Marie Koike

The corrosion resistance of pure titanium in organic acids

The purpose of this study was to assess the corrosive properties of titanium at various pH values. Cast pure titanium specimens were immersed in 128 mmol/l of lactic and formic acids at pH 1.0-8.5 for 3 weeks at 37 degrees C. The solubility, color, weight and chemical binding state of specimens were observed. Titanium dissolved in all lactic acid. The amount of dissolved titanium tended to decrease with a higher pH. In formic acid, the amount of dissolved titanium at pH 1.0 was larger than that in lactic acid at the same pH, but less than the detectable limit at pH 4.0 or higher. Significant discoloration was macroscopically observed only in formic acid at pH 2.5 and 4.0. The weight of the titanium samples immersed in lactic acid all decreased, but it was not affected by pH. In formic acid, the weight decreased at pH 1.0 and increased at pH 2.5-5.5. Thickening of the TiO2 corresponding to that showing discoloration was observed in the superficial oxide film of the titanium samples. Our results show that the corrosive properties of titanium are markedly dependent on pH in formic acid, and relatively less dependent on pH in lactic acid in which titanium is dissolvable at pH 1.0-8.5.

Corrosion behavior of cast titanium with reduced surface reaction layer made by a face-coating method

This study characterized the corrosion behavior of cast CP titanium made with a face-coating method. Wax patterns were coated with oxide slurry of Y(2)O(3) or ZrO(2) before investing with a MgO-based investment. Three surface preparations were tested: ground, sandblasted, and as-cast. Uncoated castings served as controls. Sixteen-hour open circuit potential (OCP) measurement, linear polarization and potentiodynamic cathodic polarization were performed in an aerated modified Tani-Zucchi synthetic saliva at 37 degrees C. Anodic polarization was conducted in the same deaerated medium. Polarization resistance (R(p)) and Tafel slopes were determined. Corrosion current density was calculated for each specimen. Results (n=4) were subjected to nonparametric statistical analysis (alpha=0.05). Cross sections of cast specimens were examined by optical microscopy. Energy dispersive spectroscopy (EDS) spot analysis was performed at various depths below the surface. The OCP stabilized within several hours for all the specimens. Apparent differences in anodic polarization behavior were observed among the different surfaces. A distinctive wide passive region followed by breakdown was seen on specimens with ground and sandblasted surfaces. There were no significant differences in the corrosion resistance among the control and the two face-coating groups for each group. The Mann-Whitney test showed significantly lower OCP and higher R(p) values for ground surfaces. The surface condition significantly affected the corrosion behavior more than the face coating methods. In most cases, specimens with as-cast surfaces exhibited the least corrosion resistance during the potentiodynamic anodic polarization.

Evaluation of Ti-Cr-Cu alloys for dental applications

This study examined the characteristics of as-cast Ti-Cr(7–19%)-Cu(3–7%) (all percentages in this article are mass%) alloys to evaluate their suitability for dental applications; studies on the alloy structures and mechanical properties, grindability, and corrosion behavior were included in the investigation. The alloys were centrifugally cast and bench-cooled in investment molds. The x-ray diffractometry of the as-cast alloys bench-cooled in the molds indicated the following phases: α+β+ω in the 7% Cr and 7% Cr+3% Cu; β+ω in the 13%Cr; and β in the 13%Cr+3% Cu through the 19%Cr+3% Cu alloys. The strengths of the binary β Ti-Cr and ternary β Ti-Cr-Cu alloys with 13 and 19% Cr were approximately two times higher than those of CP Ti. The alloy ductility was dependent on the chemical composition and thus, the microstructure. The 7% Cr alloys were extremely brittle and hard due to the ω phase, but the ductility was restored in the 13 and 19% Cr alloys. The hardness (HV) of the cast 13 and 19% Cr alloys was approximately 300–350 compared with a value of 200 for CP Ti. The grindability of the cast alloys was examined using a rotating SiC wheel at speeds (circumferential) of 500 and 1250 m/min. At the higher speed, the grindability of the 13 and 19% Cr alloys increased with the Cu content. The grindability of the 13% Cr alloy with 7% Cu was similar to that of CP Ti. Evaluation of the corrosion behavior in an artificial saliva revealed that the alloys are like many other titanium alloys within the normal intraoral oxidation potential. The wear resistance testing of these alloys also showed favorable results.

Mechanical Properties of Cast Ti-Fe-O-N Alloys

A recent addition to existing titanium alloys is the Super-TIX™ series (Nippon Steel Corp., Japan), which has intermediate strength between the strengths of CP Ti and Ti-6Al-4V as a result of balancing the Fe, O, and N concentrations. Two alloys in this series were investigated: Ti-1%Fe-0.35%O-0.01%N (Super-TIX800™; LN) and Ti-1%Fe-0.3%O-0.04%N (Super-TIX800N™; HN). These alloys were are-melted and cast using an investment casting method, and their mechanical properties were examined. The yield strength (∼600 MPa) and tensile strength (∼680 MPa) were approximately 33 and 29% higher, respectively, than the corresponding strength of cast CP Ti (ASTM Grade 2). Their percent elongation was somewhat (but not significantly) higher (2–3 %) than that of Ti-6A-4V. On the other hand, the elongation of CP Ti was approximately 7 %. The moduli of elasticity of the alloys ranged from 100–120 GPa. These Ti-Fe-O-N alloys exhibit higher uniaxial yield and tensile strengths than CP Ti, which is currently used for dental applications.