Masanao Terashima

The synthesis of 4-substituted isoquinoline derivatives from diethyl(4-isoquinolyl)borane

Reaction du borane du titre avec R-Br (R=aryl, heteryl, alcenyl) en presence de complexe de Pd0: obtention de R-4 isoquinoleines

The pyridyl cation as a reactive intermediate in the photoreaction of iodopyridines with benzenes

Abstract The electrophilic behavior of the reactive entity in the phtosubstitution of benzenes with 2-iodopyridine was found to be ascribable to the intermediary 2-pyridyl cation, rather than to the electrophilic 2-pyridyl radical.

A novel synthetic use of trialkyl(indol-2-yl)borate for a one-pot synthesis of [a]-annelated indoles

Abstract A novel one-pot procedure for [ a ]-annelated indole via cyclic trialkyl(indol-2-yl)borate is described.

Synthesis of Heteroarylquinolines by the Photolysis of 2-, 3-, and 4-Iodoquinolines

Photoreaction of 2-, 3-, and 4-iodoquinolines with five membered heterocycles (i.e. 1-methylpyrrole, pyrrole, furan and thiophene) afforded the corresponding n(2-heteroaryl)quinolines (n=2, 3, 4) in appreciable yields.

A facile synthesis of N-(2- and 4-pyridyl) indoles

The reactions of the sodium salts of indoles with 2- and 4-fluoropy- ridines afforded the corresponding N-pyridylindoles in good yields, whereas the reaction with 3-fluoropyridine gave no coupling product

1-(2-Oxazolinyl) indoles

Utilization of 1-(2-oxazolinyl) indoles, prepared from 1-cyano compounds, to the synthesis of 2-substituted indoles was investigated

Boron-Substituted Heteroaromatic Compounds

Publisher Summary The enormous developments in the chemistry of organoboranes and related compounds during the last two decades have contributed greatly to the recent progress of synthetic organic chemistry. The chemistry of boron-containing heterocycles is diverse. A variety of heteroaromatic compounds having a boron atom in the ring, borazaromatics for example, has been investigated, mostly due to their interesting physical and chemical properties. A number of derivatives of boron have been synthesized and evaluated for the potential use in cancer therapy. In some cases, the reaction of heterocycles with various boron reagents involves their derivatives as crucial reaction intermediates. This chapter deals with the chemistry of heteroaromatic compounds directly substituted on a ring carbon with a boron atom.

A new synthesis of anthramycin via palladium-catalysed carbonylation

A New method for the preparation of pyrrolo [1,4]benzodiazepinone derivatives using palladium-catalysed carbonylation has led to a formal synthesis of anthramycin.

An Effecient Synthesis of 2-Aroly-1H-indoles

2-Aroyl-1H-indoles were directly obtained by the reaction of 1-(N-aroylcarbamoyl) indoles, prepared from 1-(2-oxazolinyl) indole and aroyl chlorides, with LDA

Vinyloxyborane promoted 1,4-addition of triethyl (1-methylindol-2-yl)borate to 2-cycloalkenones

The conjugate addition reaction of triethyl(1- methyl-indol-2-yl) borate to 2-cycloalkenone could be effected with a catalytic amount of vinyloxyborane