Marco Benvenuti

A one-million-year-old Homo cranium from the Danakil (Afar) Depression of Eritrea

One of the most contentious topics in the study of human evolution is that of the time, place and mode of origin of Homo sapiens. The discovery in the Northern Danakil (Afar) Depression, Eritrea, of a well-preserved Homo cranium with a mixture of characters typical of H. erectus and H. sapiens contributes significantly to this debate. The cranium was found in a succession of fluvio-deltaic and lacustrine deposits and is associated with a rich mammalian fauna of early to early-middle Pleistocene age. A magnetostratigraphic survey indicates two reversed and two normal magnetozones. The layer in which the cranium was found is near the top of the lower normal magnetozone, which is identified as the Jaramillo subchron. Consequently, the human remains can be dated at ∼1 million years before present.

Facies analysis and tectonic significance of lacustrine fan-deltaic successions in the Pliocene–Pleistocene Mugello Basin, Central Italy

Abstract The Mugello Basin is an intermontane asymmetric basin, trending WNW–ESE and filled with Pliocene–Pleistocene alluvial and lacustrine deposits. The study focuses on the sedimentary succession deposited at the basins northern margin and uses facies analysis to reconstruct the margins depositional and deformation history. The controversial concepts of “fan delta” and “hyperconcentrated flow,” adopted in this study, are firstly discussed. The early Pleistocene succession consists of two higher order, coarsening-upward successions (time span ∼10 5 years), separated by an angular unconformity and referred to as the lower fan delta (LFD) and upper fan delta (UFD) systems. They show an alternation of alluvial fan, fan delta front, lacustrine, and floodplain facies associations. The alluvial facies indicate sediment dispersal by flashy, hyperconcentrated flows in the form of sheetfloods and moderately channelized flows. Deposits of the former predominate in the LFD system and deposits of the latter in the UFD system, and this change is attributed to the greater volumes of water yielded by enlarged fan catchments. The fan deltas are of Gilbert and shoal water types, indicating variable water depths at the lake margin. Each of the successions consists of fining- and coarsening-upward cyclothems of medium (tens of meters) and small scale (meters). These different-scale cycles are interpreted as the sedimentary response to pulses of a compressional deformation of the basin margin at variable frequencies, related to the contemporary Northern Apennine active thrusts (ca. 50 km away from the basin). The high-frequency flood events are attributed to episodes of heavy rainfall. The episodes of compression downwarped the basin margin alluvium, made the central lake shift periodically toward the margin, and created progressive unconformities in the sedimentary succession. The immediate effects of a compressional pulse included lake transgression and accentuation of the structural hinge of the basin margin, causing a decline of sediment supply from the catchments. As the hinge relief was subsequently reduced by denudation, the alluvial fans prograded and fan deltas were formed in normal conditions of graben subsidence. The time lag determined the amount of fine-grained sediment accumulated at the lake margin, and thus the water depth and fan delta type.

The Ziway–Shala lake basin (main Ethiopian rift, Ethiopia): a revision of basin evolution with special reference to the Late Quaternary

Abstract The Ziway–Shala basin, in the Main Ethiopian Rift (MER), is a reference site for regional to global paleoclimatic reconstructions. We undertook and interpreted a stratigraphical, pedological and geomorphological study, including a new geological map scale 1:250,000, to provide a Late Quaternary-centred revised geological history of the basin. 1 We mapped several Late Quaternary sedimentary units and arranged them in four major unconformity-bounded stratigraphic units (synthems), recording equivalent phases of geomorphic change. A new, extensive, soil survey allowed us to establish a pedostratigraphic unit, the T’ora geosol, as a distinctive marker of landscape stability and instability in the area during the Holocene. Climate change was a major control on geo-morphologic evolution of this area during the intense climate fluctuations of the last 100,000 years. Extensive lake systems developed during relatively humid Last Glacial interstadials and in the early-mid Holocene; this last was characterized by short, but high-amplitude, regressions during arid pulses. Major lakes’ lowering occurred in the terminal Pleistocene and in the last 5000 years. Evidences for high or very high terminal Pleistocene lake levels suggest possible non-climatic controls on changes in lakes’ extension and volumes between Late Pleistocene and Holocene. We suggest that modifications of hydrological thresholds, due to activity of structures parallel and transversal to the MER, established new lakes’ boundaries between terminal Pleistocene and early Holocene, setting the maximum level of Holocene lake systems at about 1670 m a.s.l. The integrated analysis of lacustrine, fluvial, slope and soil systems provided a basis for a general interpretation of relations between climatic changes and geomorphic processes at a basin scale.

