Masahiko Yamada

Development of a hybrid catalytic combustor for a 1300°C class gas turbine

Abstract The hybrid catalytic combustor concept proposed by the authors has an advantage concerned with catalyst durability, because the catalyst is maintained below 1000°C even for application to 1300°C class gas turbines. A full-scale hybrid catalytic combustor has been designed for a 200 MW (1300°C) class gas turbine. The catalyst bed was 450 mm in diameter and consisted of a Pd/ alumina washcoat on a cordierite monolith. In experiments, the combustor has demonstrated the capability of meeting the NO x emission level of SCR (selected catalytic reduction) during atmospheric pressure testing. To predict the catalyst performance at an elevated pressure, the characteristics of the catalyst were studied using a small scale reactor test, and a material property test using a DTA/TGA-Q.MASS system. The catalyst showed a higher activity in the oxidized state (PdO) than in the metallic state (Pd). This activity difference was governed by the equilibrium of the oxygen release from PdO in bulk. It was considered that oxidation rate of the metallic Pd in bulk was not so high and this caused self-oscillation for the Pd catalyst around the temperature of the oxygen release equilibrium. Even below the temperature of the oxygen release equilibrium, both surface and bulk (lattice) oxygen of the PdO was consumed by the methane oxidation reaction, and resulted in a lack of surface oxygen on the catalyst. This caused a reversible decrease in the catalyst activity during combustion testing, and indicated that the oxygen dissociation step was a rate limiting step in the catalytic combustion.

Effect of Pressure on Combustion Characteristics in LBG-Fueled 1300°C-Class Gas Turbine

Developing integrated coal gasification combined cycle systems ensures that Japan will have cost-effective and environmentally sound options for supplying future power generation needs. Reduction of NO[sub x] emissions and increasing the inlet temperature of gas turbines are the most significant issues in gas turbine development in IGCC. The coal gasified fuel, which is produced in a coal gasifier of air blown entrained-flow type has a calorific value as low as 1/10 of natural gas. Furthermore, the fuel gas contains ammonia when a gas cleaning system is a hot type, and ammonia will be converted to nitrogen oxides in the combustion process of a gas turbine. The study is performed in 1,300 C-class gas turbine combustor firing coal-gasifier fuel in IGCC power generation systems. In the previous study the advanced rich-lean combustor of 150-MW class gas turbine was designed to hold stable combustion burning low-Btu gas fuel and to reduce fuel NO[sub x] emission that is produced from the ammonia in the fuel. By testing it under atmospheric pressure conditions, they have studied the effects of fuel parameters on combustor performances and listed the basic data for development applications. In this study, by testing it under pressurized conditions, they have obtainedmorexa0» a very significant result through investigating the effect of pressure on combustion characteristics and wish to provide herein a summary of their findings.«xa0less

A Study of Low NOx Combustion in Medium-Btu Fueled 1300 °C-Class Gas Turbine Combustor in IGCC

The development of integrated coal gasification combined cycle (IGCC) systems ensures cost-effective and environmentally sound options for supplying future coal utilizing power generation needs. The Japanese government and the electric power industries in Japan promoted research and development of an IGCC system using an air-blown entrained-flow coal gasifier. We worked on developing a low-Btu fueled gas turbine combustor to improve the thermal efficiency of the IGCC by raising the inlet-gas temperature of gas turbine.On the other hand, Europe and the United States are now developing the oxygen-blown IGCC demonstration plants. Coal gasified fuel produced in an oxygen-blown entrained-flow coal gasifier, has a calorific value of 8.6MJ/m 3 which is one fifth that of natural gas. However, the adiabatic flame temperature of oxygen-blown medium-Btu coal gaseous fuel is higher than that of natural gas and so NOx production from nitrogen fixation is expected to increase significantly. In the oxygen-blown IGCC system, a surplus nitrogen in quantity is produced in the oxygen-production unit. When nitrogen premixed with coal gasified fuel is injected into the combustor, the power to compress nitrogen increases. A low NOx combustion technology which is capable of decreasing the power to compress nitrogen is a significant advance in gas turbine development with an oxygen-blown IGCC system. We have started to develop a low NOx combustion technology using medium-Btu coal gasified fuel produced in the oxygen-blown IGCC process.In this paper, the effect of nitrogen injected directly into the combustor on the thermal efficiency of the plant is discussed. A 1300 °C-class gas turbine combustor with a swirling nitrogen injection function designed with a stable and low NOx combustion technology was constructed and the performance of this combustor was evaluated under atmospheric pressure conditions. Analyses confirmed that the thermal efficiency of the plant improved by 0.2 percent (absolute), compared with a case where nitrogen is premixed with coal gasified fuel before injection into the combustor. Moreover, this new technique which injects nitrogen directly into the high temperature region in the combustor results in a significant reduction in NOx production from nitrogen fixation. We estimate that CO emission concentration decreases to a significant level under high pressure conditions, while CO emission concentration in contrast to NOx emission rises sharply with increases in quantity of nitrogen injected into the combustor.Copyright

