Marcello G. Magaldi

The Mediterranean Plastic Soup: synthetic polymers in Mediterranean surface waters

The Mediterranean Sea has been recently proposed as one of the most impacted regions of the world with regards to microplastics, however the polymeric composition of these floating particles is still largely unknown. Here we present the results of a large-scale survey of neustonic micro- and meso-plastics floating in Mediterranean waters, providing the first extensive characterization of their chemical identity as well as detailed information on their abundance and geographical distribution. All particles >700 μm collected in our samples were identified through FT-IR analysis (n = 4050 particles), shedding for the first time light on the polymeric diversity of this emerging pollutant. Sixteen different classes of synthetic materials were identified. Low-density polymers such as polyethylene and polypropylene were the most abundant compounds, followed by polyamides, plastic-based paints, polyvinyl chloride, polystyrene and polyvinyl alcohol. Less frequent polymers included polyethylene terephthalate, polyisoprene, poly(vinyl stearate), ethylene-vinyl acetate, polyepoxide, paraffin wax and polycaprolactone, a biodegradable polyester reported for the first time floating in off-shore waters. Geographical differences in sample composition were also observed, demonstrating sub-basin scale heterogeneity in plastics distribution and likely reflecting a complex interplay between pollution sources, sinks and residence times of different polymers at sea.

On the Nature and Variability of the East Greenland Spill Jet: A Case Study in Summer 2003*

AbstractResults from a high-resolution (~2 km) numerical simulation of the Irminger Basin during summer 2003 are presented. The focus is on the East Greenland Spill Jet, a recently discovered component of the circulation in the basin. The simulation compares well with observations of surface fields, the Denmark Strait overflow (DSO), and the hydrographic structure of typical sections in the basin. The model reveals new aspects of the circulation on scales of O(0.1–10) days and O(1–100) km.The model Spill Jet results from the cascade of dense waters over the East Greenland shelf. Spilling can occur in various locations southwest of the strait, and it is present throughout the simulation but exhibits large variations on periods of O(0.1–10) days. The Spill Jet sometimes cannot be distinguished in the velocity field from surface eddies or from the DSO. The vorticity structure of the jet confirms its unstable nature with peak relative and tilting vorticity terms reaching twice the planetary vorticity term.The...

Fates and Travel Times of Denmark Strait Overflow Water in the Irminger Basin

The Denmark Strait Overflow (DSO) supplies about one-third of the North Atlantic Deep Water and is critical to global thermohaline circulation. Knowledge of the pathways of DSO through the Irminger Basin and its transformation there is still incomplete, however. The authors deploy over 10 000 Lagrangian particles at the Denmark Strait in a high-resolution ocean model to study these issues. First, the particle trajectories show that the mean position and potential density of dense waters cascading over the Denmark Strait sill evolve consistently with hydrographic observations. These sill particles transit the Irminger Basin to the Spill Jet section (65.25°N) in 5–7 days and to the Angmagssalik section (63.5°N) in 2–3 weeks. Second, the dense water pathways on the continental shelf are consistent with observations and particles released on the shelf in the strait constitute a significant fraction of the dense water particles recorded at the Angmagssalik section within 60 days (~25%). Some particles circulate on the shelf for several weeks before they spill off the shelf break and join the overflow from the sill. Third, there are two places where the water density following particle trajectories decreases rapidly due to intense mixing: to the southwest of the sill and southwest of the Kangerdlugssuaq Trough on the continental slope. After transformation in these places, the overflow particles exhibit a wide range of densities.

Improved surface velocity and trajectory estimates in the Gulf of Mexico from Blended satellite altimetry and drifter data

AbstractThis study investigates the results of blending altimetry-based surface currents in the Gulf of Mexico with available drifter observations. Here, subsets of trajectories obtained from the near-simultaneous deployment of about 300 Coastal Ocean Dynamics Experiment (CODE) surface drifters provide both input and control data. The fidelity of surface velocity fields are measured in the Lagrangian frame by a skill score that compares the separation between observed and hindcast trajectories to the observed absolute dispersion. Trajectories estimated from altimetry-based velocities provide satisfactory average results (skill score > 0.4) in large (~100 km) open-ocean structures. However, the distribution of skill score values within these structures is quite variable. In the DeSoto Canyon and on the shelf where smaller-scale structures are present, the overall altimeter skill score is typically reduced to less than 0.2. After 3 days, the dataset-averaged distance between hindcast and drifter trajectorie...

