Mark Hodnett

A novel sensor for monitoring acoustic cavitation. Part I: Concept, theory, and prototype development

This paper describes a new concept for an ultrasonic cavitation sensor designed specifically for monitoring acoustic emissions generated by small microbubbles when driven by an applied acoustic field. Its novel features include a hollow, open-ended, cylindrical shape, with the sensor being a right circular cylinder of height 32 mm and external diameter 38 mm. The internal diameter of the sensor is 30 mm; its inner surface is fabricated from a 110 /spl mu/m layer of piezoelectrically active film whose measurement bandwidth is sufficient to enable acoustic emissions up to and beyond 10 MHz to be monitored. When in use, the sensor is immersed within the liquid test medium and high frequency (megahertz) acoustic emissions occurring within the hollow body of the sensor are monitored. In order to shield the sensor response from events occurring outside the cylinder, the outer surface of the sensor cylinder is encapsulated within a special 4 mm thick polyurethane-based cavitation shield with acoustic properties specifically developed to be minimally perturbing to the 40 kHz applied acoustic field but attenuating to ultrasound generated at megahertz frequencies (plane-wave transmission loss >30 dB at 1 MHz). This paper introduces the rationale behind the new sensor, describing details of its construction and the materials formulation program undertaken to develop the cavitation shield.

Validated ultrasonic power measurements up to 20 w

A project has been completed to develop reference methods for the measurement of ultrasonic power with a validated measurement uncertainty of < 7% at power levels of 1 to 20 W over the frequency range 1 to 3 MHz of collimated beams. The project is the result of collaborative research between the Physikalisch-Technische Bundesanstalt, Germany (PTB, DE), the National Physical Laboratory, UK (NPL, UK) and the Netherlands Organisation for Applied Scientific Research, Prevention and Health (TNO-PG, NL). The work has been undertaken under the 4th Framework Programme of the European Community (EC). Primary standard designs of radiation force balances based on both absorbing and reflecting targets have been constructed. To avoid heating effects, the measurements should be done relatively quickly (10 to 20 s). The methods have been validated using ultrasound (US) transducers that demonstrated an adequate short and long-term stability; a method to detect cavitation based on monitoring the acoustic signals produced by bubble oscillation and collapse has been confirmed. It has been shown that only the detection of the subharmonic can be used in practice as cavitation detector. Different procedures for obtaining degassed water have been investigated. A method showing significant promise to be used in a clinical or manufacturers environment involves the addition of sodium sulphite (Na2SO3). During the validation process, commercially available radiation force balances and ultrasonic physiotherapy devices have also been evaluated. Limitations of current measurement methods and practices, including power measurements made on transducers exhibiting a diverging beam, have been identified. It has been shown that a reflecting target is not appropriate to measure powers of transducers with a ka-value < 30. Based on beam shape and target distance, it has been shown also that proper power measurements using a 45 degrees convex-conical reflecting target can never be performed for transducers with a ka-value < 17.4.

Toward a reference ultrasonic cavitation vessel: Part 2-investigating the spatial variation and acoustic pressure threshold of inertial cavitation in a 25 kHz ultrasound field

As part of an ongoing project to establish a reference facility for acoustic cavitation at the National Physical Laboratory (NPL), carefully controlled studies on a 25 kHz, 1.8 kW cylindrical vessel are described. Using a patented high-frequency acoustic emission detection method and a sonar hydrophone, results are presented of the spatial variation of inertial acoustic cavitation with increasing peak-negative pressure. Results show that at low operating levels, inertial acoustic cavitation is restricted to, and is strongly localized on, the vessel axis. At intermediate power settings, inertial acoustic cavitation also occurs close to the vessel walls, and at higher settings, a complex spatial variation is seen that is not apparent in measurements of the 25 kHz driving field alone. At selected vessel locations, a systematic investigation of the inertial cavitation threshold is described. This was carried out by making simultaneous measurements of the peak-negative pressures leading to inertial cavitation and the resultant MHz-frequency emissions, and indicates an inertial cavitation threshold of 101 kPa plusmn 14% (estimated expanded uncertainty). However, an intermediate threshold at 84 kPa plusmn 14% (estimated expanded uncertainty) is also seen. The results are discussed alongside theoretical predictions and recent experimental findings.

A strategy for the development and standardisation of measurement methods for high power/cavitating ultrasonic fields : review of high power field measurement techniques

This review was compiled as part of a project to formulate a UK strategy for the development and standardisation of measurement methods for high power/cavitating ultrasonic fields. It reviews the scientific literature relating to various methods of measuring high power fields which have been developed for application in health care, sonochemistry and industrial ultrasonics, and compares these methods in terms of attributes such as spatial resolution, bandwidth and sensitivity.

Influence of acoustic cavitation on the controlled ultrasonic dispersion of carbon nanotubes.

Ultrasonication is the most widely used technique for the dispersion of a range of nanomaterials, but the intrinsic mechanism which leads to stable solutions is poorly understood with procedures quoted in the literature typically specifying only extrinsic parameters such as nominal electrical input power and exposure time. Here we present new insights into the dispersion mechanism of a representative nanomaterial, single-walled carbon nanotubes (SW-CNTs), using a novel up-scalable sonoreactor and an in situ technique for the measurement of acoustic cavitation activity during ultrasonication. We distinguish between stable cavitation, which leads to chemical modification of the surface of the CNTs, and inertial cavitation, which favors CNT exfoliation and length reduction. Efficient dispersion of CNTs in aqueous solution is found to be dominated by mechanical forces generated via inertial cavitation, which in turn depends critically on surfactant concentration. This study highlights that careful measurement and control of cavitation rather than blind application of input power is essential in the large volume production of nanomaterial dispersions with tailored properties.

