Mark A. Yarbrough

Overview of the Radiometric Calibration of MOBY

The Marine Optical Buoy (MOBY) provides values of water- leaving radiance for the calibration and validation of satellite ocean color instruments. Located in clear, deep ocean waters near the Hawaiian Island of Lanai, MOBY measures the upwelling radiance and downwelling irradiance at three levels below the ocean surface plus the incident solar irradiance just above the surface. The radiance standards for MOBY are two integrating spheres with calibrations based on standards traceable to the National Institute of Standards and Technology (NIST). For irradiance, the MOBY project uses standard lamps that are routinely calibrated at NIST. Wavelength calibrations are conducted with a series of emission lines observed from a set of low pressure lamps. Each MOBY instrument views these standards before and after its deployment to provide system responses (calibration coefficients). During each deployment, the stability of the MOBY spectrographs and internal optics are monitored using three internal reference sources. In addition, the collection optics for the instrument are cleaned and checked on a monthly basis while the buoy is deployed. Divers place lamps over the optics before and after each cleaning to monitor changes at the system level. As a hyperspectral instrument, MOBY uses absorption lines in the solar spectrum to monitor its wavelength stability. When logistically feasible during each deployment, coincident measurements are made with the predecessor buoy before that buoys recovery. Measurements of the underwater light fields from the deployment vessel are compared with those from the buoy. Based on this set of absolute calibrations and the suite of stability reference measurements, a calibration history is created for each buoy. These calibration histories link the measurement time series from the set of MOBY buoys. In general, the differences between the pre- and post-deployment radiance calibrations of the buoys range from +1% to -6% with a definitive bias to a negative difference for the post- deployment values. This trend is to be expected after a deployment of 3 months. To date, only the pre-deployment calibration measurements have been used to adjust the system responses for the MOBY time series. Based on these results, the estimated radiometric uncertainty for MOBY in-water ocean color measurements is estimated to be about 4% to 8% (kequals1). As part of a collaboration with NIST, annual radiometric comparisons are made at the MOBY calibration facility. NIST personnel use transfer radiometers and integrating spheres to validate (verify) the accuracy of the MOBY calibration sources. Recently, we began a study of the stray light contribution to the radiometric uncertainty in the MOBY systems. A complete reprocessing of the MOBY data set, including the changes within each MOBY deployment, will commence upon the completion of the stray light characterization, which is scheduled for the fall of 2001. It is anticipated that this reprocessing will reduce the overall radiometric uncertainty to less than 5% (kequals1).

Stray-Light Correction Algorithm for Spectrographs

In this paper, we describe an algorithm to correct a spectrographs response for stray light. Two recursion relations are developed:?one to correct the system response when measuring broad-band calibration sources, and a second to correct the response when measuring sources of unknown radiance. The algorithm requires a detailed understanding of the effect of stray light in the spectrograph on the instruments response. Using tunable laser sources, a dual spectrograph instrument designed to measure the up-welling radiance in the ocean was characterized for stray light. A?stray-light correction algorithm was developed, based on the results of these measurements. The instruments response was corrected for stray light, and the effects on measured up-welling in-water radiance were evaluated.

An Example Crossover Experiment for Testing New Vicarious Calibration Techniques for Satellite Ocean Color Radiometry

Abstract Vicarious calibration of ocean color satellites involves the use of accurate surface measurements of water-leaving radiance to update and improve the system calibration of ocean color satellite sensors. An experiment was performed to compare a free-fall technique with the established Marine Optical Buoy (MOBY) measurement. It was found in the laboratory that the radiance and irradiance instruments compared well within their estimated uncertainties for various spectral sources. The spectrally averaged differences between the National Institute of Standards and Technology (NIST) values for the sources and the instruments were <2.5% for the radiance sensors and <1.5% for the irradiance sensors. In the field, the sensors measuring the above-surface downwelling irradiance performed nearly as well as they had in the laboratory, with an average difference of <2%. While the water-leaving radiance Lw calculated from each instrument agreed in almost all cases within the combined instrument uncertainties (a...

The Marine Optical BuoY (MOBY) Radiometric Calibration and Uncertainty Budget for Ocean Color Satellite Sensor Vicarious Calibration

For the past decade, the Marine Optical Buoy (MOBY), a radiometric buoy stationed in the waters off Lanai, Hawaii, has been the primary in-water oceanic observatory for the vicarious calibration of U. S. satellite ocean color sensors, including the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) and the Moderate Resolution Imaging Spectrometers (MODIS) instruments on the National Aeronautics and Space Administrations (NASAs) Terra and Aqua satellites. The MOBY vicarious calibration of these sensors supports international effort to develop a global, multi-year time series of consistently calibrated ocean color data products. A critical component of the MOBY program is establishing radiometric traceability to the International System of Units (SI) through standards provided by the U. S. National Institute of Standards and Technology (NIST). A detailed uncertainty budget is a core component of traceable metrology. We present the MOBY uncertainty budget for up-welling radiance and discuss additional considerations related to the water-leaving radiance uncertainty budget. Finally, we discuss approaches in new instrumentation to reduce the uncertainties in in situ water-leaving radiance measurements.

