Mark W. Miller

Continental bedrock and riverine fluxes of strontium and neodymium isotopes to the oceans

Realistic models of past climate and ocean chemistry depend on reconstructions of the Earths surface environments in the geologic past. Among the critical parameters is the geologic makeup of continental drainage. Here we show, for the present, that the isotope composition of dissolved strontium in rivers increases linearly with the age of bedrock in drainage basins, with the notable exception of the drainage area of Arabia, India, and Southeast Asia that is affected by unusually radiogenic dissolved Sr from the Himalaya. We also demonstrate that the neodymium isotope compositions of suspended matter in rivers as well as clastic sediments deposited along the ocean margins decrease linearly with the bedrock ages of river drainage basins and large-scale continental drainage regions, as determined from digital geologic maps. These correlations are used to calculate the present-day input of dissolved Sr (4.7 × 1010 mol yr−1, 87Sr/86Sr of ∼0.7111) and particulate Nd isotopes (ɛNd of approximately −7.3 ± 2.2) to the oceans. The fact that the regionally averaged ɛNd of the global detrital input to the global coastal ocean is identical to globally averaged seawater (ɛNd of −7.2 ± 0.5) lends credence to the importance of “boundary exchange” for the Nd isotope composition of water masses. Regional biases in source areas of detrital matter and runoff are reflected by the observation that the average age of global bedrock, weighted according to the riverine suspended sediment flux, is significantly younger (∼336 Myr) than the age of global bedrock weighted according to water discharge (394 Myr), which is younger than the average bedrock age of the nonglaciated, exorheic portions of the continents (453 Myr). The observation that the bedrock age weighted according to Sr flux is younger (339 Myr) than that weighted according to water flux reflects the disproportionate contribution from young sedimentary and volcanic rocks to the dissolved Sr load. Neither the isotope composition of the dissolved nor the particulate continental inputs to the ocean provide unbiased perspectives of the lithologic makeup of the Earths surface. Temporal changes in bedrock geology as well as the shifting focal points of physical erosion and water discharge will undoubtedly have exerted strong controls on temporal and spatial changes in the isotope chemistry of past global runoff and thus seawater.

Quantitative bedrock geology of the continents and large-scale drainage regions

We quantitatively analyze the area-age distribution of sedimentary, extrusive volcanic, and endogenous (plutonic and/or metamorphic) bedrock on the basis of data from the most recent digital Geological Map of the World at a scale of 1:25,000,000. The spatial resolution of the digital bedrock data averages 13,905 km2 per polygon. Comparison of certain regions of the world, previously analyzed at higher spatial resolution, with the low-resolution world data reveals general consistency in the areal exposure of major rock types as well as a minor systematic bias toward older average bedrock ages in the global data set. Application of the global bedrock data to 19 large-scale drainage regions and three large, internally drained regions reveals considerable regional variability of Earths bedrock geology that is consistent with the dominant geotectonic setting of the respective drainage region.