A new method for measuring the effective radiating area of physiotherapy treatment heads

This paper describes the investigation and validation of a new method for measuring the effective radiating area (AER) of physiotherapy ultrasound treatment heads. The method is based on the use of a conventional radiation force balance, but employs special attenuating apertures that are used to selectively mask off different areas of the treatment head. The resultant reduction in the radiating surface is accompanied by a decrease in output power that is measured using the force balance. The AER of the treatment head is derived from an analysis of the measurements, which essentially involves initially evaluating the minimum area through which 75% of the acoustic power is transmitted. AER values derived using the new method are presented for 17 treatment heads representative of the range of physiotherapy systems commonly used in clinical practice. These are compared to reference values derived using hydrophone scanning, according to the recently published International Standard, IEC 1689. Typical levels of agreement between values of AER derived using the two techniques are +/- 11%. The potential of the method as a rapid, relatively low-cost, means of measuring treatment head AER, applicable in both manufacturing and hospital environments, is assessed.

Characterisation and improvement of a reference cylindrical sonoreactor

This paper describes theoretical and experimental methods for characterising the performance of a 25 kHz sonochemical reactor (RV-25), which is being developed as a reference facility for studying acoustic cavitation at the National Physical Laboratory (NPL). Field measurements, acquired in different locations inside the sonoreactor, are compared with finite element models at different temperatures, showing that relatively small temperature variations can result in significant changes in the acoustic pressure distribution (and consequent cavitation activity). To improve stability, a deeper insight into the way energy is transferred from the power supply to the acoustic field is presented, leading to criteria - based on modal analysis - to dimension and verify an effective temperature control loop. The simultaneous use of measurements and modelling in this work produced guidelines for the design of multi-frequency cylindrical sonoreactors, also described.

Self-sensing ultrasound transducer for cavitation detection

Cavitation monitoring is desired to optimize the sonication for diverse sonochemical processes and to detect changes or malfunctions during operation. In situ cavitation measurements can be carried out by detection of the acoustic emissions of cavitation bubbles by sensors in the liquid. However, in harsh environments sensors might not be applicable. Thus, the impact of cavitation on the electrical signals of a piezoelectric transducer has been analyzed as alternative method to measure the threshold, strength and type of cavitation. The applicability has been tested in three different setups to evaluate the generalizability of extracted indicators. In all setups indicators for the cavitation thresholds could be derived from the current signal. In two setups features showed two thresholds that may be linked to the types of cavitation. However, only one feature derived from the current signal in one particular setup correlated to the strength of cavitation. Cavitation detection based on the current signal of the transducer is a useful method to detect cavitation in harsh environments and without perturbing the sound field. Once applicable indicators have been identified, they may easily be tracked during the process. However, for more detailed studies about the cavitation activity and its spatial distribution, measurements with in situ sensors are recommended.

Progress in developing a thermal method for measuring the output power of medical ultrasound transducers that exploits the pyroelectric effect.

Progress in developing a new measurement method for ultrasound output power is described. It is a thermal-based technique with the acoustic power generated by a transducer being absorbed within a specially developed polyurethane rubber material, whose high absorption coefficient ensures energy deposition within a few mm of the ultrasonic wave entering the material. The rate of change of temperature at the absorber surface is monitored using the pyroelectric voltage generated from electrodes disposed either side of a 60 mm diameter, 0.061 mm thick membrane of the piezoelectric polymer polyvinylidene fluoride (pvdf) bonded to the absorber. The change in the pyroelectric output voltage generated by the sensor when the transducer is switched ON and OFF is proportional to the delivered ultrasound power. The sensitivity of the device is defined as the magnitude of these switch voltages to a unit input stimulus of power (watt). Three important aspects of the performance of the pyroelectric sensor have been studied. Firstly, measurements have revealed that the temperature dependent sensitivity increases over the range from approximately 20°C to 30°C at a rate of +1.6% °C(-1). Studies point to the key role that the properties of both the absorbing backing layer and pvdf membrane play in controlling the sensor response. Secondly, the high sensitivity of the technique has been demonstrated using an NPL Pulsed Checksource, a 3.5 MHz focused transducer delivering a nominal acoustic power level of 4 mW. Finally, proof-of-concept of a new type of acoustic sensor responding to time-averaged intensity has been demonstrated, through fabrication of an absorber-backed hydrophone of nominal active element diameter 0.4 mm. A preliminary study using such a device to resolve the spatial distribution of acoustic intensity within plane-piston and focused 3.5 MHz acoustic fields has been completed. Derived beam profiles are compared to conventional techniques that depend on deriving intensity from acoustic pressure measurements made using the sensor as a calibrated hydrophone.

Novel sensors for monitoring acoustic cavitation

This paper describes a novel acoustic sensor of potential application in monitoring cavitation occurring within ultrasonic cleaning vessels. The sensors, fabricated in the form of hollow cylinders, are manufactured from a thin (110 /spl mu/m) piezoelectric polymer whose acoustic bandwidth (10 MHz) is sufficient to detect the high-frequency signals generated by cavitating bubble collapse. One of the key characteristics of the sensors is their spatial resolution: acoustic signals detected at high frequencies originate from bubble events occurring within the hollow cylinder itself. To isolate these, the cavitation sensors are encapsulated in a 4 mm thick layer of a specially-developed acoustical absorber acting as a shield to bubble events occurring outside of the sensor volume. The construction of the new sensor is described, and early results of its response in the acoustic field of an ultrasonic cleaning vessel are presented.