Statistical properties of the surface velocity field in the northern Gulf of Mexico sampled by GLAD drifters

The Grand LAgrangian Deployment (GLAD) used multiscale sampling and GPS technology to observe time series of drifter positions with initial drifter separation of O(100 m) to O(10 km), and nominal 5 min sampling, during the summer and fall of 2012 in the northern Gulf of Mexico. Histograms of the velocity field and its statistical parameters are non-Gaussian; most are multimodal. The dominant periods for the surface velocity field are 1–2 days due to inertial oscillations, tides, and the sea breeze; 5–6 days due to wind forcing and submesoscale eddies; 9–10 days and two weeks or longer periods due to wind forcing and mesoscale variability, including the period of eddy rotation. The temporal e-folding scales of a fitted drifter velocity autocorrelation function are bimodal with time scales, 0.25–0.50 days and 0.9–1.4 days, and are the same order as the temporal e-folding scales of observed winds from nearby moored National Data Buoy Center stations. The Lagrangian integral time scales increase from coastal values of 8 h to offshore values of approximately 2 days with peak values of 3–4 days. The velocity variance is large, O(1)m2/s2, the surface velocity statistics are more anisotropic, and increased dispersion is observed at flow bifurcations. Horizontal diffusivity estimates are O(103)m2/s in coastal regions with weaker flow to O(105)m2/s in flow bifurcations, a strong jet, and during the passage of Hurricane Isaac. The Gulf of Mexico surface velocity statistics sampled by the GLAD drifters are a strong function of the feature sampled, topography, and wind forcing

Seasonal variability in warm-water inflow towards Kangerdlugssuaq Fjord

Seasonal variability in pathways of warm water masses toward the Kangerdlugssuaq Fjord-Glacier system (KF/KG), southeast Greenland, is investigated by backtracking Lagrangian particles seeded at the fjord mouth in a high-resolution regional ocean model simulation in the ice-free and the ice-covered seasons. The waters at KF are a mixture of Atlantic-origin water advected from the Irminger Basin (FF for Faxafloi), the deep waters from the Denmark Strait and the waters from the Arctic Ocean, both represented by the Kogur section (KO). Below 200m depth, the warm water is a mixture of FF and KO water masses, and is warmer in winter than in summer. We find that seasonal differences in pathways double the fraction of FF particles in winter, causing the seasonal warming and salinification. Seasonal temperature variations at the upstream sections (FF and KO) have a negligible impact on temperature variations near the fjord. Successful monitoring of heat flux to the fjord therefore needs to take place close to the fjord, and cannot be inferred from upstream conditions.

High-Frequency Variability in the Circulation and Hydrography of the Denmark Strait Overflow from a High-resolution Numerical Model

AbstractInitial results are presented from a yearlong, high-resolution (~2 km) numerical simulation covering the east Greenland shelf and the Iceland and Irminger Seas. The model hydrography and circulation in the vicinity of Denmark Strait show good agreement with available observational datasets. This study focuses on the variability of the Denmark Strait overflow (DSO) by detecting and characterizing boluses and pulses, which are the two dominant mesoscale features in the strait. The authors estimate that the yearly mean southward volume flux of the DSO is about 30% greater in the presence of boluses and pulses. On average, boluses (pulses) are 57.1 (27.5) h long, occur every 3.2 (5.5) days, and are more frequent during the summer (winter). Boluses (pulses) increase (decrease) the overflow cross-sectional area, and temperatures around the overflow interface are colder (warmer) by about 2.6°C (1.8°C). The lateral extent of the boluses is much greater than that of the pulses. In both cases the along-stra...