassing behavior of Campi Flegrei fumaroles in the current ongoing state of unrest.

Remote Colorimetric and Structural Diagnosis by RGB-ITR Color Laser Scanner Prototype

Since several years ENEAs Artificial Vision laboratory is involved in electrooptics systems development. In the last period the efforts are concentrated on cultural heritage remote diagnosis, trying to develop instruments suitable for multiple purposes concerning restoration, cataloguing, and education. Since last five years a new 3D (three-dimensional) laser scanner prototype (RGB-ITR) based on three amplitude-modulated monochromatic laser sources mixed together by dichroic filters is under development. Five pieces of information per each sampled point (pixel) are collected by three avalanche photodiodes and dedicated electronics: two distances and three target reflectivity signals for each channel, red, green, and blue. The combination of these pieces of information opens new scenarios for remote colorimetry allowing diagnoses without the use of scaffolds. Results concerning the use of RGB-ITR as colorimeter are presented.

Techniques for effective optical noise rejection in amplitude-modulated laser optical radars for underwater three-dimensional imaging

Amplitude-modulated (AM) laser imaging is a promising technology for the production of accurate three-dimensional (3D) images of submerged scenes. The main challenge is that radiation scattered off water gives rise to a disturbing signal (optical noise) that degrades more and more the quality of 3D images for increasing turbidity. In this paper, we summarize a series of theoretical findings, that provide valuable hints for the development of experimental methods enabling a partial rejection of optical noise in underwater imaging systems. In order to assess the effectiveness of these methods, which range from modulation/demodulation to polarimetry, we carried out a series of experiments by using the laboratory prototype of an AM 3D imager ( = 405 nm) for marine archaeology surveys, in course of realization at the ENEA Artificial Vision Laboratory (Frascati, Rome). The obtained results confirm the validity of the proposed methods for optical noise rejection.

Experimental evidence of signal-optical noise interferencelike effect in underwater amplitude-modulated laser optical radar systems.

We report experimental evidence that in an amplitude-modulated laser optical radar system for underwater 3D imaging the observed contrast oscillations as a function of the modulation frequency originate from an interference-like effect between target signal VT and water backscattered radiation VW. The demonstration relies on the ability to perform a direct measurement of VW in a 25 m long test tank. The proposed data processing method enables one to remove the contribution of water backscattering from the detected signal and drastically reduce signal fluctuations due to the medium. Experiments also confirm the possibility to improve the signal to optical noise ratio and contrast by increasing the modulation frequency.

A new eye-safe UV Raman spectrometer for the remote detection of energetic materials in fingerprint concentrations: Characterization by PCA and ROC analyzes.

We report the results of proximal Raman investigations at a distance of 7 m, to detect traces of explosives (from 0.1 to 0.8 mg/cm(2)) on common clothes with a new eye-safe apparatus. The instrument excites the target with a single laser shot of few ns (10(-9)s) in the UV range (laser wavelength 266 nm) detecting energetic materials like Pentaerythritol tetranitrate (PETN), Trinitrotoluene (TNT), Urea Nitrate (UN) and Ammonium Nitrate (AN). Samples were prepared using a piezoelectric-controlled plotter device to realize well-calibrated amounts of explosives on several cm(2). Common fabrics and tissues such as polyester, polyamide and leather were used as substrates, representative of base-materials used in the production of jackets or coats. Other samples were prepared by touching the substrate with a silicon finger contaminated with explosives, to simulate a spot left by contaminated hands on a jacket or bag during the preparation of an improvised explosive device (IED) by a terrorist. The observed Raman signals showed some peculiar molecular bands of the analyzed compounds, allowing us to identify and discriminate them with high sensitivity and selectivity, also in presence of the interfering signal from the underlying fabric. A dedicated algorithm was developed to remove noise and fluorescence background from the single laser shot spectra and an automatic spectral recognition procedure was also implemented, evaluating the intensity of the characteristic Raman bands of each explosive and allowing their automatic classification. Principal component analysis (PCA) was used to show the discrimination potentialities of the apparatus on different sets of explosives and to highlight possible criticalities in the detection. Receiver operating characteristic (ROC) curves were used to discuss and quantify the sensitivity and the selectivity of the proposed recognition procedure. To our knowledge the developed device is at the highest sensitivity nowadays achievable in the field of eye-safe, Raman devices for proximal detection.