Late-Holocene catastrophic floods in the terminal Arno River (Pisa, Central Italy) from the story of a Roman riverine harbour

The results of the stratigraphic and sedimentological analysis carried out at an exceptional archaeological site situated in the coastal plain of the Arno and Serchio Rivers (western Tuscany, Italy) are reported. The site, discovered near central Pisa, records a 1000-yr history of a riverine harbour built by the Etruscans and used by the Romans. This harbour was adjacent to the Arno River, located within an abandoned channel then still connected to the sea, thus allowing efficient stock transfer to and from Roman Pisa. The archaeological importance of this site is primarily due to the discovery of at least 16 well-preserved Roman ships and many other remains mostly deriving from their cargoes. The sedimentological relevance of this record is related to the recurrent, catastrophic, destruction of the harbour documented by the features of the sediment encasing the ships and by the ships’ distribution and age. Such repeated destruction was related to catastrophic flood flows generated by levee crevassing of the Arno River during high-magnitude floods that occurred between the second century BC and the fifth century AD. The Pisa harbour tells a story of river channel instability. The repeated flooding of the harbour indicates that the Roman Arno River attempted to abruptly change its course, exploiting a pre-existing river channel. The concomitance of climatic and eustatic causes is expounded upon to explain the sedimentary dynamic of a coastal floodplain during historical times.

Mercury deposits in metamorphic settings: the example of Levigliani and Ripa mines, Apuane Alps (Tuscany, Italy)

In addition to the world-class epithermal deposits in the Monte Amiata area (Southern Tuscany), mercury production in Tuscany is recorded from the Levigliani and Ripa deposits in Apuane Alps. Both deposits are hosted by sedimentary and subordinate volcanic rock sequences, belonging to the Apuane Metamorphic Complex (AMC), metamorphosed in the greenschist facies during the Apenninic orogeny (ca. 27–8 Ma). At Ripa, mineralization is very simple, consisting of cinnabar with minor pyrite in quartz gangue. Its emplacement is obviously controlled by shear structures produced during the second Apenninic deformation event (D2). At Levigliani, both the setting and the mineral assemblage are more complex. Mineralization is confined to a lithologic horizon comprised of carbonatic chloritic phyllites and calc-alkaline metabasites. The mineralizing process spanned the entire tectono-metamorphic Apenninic event. A first mineral assemblage (cinnabar I+zincian metacinnabar+pyrite) was formed under conditions presumably not far from the metamorphic thermal peak, whereas a second assemblage (cinnabar II+mercurian sphalerite+pyrite±native mercury±chalcopyrite±galena±pyrrhotite±grumiplucite) was formed in a retrograde stage. In both deposits, the overall P–T–X features of fluid inclusions in quartz are similar to those previously established for syn-metamorphic hydrothermal circulation in AMC. At Ripa, the syn-D2 shear structures provided a hydrologic trap for mercury mobilized from an unknown source. At Levigliani, the strict lithological control, the protracted nature of the mineralizing process, and the similarities to the setting of Palaeozoic peri-Mediterranean mercury deposits, suggest a small scale remobilization from a pre-existing anomaly.

