Maryse H. Delevaux

The potential source of lead in the Permian Kupferschiefer bed of Europe and some selected Paleozoic mineral deposits in the Federal Republic of Germany

New lead isotopic compositions have been measured for Paleozoic bedded and vein ore deposits of Europe by the high precision thermal emission (triple filament) technique. Eleven samples have been analyzed from the Upper Permian Kupferschiefer bed with representatives from Poland to England, three samples from the Middle Devonian Rammelsberg deposit and one from the Middle Devonian Meggen deposit, both of which are conformable ore lenses and are in the Federal Republic of Germany (FRG); and also two vein deposits from the FRG were analyzed, from Ramsbeck in Devonian host rocks and from Grund in Carboniferous host rocks. For Kupferschiefer bed samples from Germany, the mineralization is of variable lead isotopic composition and appears to have been derived about 250 m.y. ago from 1700 m.y. old sources, or detritus of this age, in Paleozoic sedimentary rocks. Samples from England, Holland, and Poland have different isotopic characteristics from the German samples, indicative of significantly different source material (perhaps older). The isotopic variability of the samples from the Kupferschiefer bed in Germany probably favors the lead containing waters coming from shoreward (where poor mixing is to be expected) rather than basinward (where better mixing is likely) directions. The data thus support the interpretation of the metal source already given by Wedepohl in 1964. Data on samples from Rammelsberg and Meggen tend to be slightly less radiogenic than for the Kupferschiefer, about the amount expected if the leads were all derived from the same source material but 100 to 150 m.y. apart in time. The vein galena from Ramsbeck is similar to that from Rammelsberg conformable ore lenses, both in rocks of Devonian age; vein galena from Grund in Upper Carboniferous country rocks is similar to some bedded Kupferschiefer mineralization in Permian rocks, as if the lead composition was formed at about the same time and from similar source material as the bedded deposits. Although heat has played a more significant role in the formation of some of these deposits (veins and Rammelsberg-Meggen) than in others (Kupferschiefer), there is no indication of radically different sources for the lead, all apparently coming from sedimentary source material containing Precambrian detritus. One feldspar lead sample from the Brocken-Oker Granite is not the same in isotopic composition as any of the ores analyzed.

Variations in Lead-Isotopic Compositions in Mesozoic Granitic Rocks of California: A Preliminary Investigation

Six alkali feldspar and two whole-rock samples of granitic rocks from the Sierra Nevada batholith and adjacent Klamath Mountains were analyzed for their lead-isotope compositions. The samples represented each of three 87 Sr/ 86 Sr groupings ( 0.706) for granitic rocks north of the Garlock fault in California. The isotopic compositions of lead in the samples from the Sierra Nevada batholith range from 18.73 to 19.37 for 206 Pb/ 204 Pb, 15.61 to 15.71 for 207 Pb/ 204 Pb, and 38.44 to 39.10 for 208 Pb/ 204 Pb. A crude parallel correspondence was found between lead and strontium isotopes, in that the specimens with the most radiogenic strontium also tend to have the most radiogenic lead similar to the previously studied Boulder batholith of Montana. A parallel correspondence is thought to imply characteristics of the source rocks for the plutons rather than consequences of partial melting or natural contamination. Lead-isotopic compositions for the Sierra Nevada batholith and the Boulder batholith differ, average values of 206 Pb/ 204 Pb being at least 18.8 for the Sierra Nevada batholith and about 18 for the Boulder batholith. In the Late Cretaceous part of the Sierra Nevada batholith, the secondary isochron “age” for the lead data in these rocks is about 2,900 m.y., far older than known Precambrian in California. Sources are proposed for these plutons from the lower continental crust and upper continental mantle or dominantly recycled continental materials, probably of intermediate composition and possibly carried down to the zone of melting by subduction. This source material may have been formed in Pre-cambrian times but did not undergo a Precambrian metamorphism greater than upper amphibolite facies which would have reduced the values of 238 U/ 204 Pb in the source rocks and resulted in Mesozoic leads like those found in the Boulder batholith and elsewhere in the Rocky Mountain region. A trondhjemite from the Klamath Mountains has a lead-isotope composition ( 206 Pb/ 204 Pb, 18.57; 207 Pb/ 204 Pb, 15.50; 208 Pb/ 204 Pb, 38.08) similar to that of oceanic volcanic rocks, particularly like those of island volcanics on oceanic ridges. Derivation of this trondhjemite from an oceanic mantle or recycled mantle material is indicated by this observation and supports the conclusion of Kistler and Peterman (1973) based on its alkali abundances and 87 Sr/ 86 Sr value.

Lead and strontium isotopic evidence for crustal interaction and compositional zonation in the source regions of Pleistocene basaltic and rhyolitic magmas of the Coso volcanic field, California

The isotopic compositions of Pb and Sr in Pleistocene basalt, high-silica rhyolite, and andesitic inclusions in rhyolite of the Coso volcanic field indicate that these rocks were derived from different levels of compositionally zoned magmatic systems. The 2 earliest rhyolites probably were tapped from short-lived silicic reservoirs, in contrast to the other 36 rhyolite domes and lava flows which the isotopic data suggest may have been leaked from the top of a single, long-lived magmatic system. Most Coso basalts show isotopic, geochemical, and mineralogic evidence of interaction with crustal rocks, but one analyzed flow has isotopic ratios that may represent mantle values (87Sr/86Sr=0.7036,206Pb/204Pb=19.05,207Pb/204Pb=15.62,208Pb/204Pb= 38.63). The (initial) isotopic composition of typical rhyolite (87Sr/86Sr=0.7053,206Pb/204Pb=19.29,207Pb/204Pb= 15.68,208Pb/204Pb=39.00) is representative of the middle or upper crust. Andesitic inclusions in the rhyolites are evidently samples of hybrid magmas from the silicic/mafic interface in vertically zoned magma reservoirs. Silicic end-member compositions inferred for these mixed magmas, however, are not those of erupted rhyolite but reflect the zonation within the silicic part of the magma reservoir. The compositional contrast at the interface between mafic and silicic parts of these systems apparently was greater for the earlier, smaller reservoirs.

Lead Isotope Variation with Growth Zoning in a Galena Crystal

A large crystal of lead sulfide from Picher, Oklahoma, has significant differences in isotopic composition of lead in successive growth zones. Lead isotope ratios in the parent ore-fluid evidently changed with time during crystal growth. The growth history of this crystal, interpreted quantitatively, points to a tentative hypothesis of genesis of Mississippi Valley deposits of lead and zinc.