Proximal detection of traces of energetic materials with an eye-safe UV raman prototype developed for civil applications

A new Raman-based apparatus for proximal detection of energetic materials on people, was developed and tested for the first time. All the optical and optoelectronics components of the apparatus, as well as their optical matching, were carefully chosen and designed to respect international eye-safety regulations. In this way, the apparatus is suitable for civil applications on people in public areas such as airports and metro or railway stations. The acquisition software performs the data analysis in real-time to provide a fast response to the operator. Moreover, it allows for deployment of the apparatus either as a stand alone device or as part of a more sophisticated warning system architecture made up of several sensors. Using polyamide as substrate, the apparatus was able to detect surface densities of ammonium nitrate (AN), 2-methyl-1,3,5-trinitrobenzene (TNT), 3-nitrooxy-2,2-bis(nitrooxymethyl)propyl] nitrate (PETN) and urea nitrate (UN) in the range of 100–1000 μg/cm2 at a distance of 6.4 m using each time a single laser pulse of 3 mJ/cm2. The limit of detection calculated for AN is 289 μg/cm2. AN and UN provided the highest percentages of true positives (>82% for surface densities of 100–400 μg/cm2 and fingerprints) followed by TNT and PETN (17%–70% for surface densities of 400–1000 μg/cm2 and fingerprints).

Early detection of volcanic hazard by lidar measurement of carbon dioxide

Abstract Volcanic gases give information on magmatic processes. In particular, anomalous releases of carbon dioxide precede volcanic eruptions. Up to now, this gas has been measured in volcanic plumes with conventional measurements that imply the severe risks of local sampling and can last many hours. For these reasons and for the great advantages of laser sensing, the thorough development of volcanic lidars has been undertaken at ENEA (Italian National Agency for New Technologies, Energy and Sustainable Economic Development). In fact, lidar profiling allows one to scan remotely volcanic plumes in a fast and continuous way, and with high spatial and temporal resolution. A differential absorption lidar instrument will be presented in this paper: BILLI (BrIdge voLcanic LIdar). It is based on injection-seeded Nd:YAG laser, double-grating dye laser, difference frequency mixing and optical parametric amplifier. BILLI is funded by the ERC (European Research Council) project BRIDGE (BRIDging the gap between Gas Emissions and geophysical observations at active volcanos). It scanned the gas emitted by Pozzuoli Solfatara (Naples, Italy) and Stromboli Volcano (Sicily, Italy) during field campaigns carried out from October 13 to 17, 2014, and from June 24 to 29, 2015, respectively. Carbon dioxide concentration maps were retrieved remotely in few minutes in the crater areas. To our knowledge, it is the first time that carbon dioxide in a volcanic plume is retrieved by lidar. This result represents the first direct measurement of this kind ever performed on active volcanos and shows the high potential of laser remote sensing in early detection of volcanic hazard.

Polarimetry as a valid means to reduce optical noise in underwater 3D imaging by means of amplitude-modulated laser optical radar systems

We report the results of a series of underwater imaging experiments in the visible, carried out at ENEA (Frascati, Rome) by using a bistatic, amplitude-modulated laser optical radar system. In these experiments, polarimetry is used for minimizing the water backscattering signal and improving the accuracy of phase measurements directly related to distance. The presented technique enables one to obtain 3D images of underwater real scenes characterized by high quality, space resolution, and contrast. The results are of remarkable importance for applications in the 3D imaging of submerged objects, such as submarine archaeological sites.

Imaging topological radar technology as a general purpose instrument for remote colorimetric assessment, structural security, cataloguing, and dissemination

Abstract While today 3D digitisation techniques are commonly applied in several areas of cultural heritage, introducing new ways for monitoring, cataloguing, and studying masterpieces, the use of these technologies is not always worthwhile in terms of costs/benefits. The ENEA UTAPRAD-DIM laboratory has developed opto-electronic devices for cultural heritage applications. Two different 3D laser scanners for terrestrial and underwater inspection have been the subject of laboratory research for the last decade and a new technique known as imaging topological radar (ITR) has been developed and patented. The ITR system is based on the superimposition of three amplitude-modulated laser sources for the simultaneous acquisition of data related to colour and structure. This approach opens new scenarios for colour measurement and remote/non-invasive analysis, reducing the gap between costs and benefits from the technology. Several factors affect the quality of data collected by ITR, such as the precision of the scanner mechanism, the material and shape of the work studied, and the geometry of scanning (i.e. distance and angular dependencies). This paper explores the effect of the geometry of scanning on point cloud quality, focussing attention on data correction algorithms and their practical application. The data collected during the digitisation of the Sistine Chapel using the RGB-ITR scanner serve as a case study for validating the theoretical assumptions, models, and algorithms.

Stand-off detection of traces of explosives and precursors on fabrics by UV Raman spectroscopy

At the Diagnostic and Metrology Laboratory (ENEA) is under development a stand-off apparatus for trace detection of explosive compounds. The system is based on the Raman technique due to the high discrimination capabilities. All the optoelectronics components of the apparatus have been carefully designed as well as their optical matching. The main goal will be to detect low trace components within the respect of the eye safe regulation.