Chemical speciation of Ag in galena by EPR spectroscopy

Abstract Electron paramagnetic resonance (EPR) spectroscopy has been used to study the valence state of silver in “argentiferous” galena samples from the Apuane Alps (Tuscany, Italy) mining district. This method was used to reveal primary metallic silver (Ag0) in galena. Both thermodynamic data and experimental studies suggest that galena and native silver can stably coexist, but have not been reported as a primary (hypogene) assemblage in natural samples. EPR spectroscopy proved to be a suitable tool to solve this problem, because this technique is capable of detecting paramagnetic species down to the ppb level, even in a highly absorbent matrix such as galena. A detailed SEM-EDS investigation could not detect metallic silver (or gold) in galena samples, but did reveal small (few micrometers) inclusions of Ag-bearing phases, in which silver has a formal valence of +1. On the other hand, EPR spectra indicated the presence in galena of pairs and clusters of elemental silver atoms, which may be associated with pairs of metallic gold, or with silver-gold hetero-atomic pairs. Therefore, SEM/EDS and EPR are complementary techniques, revealing the presence of both Ag+ and Ag0. The Ag(Au) metallic species were apparently deposited on the galena surface during its growth from mineralizing fluids. Their scarcity, and the presence of larger amounts of Ag1+ phases, suggest that the assemblage galena-metallic silver was stable only under peculiar physical and chemical conditions. The formation of Ag0 was presumably linked to local and rare chemical fluctuations of the hydrothermal environment, characterized by low activities of S, Sb, Bi (Cu…) and high activity of Ag in the fluids. The occurrence of both homo- and hetero-atomic pairs suggests either different kinetics of pair formation, or possible fluctuations in the composition of the hydrothermal fluids, which alternatively carried Ag or Au species, or both

Metamorphogenic barite-pyrite (Pb-Zn-Ag) veins at pollone, apuane alps, tuscany: vein geometry, geothermobarometry, fluid inclusions and geochemistry

SummaryThe barite-pyrite-(Pb-Zn-Ag) deposit of Pollone is located in the southernmost tip of the Apuane Alps metamorphic core complex, and is hosted by a siliciclastic formation of pre-Norian age. The southern sector of the deposit mainly consists of stratiform, supposedly syngenetic, barite-pyrite orebodies, whereas the northern area is characterized by a barite-pyrite-(Pb-Zn-Ag) vein system. Vein geometry in the northern area is controlled by a shear zone, developed during the greenschist facies metamorphism which affected the Apuane Alps core complex between 27 and 8 Ma, that was responsible for fluid focusing and vein emplacement. At Pollone, arsenopyrite and chlorite geothermometers show broadly comparable results, and suggest local metamorphic peak temperatures between 320 and 350°C. Phengite geobarometry indicates minimum pressures of about 3.5 kbar. Fluid inclusion data and mineral equilibria suggest that the mineralizing fluids were initially hotter than the country rocks (about 450°C at 3.5–4.0 kbar). Rocks in direct contact with the orebodies are depleted in Rb and enriched in Sr in comparison to similar rocks elsewhere in the area. This is attributed to the presence of Rb-poor muscovite and Sr-rich barite. Rb-depleted muscovites suggest mineral-fluid interaction in a rock reservoir characterized by a different (modal) mineralogical composition than the Pollone host rocks. The progressive decrease of Sr in barite with increasing distance from the orebodies may be explained with a temperature decrease along the infiltration paths of mineralizing fluids (i.e., from the vein into the wall rocks). The similar O-isotope composition of quartz from veins and host rocks is explained with the overall homogeneous O-isotope composition of the Alpi Apuane basement rocks. This indicates a limited interaction between mineralizing fluids and the rocks exposed at Pollone. Remobilization of syngenetic orebodies was conceivably of minor importance in the production of metamorphogenec veins. Fluid cooling along a major tectonic lineament is thought to be responsible for barite deposition.ZusammenfassungDie Baryt-Pyrit (Pb-Zn-Ag) Lagerstätte von Pollone liegt im südlichsten Ende des metamorphen Kern-Komplexes der Apuanischen Alpen, und sitzt in einer siliziklastischen Formation prä-Norischen Alters auf. Der südliche Sektor der Lagerstätte besteht hauptsächlich aus stratiformen, wahrscheinlich syngenetischen Baryt-Pyrit-Erzkörpern, während der nördliche Teil des Gebietes durch ein Baryt-Pyrit (Pb-Zn-Ag) Gangsystem charakterisiert wird. Die Geometrie der Gänge im Nordteil wird durch eine Scherzone kontrolliert, die während einer grünschieferfaziellen Metamorphose entstanden ist, die den Kernkomplex der Apuanischen Alpen zwischen 27 und 8 Ma betroffen hat. Diese Scherzone war auch für die Zufuhr der Fluide und die Platznahme der Gänge verantwortlich. In Pollone zeigen Arsenopyrit- und Chlorit-Geothermometrie weithin vergleichbare Ergebnisse und weisen auf lokale Maximaltemperaturen der Metamorphose zwischen 320 und 350°C hin. Phengit-Geobarometrie läßt Minimal-Drucke von ungefähr 3,5 kbar erkennen. Fluidflüssigkeitseinschluß-Daten und Mineral-Gleichgewichte zeigen, daß die erzbringenden Fluide ursprünglich heißer als die Wirtsgesteine waren (ca. 450 °C für P von 3,5 bis 4 kbar). Gesteine, die im direkten Kontakt mit den Erzkörpern sind, zeigen eine Anreicherung an Rb und eine Anreicherung an Sr, im Vergleich mit ähnlichen Gesteinen, die im Gebiet anzutreffen sind. Dies wird auf das Vorkommen von Rb-armen Muscovit und Sr-reichen Baryt zurückgeführt. An Rbabgereicherte Muscovite legen Mineral-Fluid-Reaktionen nahe, die in einem Gesteinsreservoir abliefen, das durch eine andere mineralogische Zusammensetzung als die Wirtsgesteine von Pollone charakterisiert war. Der zunehmende Verlust von Sr im Baryt mit zunehmender Entfernung von den Erzkörpern, kann durch einen Temperaturabfall entlang der Infitrations-Pfade der erzführenden Lösungen erklärt werden (d.h. von Gang in die Nebengeseine). Die ähnliche Sauerstoff-Isotopen-Zusammensetzung für Quarz aus den Gängen und den Nebengesteinen läßt sich auf die allgemein homogene Sauerstoffisotopen-Signatur des Basements der Apuanischen Alpen zurückführen. Dies weist auf beschränkte Wechselwirkung zwischen erzführenden Lösungen und den in Pollone anstehenden Gesteinen hin. Die Remobilisation von syngenetischen Erzkörpern in Pollone war nur von geringer Bedeutung für die Entstehung der metamorphogenen Gänge. Abkühlung der Fluide an einem wichtigen tektonischen Lineament gilt als Ursache für den Absatz von Baryt.

