Mianqi Xue

Observation of the Chiral-Anomaly-Induced Negative Magnetoresistance in 3D Weyl Semimetal TaAs

Xiaochun Huang, Lingxiao Zhao, Yujia Long, Peipei Wang, Dong Chen, Zhanhai Yang, Hui Liang, Mianqi Xue, Hongming Weng, Zhong Fang, Xi Dai, and Genfu Chen Beijing National Laboratory for Condensed Matter Physics, and Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China Collaborative Innovation Center of Quantum Matter, Beijing 100084, China (Received 14 May 2015; published 24 August 2015)

Superconductivity above 30 K in alkali-metal-doped hydrocarbon

The recent discovery of superconductivity with a transition temperature (Tc) at 18 K in Kxpicene has extended the possibility of high-Tc superconductors in organic materials. Previous experience based on similar hydrocarbons, like alkali-metal doped phenanthrene, suggested that even higher transition temperatures might be achieved in alkali-metals or alkali-earth-metals doped such polycyclic-aromatic-hydrocarbons (PAHs), a large family of molecules composed of fused benzene rings. Here we report the discovery of high-Tc superconductivity at 33 K in K-doped 1,2:8,9-dibenzopentacene (C30H18). To our best knowledge, it is higher than any Tc reported previously for an organic superconductor under ambient pressure. This finding provides an indication that superconductivity at much higher temperature may be possible in such PAHs system and is worthy of further exploration.

Superconductivity in potassium-doped few-layer graphene.

Here we report the successful synthesis of superconducting potassium-doped few-layer graphene (K-doped FLG) with a transition temperature of 4.5 K, which is 1 order of magnitude higher than that observed in the bulk potassium graphite intercalation compound (GIC) KC(8) (T(c) = 0.39 K). The realization of superconductivity in K-doped FLG shows the potential for the development of new superconducting electronic devices using two-dimensional (2D) graphene as a basis material.

High-Oriented Polypyrrole Nanotubes for Next-Generation Gas Sensor.

Highly oriented PPy nanotubes are grown by in situ vapor phase polymerization within a nanoscale template under low temperature. As-fabricated PPy nanotubes are used for gas sensing, where an ultralow detection limit (0.05 ppb) and very fast response are achieved. Such an in situ mass-productive method for synthesizing highly oriented conducting polymers may pave a new step toward next-generation gas sensors.

Novel Metal Chalcogenide SnSSe as a High-Capacity Anode for Sodium-Ion Batteries

A novel layered SnSSe material is designed as a high-performance anode for sodium-ion batteries with characteristics of high capacity, superior cyclability, facile synthetic method, and large-scale production ability. The transformation from bulk SnSSe particles into closely packed nanoplate aggregates with greater resistance to structure pulverization and the partial pseudocapacitive capacity contribution may engender excellent cycling performance and rate capability.

Single‐Crystal‐Conjugated Polymers with Extremely High Electron Sensitivity through Template‐Assisted In Situ Polymerization

Single-crystal-conjugated polymer (SCCP) arrays are prepared successfully via a simple method, which is a combination of the contact thermochemical reaction and solvent-free in situ polymerization. The dramatic X-ray diffraction and selective-area electron diffraction results show the high crystallinity of the SCCP arrays. These SCCP arrays display unique physical properties and show great potential in flexible electronics.

Atom-Thin SnS2–xSex with Adjustable Compositions by Direct Liquid Exfoliation from Single Crystals

Two-dimensional (2D) chalcogenide materials are fundamentally and technologically fascinating for their suitable band gap energy and carrier type relevant to their adjustable composition, structure, and dimensionality. Here, we demonstrate the exfoliation of single-crystal SnS2-xSex (SSS) with S/Se vacancies into an atom-thin layer by simple sonication in ethanol without additive. The introduction of vacancies at the S/Se site, the conflicting atomic radius of sulfur in selenium layers, and easy incorporation with an ethanol molecule lead to high ion accessibility; therefore, atom-thin SSS flakes can be effectively prepared by exfoliating the single crystal via sonication. The in situ pyrolysis of such materials can further adjust their compositions, representing tunable activation energy, band gap, and also tunable response to analytes of such materials. As the most basic and crucial step of the 2D material field, the successful synthesis of an uncontaminated and atom-thin sample will further push ahead the large-scale applications of 2D materials, including, but not limited to, electronics, sensing, catalysis, and energy storage fields.

Carbonized poly(vinylidene fluoride)/graphene oxide with three-dimensional multiscale-pore architecture as an advanced electrode material

A low-cost, mass-produced, dry-gel-based method for fabricating graphene based electroactive materials relevant to energy storage has been reported. This technique combines thermal decomposition of carbon-based materials for the formation of ultramicropores/micropores and freeze drying of graphene gels for the formation of mesopores/macropores. The as-fabricated pore-rich carbon materials show electrochemical performances with superior characteristics of stabilization, specific capacitance and rate capability, demonstrating their great potential applications in clean energy.

Rewriting the Superconductivity in Iron‐Based Superconductors by Lithium‐Ion Insertion and Extraction

D. Chen, Prof. Z.-A. Ren, Prof. M. Q. Xue, Prof. G. F. Chen Institute of Physics and Beijing National Laboratory for Condensed Matter Physics Chinese Academy of Sciences Beijing 100190 , China E-mail: xuemq@iphy.ac.cn; gfchen@aphy.iphy.ac.cn X. Wang, Prof. J. T. Chen Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular Engineering Peking University Beijing 100871 , PR China Prof. Z.-A. Ren, Prof. G. F. Chen Collaborative Innovation Center of Quantum Matter Beijing 100190 , China

Superconducting Continuous Graphene Fibers via Calcium Intercalation

Superconductors are important materials in the field of low-temperature magnet applications and long-distance electrical power transmission systems. Besides metal-based superconducting materials, carbon-based superconductors have attracted considerable attention in recent years. Up to now, five allotropes of carbon, including diamond, graphite, C60, CNTs, and graphene, have been reported to show superconducting behavior. However, most of the carbon-based superconductors are limited to small size and discontinuous phases, which inevitably hinders further application in macroscopic form. Therefore, it raises a question of whether continuously carbon-based superconducting wires could be accessed, which is of vital importance from viewpoints of fundamental research and practical application. Here, inspired by superconducting graphene, we successfully fabricated flexible graphene-based superconducting fibers via a well-established calcium (Ca) intercalation strategy. The resultant Ca-intercalated graphene fiber (Ca-GF) shows a superconducting transition at ∼11 K, which is almost 2 orders of magnitude higher than that of early reported alkali metal intercalated graphite and comparable to that of commercial superconducting NbTi wire. The combination of lightness and easy scalability makes Ca-GF highly promising as a lightweight superconducting wire.