Luca Schio

Angular and energy distributions of fragment ions in dissociative double photoionization of acetylene molecules in the 31.9-50.0 eV photon energy range

The two-body dissociation reactions of the dication C2H2+2, initiated via double ionization of acetylene molecules by photons in the energy range 31.9-50.0 eV, have been studied by coupling photoelectron-photoion-photoion coincidence and ion imaging techniques. The angular distributions and kinetic energy of product ions, measured in the 31.9-50.0 eV energy range, exhibit significant differences for the three leading dissociation reactions with respect to a previous investigation carried out at a fixed energy of 39.0 eV, providing thus new information on the dynamical evolution of the system. The analysis of the results indicates that such dissociation reactions occur with a different mechanism. In particular, the symmetric dissociation in two CH+ ions is characterized by different dynamics, and the anisotropy of the angular distribution of ionic products increases with photon energy in a more pronounced way than the other two reactions. Moreover, the kinetic energy distribution of the symmetric dissociat...

Experimental and theoretical XPS and NEXAFS studies of N-methylacetamide and N-methyltrifluoroacetamide

Experimental Near-Edge X-ray Absorption Fine-Structure (NEXAFS) spectra of N-methyltrifluoroacetamide (FNMA), which is a peptide model system, measured at the C, N, O and F K-edges are reported. The features in the spectra have been assigned by Static-Exchange (STEX) calculations. Using the same method, we have also assigned previously measured NEXAFS spectra of another peptide model system, N-methylacetamide (NMA). To facilitate the NEXAFS feature assignments, X-ray Photoelectron Spectroscopy (XPS) measurements for NMA and FNMA have been carried out with the aim of obtaining the 1s electron ionization potentials, which are compared with the values predicted by our Hartree-Fock (ΔHF) and Multi Configuration Self Consistent Field (ΔMCSCF) calculations. We also demonstrate an approach to compensate for screening effects that are neglected in the STEX method. Ion yield measurements of FNMA associated with the excitation of several C, N, O, and F K-shell pre-edge resonances have revealed site-specific fragmentation in some cases which we interpret with the aid of our theoretical calculations.

Double photoionization of propylene oxide: A coincidence study of the ejection of a pair of valence-shell electrons

Propylene oxide, a favorite target of experimental and theoretical studies of circular dichroism, was recently discovered in interstellar space, further amplifying the attention to its role in the current debate on protobiological homochirality. In the present work, a photoelectron-photoion-photoion coincidence technique, using an ion-imaging detector and tunable synchrotron radiation in the 18.0-37.0 eV energy range, permits us (i) to observe six double ionization fragmentation channels, their relative yields being accounted for about two-thirds by the couple (C2H4+, CH2O+) and one-fifth by (C2H3+, CH3O+); (ii) to measure thresholds for their openings as a function of photon energy; and (iii) to unravel a pronounced bimodality for a kinetic-energy-released distribution, fingerprint of competitive non-adiabatic mechanisms.

A Study of H2O2 with Threshold Photoelectron Spectroscopy (TPES) and Electronic Structure Calculations: Redetermination of the First Adiabatic Ionization Energy (AIE)

In this work, hydrogen peroxide has been studied with threshold photoelectron (TPE) spectroscopy and photoelectron (PE) spectroscopy. The TPE spectrum has been recorded in the 10.0-21.0 eV ionization energy region, and the PE spectrum has been recorded at 21.22 eV photon energy. Five bands have been observed which have been assigned on the basis of UCCSD(T)-F12/VQZ-F12 and IP-EOM CCSD calculations. Vibrational structure has only been resolved in the TPE spectrum of the first band, associated with the X̃(2)Bg H2O2(+) ← X̃(1)A H2O2 ionization, on its low energy side. This structure is assigned with the help of harmonic Franck-Condon factor calculations that use the UCCSD(T)-F12a/VQZ-F12 computed adiabatic ionization energy (AIE), and UCCSD(T)-F12a/VQZ-F12 computed equilibrium geometric parameters and harmonic vibrational frequencies for the H2O2 X̃(1)A state and the H2O2(+) X̃(2)Bg state. These calculations show that the main vibrational structure on the leading edge of the first TPE band is in the O-O stretching mode (ω3) and the HOOH deformation mode (ω4), and comparison of the simulated spectrum to the experimental spectrum gives the first AIE of H2O2 as (10.685 ± 0.005) eV and ω4 = (850 ± 30) and ω3 = (1340 ± 30) cm(-1) in the X̃(2)Bg state of H2O2(+). Contributions from ionization of vibrationally excited levels in the torsion mode have been identified in the TPE spectrum of the first band and the need for a vibrationally resolved TPE spectrum from vibrationally cooled molecules, as well as higher level Franck-Condon factors than performed in this work, is emphasized.