Effect of Pressure on Combustion Characteristics in LBG–Fueled 1300°C–Class Gas Turbine

Developing integrated coal gasification combined cycle systems ensures that Japan will have cost–effective and environmentally sound options for supplying future power generation needs. The reduction of NOx emissions and increasing the inlet temperature of gas turbines are the most significant issues in gas turbine development in IGCC. The coal gasified fuel, which is produced in a coal gasifier of air–blown entrained–flow type has calorific value as low as 1/10 of natural gas. Furthermore the fuel gas contains ammonia when a gas cleaning system is a hot type, and ammonia will be converted to nitrogen oxides in the combustion process of a gas turbine.The study is performed in 1300°C–class gas turbine combustor firing coal–gasified fuel in IGCC power generation systems. In the previous study the advanced rich–lean combustor of 150–MW class gas turbine was designed to hold stable combustion burning low–Btu gas fuel and to reduce fuel NOx emission that is produced from the ammonia in the fuel. By testing it under atmospheric pressure conditions, we have studied the effects of fuel parameters on combustor performances and listed the basic data for development applications. In this study, by testing it under pressurized conditions, we have obtained a very significant result through investigating the effect of pressure on combustion characteristics and wish to provide herein a summary of our findings.Copyright

Design and Test of a Low-NOx Advanced Rich-Lean Combustor for LBG Fueled 1300°C-Class Gas Turbine

Research and development of an IGCC (Integrated Coal Gasification Combined Cycle) power generation system is being carried out as one of the advanced coal utilization technology in Japan. The coal gasified fuel, which is produced in a coal gasifier of air-blown entrained-flow type has calorific value as low as 1/10 of LNG. Furthermore, the fuel gas contains ammonia when a gas cleaning system is a hot type, and ammonia will be converted to nitrogen oxides in the combustion process of a gas turbine. The authors have designed and made an 1300°C-class advanced rich-lean combustor mainly designed for achieving low fuel-NOx combustion. By testing it under atmospheric pressure conditions, we have successfully reduced the NOx emissions (to 60 ppm corrected at 16 percent O2) by more than half the level previously achieved when the ammonia concentration was 1000 ppm. Combustion stability was adequate even when the calorific value of the fuel decreased to 2700 kJ/m3N.Copyright

Coal Gaseous Fueled, Low Fuel-NOx Gas Turbine Combustor

From the view point of future coal utilization technology for the thermal power generation systems, the coal gasification combined cycle system has drawn special interest recently. In the coal gasification combined cycle power generation system, it is necessary to develop a high temperature gas turbine combustor using a low–BTU gas (LBG) which has high thermal efficiency and low emissions.In Japan a development program on the coal gasification combined cycle power generation system has started in 1985 by the national government and Japanese electric companies. In this program, is planned to develop the 1300 °C class gas turbines. However, in the case of using a hot type fuel gas cleaning system, the coal gas fuel to be supplied to gas turbines will contain ammonia. Ammonia will be converted to nitric oxides in the combustion process in gas turbines. Therefore, low fuel–NOx combustion technology is one of the most important research subjects.This paper describes low fuel–NOx combustion technology for 1300 °C class gas turbine combustor using low BTU coal gas fuel.Authors have showed that the rich–lean combustion method is effective to decrease fuel–NOx (1). In general in rich–lean combustion method, the fuel–NOx decreases, as the primary zone becomes richer. But flameholding becomes very difficult in even rich primary zone. For this reason this combustor was designed to have a flameholder with pilot flame.Combustion tests were conducted by using a full scale combustor used in 150 MW gas turbine at the atmospheric pressure condition.Copyright