Luqman Jameel Rather

Antimicrobial and fluorescence finishing of woolen yarn with Terminalia arjuna natural dye as an ecofriendly substitute to synthetic antibacterial agents

The current study deals with the use of Terminalia arjuna natural dye as an ecofriendly finishing agent for producing highly functional antimicrobial and fluorescent woolen yarn along with the evaluation of kinetic and thermodynamic adsorption characteristics. The effect of pH on the adsorption was investigated, showing an increase in adsorption capacity with decreasing pH over the range of 2–9, with maximum adsorption at pH 3.5. Two kinetic equations pseudo-first order and pseudo-second order were employed for determining adsorption rates. The pseudo-second order equation provided the best fit to experimental data with an activation energy of 105.58 kJ mol−1, indicating chemisorption. The equilibrium adsorption data was fitted to Langmuir, Freundlich and Redlich–Peterson adsorption isotherms. The adsorption behavior accorded with the Redlich–Peterson isotherm with exceptionally high regression coefficients for dyeing temperatures of 50, 70 and 90 °C with dye concentration varying from 0.5–10% (o.w.f). Comparative results of the colorimetric properties (CIEL*a*b* and K/S) using a spectrophotometer under D65 illuminant (10° standard observer) and color fastness (light, wash, and rub) of dyed woolen yarns were studied to quantify the effect of metal mordants. The antimicrobial potential of Terminalia arjuna solution and dyed woolen yarn were assessed in terms of percentage inhibition of bacterial growth against a wide variety of bacterial strains, showing more than 85% inhibition. Reduction in antimicrobial activity of dyed woolen yarn was observed with mordanted samples, however they were found to retain more antimicrobial activity as compared to unmordanted samples as a function of successive washing cycles. The chemical nature of different mordants and wool–mordant–dye complex forming ability were found to have significant impact on the colorimetric and fluorescence characteristics of dyed woolen yarn.

Phytochemistry, biological activities and potential of annatto in natural colorant production for industrial applications – A review

Bixa orellana commonly known as annatto is one of the oldest known natural dye yielding plants native to Central and South America. Various parts of annatto have been widely used in the traditional medical system for prevention and treatment of a wide number of health disorders. The plethora of traditional uses has encouraged researchers to identify and isolate phytochemicals from all parts of this plant. Carotenoids, apocarotenoids, terpenes, terpenoids, sterols, and aliphatic compounds are main compounds found in all parts of this plant and are reported to exhibit a wide range of pharmacological activities. In recent years annatto has received tremendous scientific interest mainly due to the isolation of yellow-orange natural dye from its seeds which exhibits high biodegradability, low toxicity, and compatibility with the environment. Considerable research work has already been done and is currently underway for its applications in food, textile, leather, cosmetic, solar cells, and other industries. The present review provides up-to-date systematic and organized information on the traditional usage, phytochemistry and pharmacology of annatto. It also highlights its non-food industrial applications in order to bring more interest on this dye plant, identifies the existing gaps and provides potential for future studies. Studies reported in this review have demonstrated that annatto holds a great potential for being exploited as source of drugs and a potential natural dye. However, further efforts are required to identify extract biomolecules and their action mechanisms in exhibiting certain biological activities in order to understand the full phytochemical profile and the complex pharmacological effects of this plant.

Mixed Metal Mordant Dyeing of Wool using Root Extract of Rheum emodi (Indian Rhubarb/Dolu)

In the present study, the root extract of Rheum emodi (Indian Rhubarb/Dolu/Revandchini) has been used as a natural dye to develop a variety of harmonizing natural shades on woolen yarn using combination of ecofriendly mixed metal mordants. Dyeings were carried out in neutral acidic, and alkaline medium using 0.5%–5% dye concentrations pre-treated with (4.5% iron + 0.1% tin), (2.5% iron + 0.5% tin), and (0.5% iron + 0.9% tin) mordant combinations. A total of 54 shades have been developed by varying the amount of dye and percentage combination of mordants. The hue of color ranged from reddish-brown, greenish-yellow to dark yellow. The color of dyed woolen yarns was investigated in terms of color strength (K/S), CIELab, CIELch values. Fastness properties (light, washing, and rub/crocking) of dyed woolen yarn samples were also assessed.

Bi and tri metal salt combinations plus colorants extracted from timber industry waste as effective dyeing materials to produce novel shades on wool

ABSTRACT This study was undertaken to propose alternative use for teak leaves, a timber industry byproduct, as potential dyeing source for wool fibers. The coloring potential of anthraquinone colorants from teak leaves were studied on wool with pre-mordanting method using double and triple mix metal salt combinations (ferrous sulphate, stannous chloride and potassium aluminum sulphate) as mordants. Thirty-six sober and elegant shades were developed on wool by varying the type of metal involved in combination as well as concentration of the dye. The hue of color developed ranged from light orange—brown to dark brown. The color strength (K/S) has been found to be very good in dyed woolen yarn samples and particularly was highest for iron + alum combination. Color fastness with respect to light exposure washing, rubbing for the developed shades ranged between good to very good, which confirmed the possibility of using waste leaves of Tectona grandis as a source of effective brown natural dye.

