Luis A. Correa

Quantum-enhanced absorption refrigerators

Thermodynamics is a branch of science blessed by an unparalleled combination of generality of scope and formal simplicity. Based on few natural assumptions together with the four laws, it sets the boundaries between possible and impossible in macroscopic aggregates of matter. This triggered groundbreaking achievements in physics, chemistry and engineering over the last two centuries. Close analogues of those fundamental laws are now being established at the level of individual quantum systems, thus placing limits on the operation of quantum-mechanical devices. Here we study quantum absorption refrigerators, which are driven by heat rather than external work. We establish thermodynamic performance bounds for these machines and investigate their quantum origin. We also show how those bounds may be pushed beyond what is classically achievable, by suitably tailoring the environmental fluctuations via quantum reservoir engineering techniques. Such superefficient quantum-enhanced cooling realises a promising step towards the technological exploitation of autonomous quantum refrigerators.

Performance bound for quantum absorption refrigerators.

An implementation of quantum absorption chillers with three qubits has been recently proposed that is ideally able to reach the Carnot performance regime. Here we study the working efficiency of such self-contained refrigerators, adopting a consistent treatment of dissipation effects. We demonstrate that the coefficient of performance at maximum cooling power is upper bounded by 3/4 of the Carnot performance. The result is independent of the details of the system and the equilibrium temperatures of the external baths. We provide design prescriptions that saturate the bound in the limit of a large difference between the operating temperatures. Our study suggests that delocalized dissipation, which must be taken into account for a proper modeling of the machine-baths interaction, is a fundamental source of irreversibility which prevents the refrigerator from approaching the Carnot performance arbitrarily closely in practice. The potential role of quantum correlations in the operation of these machines is also investigated.

Individual quantum probes for optimal thermometry

The unknown temperature of a sample can be estimated with minimal disturbance by putting it in thermal contact with an individual quantum probe. If the interaction time is sufficiently long so that the probe thermalizes, the temperature can be read-out directly from its steady state. Here we prove that the optimal quantum probe, acting as a thermometer with maximal thermal sensitivity, is an effective two-level atom with a maximally degenerate excited state. When the total interaction time is insufficient to produce full thermalization, we optimize the estimation protocol by breaking it down into sequential stages of probe preparation, thermal contact, and measurement. We observe that frequently interrogated probes initialized in the ground state achieve the best performance. For both fully and partly thermalized thermometers, the sensitivity grows significantly with the number of levels, though optimization over their energy spectrum remains always crucial.

Optimal performance of endoreversible quantum refrigerators

The derivation of general performance benchmarks is important in the design of highly optimized heat engines and refrigerators. To obtain them, one may model phenomenologically the leading sources of irreversibility ending up with results that are model independent, but limited in scope. Alternatively, one can take a simple physical system realizing a thermodynamic cycle and assess its optimal operation from a complete microscopic description. We follow this approach in order to derive the coefficient of performance at maximum cooling rate for any endoreversible quantum refrigerator. At striking variance with the universality of the optimal efficiency of heat engines, we find that the cooling performance at maximum power is crucially determined by the details of the specific system-bath interaction mechanism. A closed analytical benchmark is found for endoreversible refrigerators weakly coupled to unstructured bosonic heat baths: an ubiquitous case study in quantum thermodynamics.

Internal dissipation and heat leaks in quantum thermodynamic cycles.

The direction of the steady-state heat currents across a generic quantum system connected to multiple baths may be engineered to realize virtually any thermodynamic cycle. In spite of their versatility, such continuous energy-conversion systems are generally unable to operate at maximum efficiency due to non-negligible sources of irreversible entropy production. In this paper we introduce a minimal model of irreversible absorption chiller. We identify and characterize the different mechanisms responsible for its irreversibility, namely heat leaks and internal dissipation, and gauge their relative impact in the overall cooling performance. We also propose reservoir engineering techniques to minimize these detrimental effects. Finally, by looking into a known three-qubit embodiment of the absorption cooling cycle, we illustrate how our simple model may help to pinpoint the different sources of irreversibility naturally arising in more complex practical heat devices.