NEXAFS spectroscopy and site-specific fragmentation of N-methylformamide, N,N-dimethylformamide, and N,N-dimethylacetamide.

Near-edge X-ray absorption fine-structure (NEXAFS) spectra measured at the C, N, and O K-edges for three molecules containing the amide moiety, N-methylformamide (HCONHCH3), N,N-dimethylformamide (HCON(CH3)2), and N,N-dimethylacetamide (CH3CON(CH3)2) are presented. These molecules have similar structures and differ by the number of methyl groups located at the molecular ends. The fragmentation of these molecules after resonant excitation at different K-edge resonances is also investigated, using a 3D-ion imaging time-of-flight spectrometer. A comparison between the molecules with respect to the relative contributions of the fragments created upon excitation at distinct resonances reveals site-specific fragmentation. Further information about the character of the core-excitation and dissociation process is obtained from the angular distributions of the ion fragments.

Complete dissociation branching fractions and Coulomb explosion dynamics of SO2 induced by excitation of O 1s pre-edge resonances

Fragmentation processes of SO2 following excitation of the six main O 1s pre-edge resonances, as well as above the ionization threshold and below the resonances, are studied using a position-sensitive time-of-flight ion imaging detector, and the associated dissociation branching ratios and break-up dynamics are determined. In order to distinguish between the O(+) and S(2+) fragments of equal mass-to-charge ratio, the measurements have been performed with the isotopically enriched S(18)O2 sample. By analysis of the complete set of the fragment momentum vectors, the β values for the fragments originating from the SO(+) + O(+) break-up and the kinetic energy release for fragmentation channels of both SO2 (2+) and SO2 (3+) parent ions are determined. We also present results on the three-body break-up dynamics.

Double Photoionization of Simple Molecules of Astrochemical Interest

An experimental and computational investigation characterizing the processes following the double photoionization of the methyloxirane and N-methylformamide molecules has been reported. The double photoionization experiments have been performed at the Elettra Synchrotron Facility of Trieste (Italy). Preliminary data show: (i) in the case of methyloxirane, six different two-body fragmentation processes leading to \( {\text{CH}}_{2}^{ + } /{\text{C}}_{2} {\text{H}}_{4} {\text{O}}^{ + } ,{\text{CH}}_{3}^{ + } /{\text{C}}_{ 2} {\text{H}}_{ 3} {\text{O}}^{ + } ,{\text{O}}^{ + } /{\text{C}}_{ 3} {\text{H}}_{6}^{ + } , {\text{ OH}}^{ + } / {\text{C}}_{ 3} {\text{H}}_{5}^{ + } ,{\text{C}}_{ 2} {\text{H}}_{3}^{ + } /{\text{CH}}_{ 3} {\text{O}}^{ + } ,{\text{C}}_{ 2} {\text{H}}_{4}^{ + } /{\text{CH}}_{ 2} {\text{O}}^{ + } \) pairs of final ions; (ii) in the case of N-methylformamide, two main two-body fragmentation processes, leading to \( {\text{CH}}_{3}^{ + } + {\text{CH}}_{2} {\text{NO}}^{ + } \) and \( {\text{H}}^{ + } + {\text{C}}_{2} {\text{H}}_{4} {\text{NO}}^{ + } \). The threshold’s energy for each dissociation channel is determined with the relative cross sections as a function of the investigated photon energy range. A careful analysis of recorded electron-ion-ion coincidence spectra mainly based on a Monte Carlo trajectory simulation is able to provide also the kinetic energy released (KER) distribution for the final ions of the investigated fragmentation reactions. These important experimental data are mandatory information to unravel the physical chemistry of the elementary processes induced by the interaction of photons, with simple relevant organic molecules: (i) the methyloxirane of astrochemical interest, being the first chiral molecule recently discovered in interstellar cloud Sagittarius B2; (ii) the N-methylformamide, being an important simple molecule containing the peptide bond, recently detected in the interstellar medium, in order to investigate its selective cleavage induced by UV photons. In the latter case, this can improve a deeper definition of formation/destruction routes in astrochemical environments of the more abundant formamide molecule.

Investigating core-excited states of nitrosyl chloride (ClNO) and their break-up dynamics following Auger decay

The fragmentation of ClNO upon resonant core-electron excitation to the LUMO and LUMO+1 orbitals at the N and O K-edges is investigated. The produced fragment ions were detected in coincidence with a position sensitive ion time-of-flight detector which enables deduction of the angular distribution of the ions. This facilitates a comparison between the two resonances and the two K-edges with respect to fragmentation time, transition dipole moment orientation, fragment yield of single-ion and ion-pair channels, and fragmentation mechanisms. We observe significant correlations between the core-excited site and the location of the bonds that are broken, as well as the dissociation time. Moreover, we observe preferential cleavage of specific bonds upon excitation to the LUMO and LUMO+1 states which can be attributed to their orbital character.