Effect of binary and ternary combination of metal salt mordants on dyeing and fastness properties of natural protein fibre with Juglans regia L. dye

ABSTRACT The present article focuses on the effect of different combinations of metal mordants on color characteristics and fastness properties of natural dye extracted from Juglan regia L bark powder. The influence of different types of mordant combinations such as alum + ferrous sulphate, alum + stannous chloride, ferrous sulphate + stannous chloride, and alum + ferrous sulphate + stannous chloride on color parameters has been investigated in terms of CIELab (L*, a*, b*, c*, and h°) and K/S values. The fastness properties with respect to light, washing, and crocking of developed shades were determined according to ISO and AATCC test methods. Based on the experimental results, it has been found that 96 shades with novel and fashionable hues were produced by the use of these metal salt combinations. It was also found that all mordanted samples had satisfactory light and wash fastness ratings. Dry rub fastness was found relatively better than wet rub fastness.

Light Fastness and Shade Variability of Tannin Colorant Dyed Wool with the Effect of Mordanting Methods

ABSTRACT Mordanting methods effect on color characteristics and fastness properties, particularly light fastness were evaluated in this study. Effect of metal mordants and their combinations on wool dyeing with Terminalia chebula natural dye were investigated and correlation between dye structures, effect of metal mordant and mordanting methods were established. Results reveal that T. chebula can be used as yellow dye with or without metal mordants to get a variable range of shades on wool with good color strength and fastness properties, and appreciable shade variations with mordanting methods observed. Color performances of dyed substrate indicated substantial improvement in depth of shades and color fastness in case of mordanted samples. Pre-mordanting with tin and post-mordanting with alum proved to be most effective for increasing K/S values of the dyed substrate under the optimum dyeing conditions.

Adhatoda vasica in Conjunction with Binary Combinations of Metal Salts and Biomordants as an Effective Textile Dye to Produce novel Shades on Wool

ABSTRACT This study was undertaken to propose an alternative use of Adhatoda vasica leaves extract as a potential source of natural dye for the coloration of woolen yarn/fibers. Premordanting technique was adopted with double metal salt combinations of ferrous sulfate, stannous chloride, and potassium aluminum sulfate and double biomordant combinations of gallnut, pomegranate, and babool, to achieve dyed textile materials of acceptable colorimetric and fastness properties. Sixty-three sober and elegant shades were developed on wool by varying the nature and the concentration of mordants involved in the combinations. The hue of color developed was found to be in yellow-red coordinate of color space diagram. All the dyed samples presented excellent color strength (K/S) values and highest values were found in case of gallnut + pomegranate peel extract (PPE) combination. Biomordants produced altogether different behavior in comparison to metal mordants in the development of ecofriendly shades of different hue and tune. Majority of the dyed samples showed excellent fastness properties with respect to light, washing, and rubbing which confirmed the possibility of using A. vasica leaves extract as an effective yellow natural dye.

Biomordanting Potential of Acacia nilotica (Babul) in Conjunction with Kerria lacca and Rheum emodi Natural Dyes

ABSTRACT This study was undertaken to propose an alternative use of Acacia nilotica bark extract as a potential source of biomordant for the development of ecofriendly shades of varying hue and tone in conjunction with Kerria lacca (Lac) and Rheum emodi (Himalayan rhubarb) natural dyes. The colorimetric analysis of K. lacca and R. emodi natural dyes were evaluated onto the woolen yarn samples adopting pre-mordanting technique using 1.0–5.0% (o.w.f.) A. nilotica as biomordant. The hue of color developed was found to be in yellow-red coordinate of color space diagram with hues shifted toward red region for K. lacca and toward yellow region for R. emodi dyed samples. The color strength (K/S) values were found to increase with increase in the concentration of biomordant and were found highest for 5.0% (o.w.f.) A. nilotica mordanted samples. Color fastness with respect to light exposure, washing, rubbing for the developed shades ranged between good to very good ratings of 4–5 on grey scale, confirming the possibility of using A. nilotica bark extract as a potential source of biomordant for enhancing the colorimetric and fastness characteristics of dyed woolen yarn samples.

Dyeing of Wool with Anthraquinone based Natural Colorants from Cassia fistula fruit

ABSTRACT The searches for new sources of natural dyes have been recently increased in many countries. This article is aimed to explore the dyeing potential of Cassia fistula as a source of natural dye on wool. In this study, the anthraquinone colorants are extracted from fruit of Cassia fistula by aqueous extraction method. Mordanting and subsequent dyeing of wool with extracted colorants were then performed to study the colorimetric and fastness properties. Three metallic salts aluminum sulfate, ferrous sulfate, stannous chloride and their combinations were used in this study to fix and increase the color as well as fastness properties of the substrate. UV visible and Fourier transform infrared spectroscopy (FTIR) analysis show identification of functional groups in the dye molecule. Colorimetric properties were analyzed by reflectance spectrometry in terms of L*, a*, b*, c*, h○ and K/S values. Color fastness was investigated in terms of light, wash and rub (dry/wet) tests. Results demonstrate that novel and fashionable brown shades with different hue and tone were obtained. Therefore, Cassia fistula has an exciting opportunity to be used as a source of natural dye in textile coloration.

Simultaneous shade development, antibacterial, and antifungal functionalization of wool using Punica granatum L. Peel extract as a source of textile dye

ABSTRACT In this work, we investigated the use of pomegranate peel extract as an effective functional dye for producing beautiful natural shades on wool and to impart durable antimicrobial properties. Wool is treated with various metal salt mordants in the presence of pomegranate dye under optimum natural dyeing conditions. The structural changes of wool are characterized by SEM and FT-IR techniques. The properties of color strength, color fastness to light, washing, rubbing, and durability of antimicrobial activity to washing are investigated. The experimental results indicate that there is small color variation among shades obtained under identical dyeing conditions. Furthermore, it was found that metal salt mordants improved dyeing depth, fastness properties, and effectively enhanced the durability of antimicrobial activity up to several washing cycles.