Asymptotic discord and entanglement of nonresonant harmonic oscillators under weak and strong dissipation

In this work, we calculate the exact asymptotic quantum correlations between two interacting non-resonant harmonic oscillators in a common Ohmic bath. We derive \emph{analytical formulas} for the covariances, fully describing any Gaussian stationary state of the system, and use them to study discord and entanglement in the strong and weak dissipation regimes. We discuss the rich structure of the discord of the stationary separable states arising in the strong dissipation regime. Also under strong dissipation, when the modes are not mechanically coupled, these may entangle only through their interaction with the \emph{common} environment. Interestingly enough, this stationary entanglement is only present within a \emph{finite band of frequencies} and increases with the dissipation rate. In addition, robust entanglement between \emph{detuned} oscillators is observed at low temperature.

Thermodynamics of quantum feedback cooling

The ability to initialize quantum registers in pure states lies at the core of many applications of quantum technologies, from sensing to quantum information processing and computation. In this paper, we tackle the problem of increasing the polarization bias of an ensemble of two-level register spins by means of joint coherent manipulations, involving a second ensemble of ancillary spins and energy dissipation into an external heat bath. We formulate this spin refrigeration protocol, akin to algorithmic cooling, in the general language of quantum feedback control, and identify the relevant thermodynamic variables involved. Our analysis is two-fold: on the one hand, we assess the optimality of the protocol by means of suitable figures of merit, accounting for both its work cost and effectiveness; on the other hand, we characterise the nature of correlations built up between the register and the ancilla. In particular, we observe that neither the amount of classical correlations nor the quantum entanglement seem to be key ingredients fuelling our spin refrigeration protocol. We report instead that a more general indicator of quantumness beyond entanglement, the so-called quantum discord, is closely related to the cooling performance.

Achieving sub-shot-noise sensing at finite temperatures

We investigate sensing of magnetic fields using quantum spin chains at finite temperature and exploit quantum phase crossovers to improve metrological bounds on the estimation of the chain parameters. In particular, we analyze the XX spin chain and show that the magnetic sensitivity of this system is dictated by its adiabatic magnetic susceptibility, which scales extensively (linearly) in the number of spins N. Next, we introduce an iterative feedforward protocol that actively exploits features of quantum phase crossovers to enable super-extensive scaling of the magnetic sensitivity. Moreover, we provide experimentally realistic observables to saturate the quantum metrological bounds. Finally, we also address magnetic sensing in the Heisenberg XY spin chain.

Practical quantum metrology in noisy environments

The problem of estimating an unknown phase ϕ using two-level probes in the presence of unital phase-covariant noise and using finite resources is investigated. We introduce a simple model in which the phase-imprinting operation on the probes is realized by a unitary transformation with a randomly sampled generator. We determine the optimal phase sensitivity in a sequential estimation protocol and derive a general (tight-fitting) lower bound. The sensitivity grows quadratically with the number of applications N of the phase-imprinting operation, then attains a maximum at some Nopt, and eventually decays to zero. We provide an estimate of Nopt in terms of accessible geometric properties of the noise and illustrate its usefulness as a guideline for optimizing the estimation protocol. The use of passive ancillas and of entangled probes in parallel to improve the phase sensitivity is also considered .We find that multiprobe entanglement may offer no practical advantage over single-probe coherence if the interrogation at the output is restricted to measuring local observables.

Enhancement of low-temperature thermometry by strong coupling

Luis A. Correa,1, 2 Martı́ Perarnau-Llobet,3, 4 Karen V. Hovhannisyan,5, 4 Senaida Hernández-Santana,4 Mohammad Mehboudi,2 and Anna Sanpera2, 6 1School of Mathematical Sciences and Centre for the Mathematics and Theoretical Physics of Quantum Non-Equilibrium Systems, The University of Nottingham, University Park, Nottingham NG7 2RD, United Kingdom∗ 2Departament de Fı́sica, Universitat Autònoma de Barcelona, 08193 Bellaterra, Spain 3Max-Planck-Institut für Quantenoptik, Hans-Kopfermann-Str. 1, D-85748 Garching, Germany 4Institut de Ciències Fotòniques (ICFO), The Barcelona Institute of Science and Technology, 08860 Castelldefels (Barcelona), Spain 5Department of Physics and Astronomy, Ny Munkegade 120, 8000 Aarhus, Denmark 6Institució Catalana de Recerca i Estudis Avançats (ICREA), Psg. Lluı́s Companys 23, 08010 Barcelona, Spain (Dated: August 8, 2017)