Geology of the Monte Amiata region, Southern Tuscany, Central Italy

This paper and the associated 1:50,000 geological map are devoted to describe the geological features of the Monte Amiata region. The tectono-stratigraphic setting of Monte Amiata region includes, from bottom to top, 1) the pre-Neogene stack of tectonic units, made up of Tuscan, Sub-Ligurian and Ligurian Tectonic Units, 2) the Neogene sedimentary deposits and 3) the Plei -stocene Radicofani and Monte Amiata volcanoes. The pre-Neogene stack of tectonic units includes, from bottom to top, the Tuscan Nappe, belonging to the Tuscan Domain, and Canetolo Tectonic Unit, belonging to the Sub-Ligurian Domain. These tectonic units, regarded as representative of the thinned continental margin of the Adria plate, are topped by the Santa Fiora and Ophiolitic Tectonic Units, interpreted as remnants of the Ligure-Piemontese oceanic basin and its transition to the Adria continental margin. All the tectonic units of the pre-Neogene stack have been affected by folds and thrusts originated during the convergence related to the Europe-Africa motion during the Middle Eocene-Early Miocene. Subsequently, these tectonic units were affected by a widespread reduction of thickness of their successions due to low-angle normal faulting related to the Middle Miocene extensional tectonics. The Neogene sedimentary deposits unconformably overlie the pre-Neogene stack of tectonic units. They consist of Upper Miocene to Pliocene continental and marine sediments, filling the Cinigiano-Baccinello, Velona, and Siena-Radicofani basins, adopting an informal hierarchy of different stratigraphic units where the first order units are synthems. The Pleistocene Radicofani and Monte Amiata volcanoes are made up by high-K basaltic andesitic to shoshonitic volcanic rocks and by trachydacitic to trachytic and olivine-latitic volcanic rocks, respectively. The geological mapping has provided evidences of a complex tectonic setting resulting from a long-lived history shifting from Cretaceous to Early Miocene compressive events to Middle Miocene extensional tectonics and Late Miocene-Pleistocene contractional and extensional events during which the Pleistocene magmatic activity occurred. In this regard, the Monte Amiata region can be regarded as a key area where the final result of a 200 Ma long geological history of the Northern Apennines is exposed.