Stray light correction algorithm for multichannel hyperspectral spectrographs

An algorithm is presented that corrects a multichannel fiber-coupled spectrograph for stray or scattered light within the system. The efficacy of the algorithm is evaluated based on a series of validation measurements of sources with different spectral distributions. This is the first application of a scattered-light correction algorithm to a multichannel hyperspectral spectrograph. The algorithm, based on characterization measurements using a tunable laser system, can be extended to correct for finite point-spread response in imaging systems.

Stray Light Correction of the Marine Optical System

Abstract The Marine Optical System is a spectrograph-based sensor used on the Marine Optical Buoy for the vicarious calibration of ocean color satellite sensors. It is also deployed from ships in instruments used to develop bio-optical algorithms that relate the optical properties of the ocean to its biological content. In this work, an algorithm is applied to correct the response of the Marine Optical System for scattered, or improperly imaged, light in the system. The algorithm, based on the measured response of the system to a series of monochromatic excitation sources, reduces the effects of scattered light on the measured source by one to two orders of magnitude. Implications for the vicarious calibration of satellite ocean color sensors and the development of bio-optical algorithms are described. The algorithm is a one-dimensional point spread correction algorithm, generally applicable to nonimaging sensors, but can in principle be extended to higher dimensions for imaging systems.

VERTEX: biological implications of total attenuation and chlorophyll and phycoerythrin fluorescence distributions along a 2000 m deep section in the Gulf of Alaska

Abstract A 2000 m deep section of total attenuation and chlorophyll and phycoerythrin fluorescence from 26° to 59°N latitude in the northeast Pacific is discussed in terms of inferred biological processes. Photic zone distributions of these quantities vary from nutrient-limited conditions in the subtropics to light-limited conditions in the subarctic. Phycoerythrin-containing organisms, probably Synechococcus, contribute to a strong, near-surface orange fluorescence signal in the Gulf of Alaska. We now recognize that the fluorescence minimum (about 300 m) between the photic zone and the tertiary fluorescence maximum may be related to secondary producers that “repackage” organic matter produced in the photic zone. The tertiary fluorescence maximum (about 1000 m) is a continuous feature of the oxygen minimum zone in the North Pacific. The presence of phycoerythrin in the tertiary maximum is consistent with heterotrophic cyanobacteria and other unidentified microbial assemblages in the oxygen minimum, though there is no strong biological evidence that this is true.

A Method to Extrapolate the Diffuse Upwelling Radiance Attenuation Coefficient to the Surface as Applied to the Marine Optical Buoy (MOBY)

The upwelling radiance attenuation coefficient (KLu) in the upper 10 m of the water column can be significantly influenced by inelastic scattering processes, and thus will vary even with homogeneous water properties. The Marine Optical BuoY (MOBY), the primary vicarious calibration site for many ocean color sensors, makes measurements of the upwelling radiance (Lu) at 1 m, 5 m, and 9 m and uses these values to determine KLu and propagate the upwelling radiance directed toward the zenith, Lu, at 1 m to and through the surface. Inelastic scattering causes the KLu derived from the arm measurements to be an underestimate of the true KLu from 1 m to the surface at wavelengths greater than 575 nm, thus the derived water leaving radiance is underestimated at wavelengths longer than 575 nm. A method to correct this KLu, based on a model of the upwelling radiance including Raman scattering and chlorophyll fluorescence has been developed which corrects this bias. The model has been experimentally validated, and this technique can be applied to the MOBY data set to provide new, more accurate products at these wavelengths. When applied to a 4 month MOBY deployment, the corrected water leaving radiance, Lw, can increase by 5 % (600 nm), 10 % (650 nm) and 50 % (700 nm). This method will be used to provide additional more accurate products in the MOBY data set.

Results in coastal waters with high resolution in situ spectral radiometry: The Marine Optical System ROV

The water-leaving spectral radiance is a basic ocean color remote sensing parameters required for the vicarious calibration. Determination of water-leaving spectral radiance using in-water radiometry requires measurements of the upwelling spectral radiance at several depths. The Marine Optical System (MOS) Remotely Operated Vehicle (ROV) is a portable, fiber-coupled, high-resolution spectroradiometer system with spectral coverage from 340 nm to 960 nm. MOS was developed at the same time as the Marine Optical Buoy (MOBY) spectrometer system and is optically identical except that it is configured as a profiling instrument. Concerns with instrument self-shadowing because of the large exterior dimensions of the MOS underwater housing led to adapting MOS and ROV technology. This system provides for measurement of the near-surface upwelled spectral radiance while minimizing the effects of shadowing. A major advantage of this configuration is that the ROV provides the capability to acquire measurements 5 cm to 10 cm below the water surface and is capable of very accurate depth control (1 cm) allowing for high vertical resolution observations within the very near-surface. We describe the integrated system and its characterization and calibration. Initial measurements and results from observations of coral reefs in Kaneohe Bay, Oahu, extremely turbid waters in the Chesapeake Bay, Maryland, and in Case 1 waters off Southern Oahu, Hawaii are presented.

Immersion coefficient for the Marine Optical BuoY (MOBY) radiance collectors

The immersion coefficient accounts for the difference in responsivity for a radiometer placed in the air versus water or another medium. In this study, the immersion coefficients for the radiance collectors on the Marine Optical Buoy (MOBY) were modeled and measured. The experiment showed that the immersion coefficient for the MOBY radiance collectors agreed with a simple model using only the index of refraction for water and fused silica. With the results of this experiment, we estimate that the uncertainty in the current value of the immersion coefficient used in the MOBY project is 0.05 % (k = 1).