Environmental mineralogy and geochemistry of waste dumps at the Pb(Zn)-Ag Bottino mine, Apuane Alps, Italy

The Bottino mine (Apuane Alps, Tuscany) had been exploited for silver and lead since at least Renaissance times. Detailed field work has led to the recognition of several mine dumps which differ in size, age, and types (rock waste dumps; jigging and handpicking wastes). In the dumps, the primary sulfides are sphalerite, galena, and pyrite ± variable amounts of chalcopyrite, pyrrhotite, arsenopyrite, and a wealth of other sulfides and sulfosalts. These mine- rals are associated with gangue quartz, white micas, chlorite, and carbonates, mostly of the siderite-magnesite and dolomite-ankerite series, whereas calcite is scarce. Supergene alteration led to the development of secondary mine- rals such as goethite, lepidocrocite, pyrolusite, cerussite, and clay minerals (kaolinite, montmorillonite, and vermi- culite). Two main types of supergene effects have been observed: (a) development in situ of pseudomorphic replacement of primary minerals, and (b) leaching and dissolution. Acid generation and metal release are mainly pro- duced by the replacement of pyrrhotite by iron hydroxides, the partial dissolution of siderite-magnesite carbonates, and the extensive dissolution/replacement of galena and sphalerite. Given the scarcity of calcite in the primary assem- blage, the most effective attenuators of acidity seem to have been dolomite-ankerite and siderite-magnesite. The mainly unpolluted character of the Bottino waters may be explained by a number of concurring factors, including the moderate volume of wastes, their overall coarse grain size, the low abundance of acid-producing phases (pyrite and pyrrhotite) relative to acid-consuming phases such as dolomite-ankerite, and the steep topography.

Geochemistry and Sr-Nd-Pb isotopes of Monte Amiata Volcano, Central Italy: evidence for magma mixing between high-K calc-alkaline and leucititic mantle-derived magmas

Monte Amiata is a small volcano composed by trachytic to olivine latitic lava flows and domes emplaced in a very short time between 305 and 231 ka. The main petrographic features are represented by the occurrence of i) abundant rounded magmatic enclaves increasing in dimension and quantity passing from early to late erupted Monte Amiata volcanic rocks, ii) large sanidine megacrysts, mainly confined in the second stage of activity characterised by the emplacement of exogenous domes and massive lava flows, and iii) mafic olivine latitic lava flows, with intermediate compositions between the early silica-rich volcanic rocks and the most mafic rounded magmatic enclaves hosted by the Monte Amiata volcanic rocks. The occurrence of rounded magmatic enclaves testifies fresh magma injection and stirring within a differentiated magma reservoir. This triggered the pouring out of the viscous trachydacitic resident magma. A reverse differentiation pathway is observed with time of magma emplacement, which is accompanied by the decrease of silica contents and increase of MgO and compatible elements passing from early trachydacites to final olivine-latites. The same timely reverse differentiation pathway is observed among magmatic enclaves, with the most mafic terms hosted by final olivine-latitic lava flows. Fine-grained rounded magmatic enclaves, indeed, range in composition from potassic trachybasalt (absarokite) to olivine-latite. The overall geochemical and isotopic features agree with a mixing process between a highly differentiated (i.e., high silica), and partially crystallised, high-K calc-alkaline end- member and a mafic ultrapotassic magma possibly leucite-bearing. Absence of leucite in the Amiata rocks and enclaves is due to high-silica activity of derived magmas caused by the high-silica end-member of the mixing process.