Michael D Cheetham

Decoupling between Water Column Oxygenation and Benthic Phosphate Dynamics in a Shallow Eutrophic Estuary

Estuaries are crucial biogeochemical filters at the land-ocean interface that are strongly impacted by anthropogenic nutrient inputs. Here, we investigate benthic nitrogen (N) and phosphorus (P) dynamics in relation to physicochemical surface sediment properties and bottom water mixing in the shallow, eutrophic Peel-Harvey Estuary. Our results show the strong dependence of sedimentary P release on Fe and S redox cycling. The estuary contains surface sediments that are strongly reducing and act as net P source, despite physical sediment mixing under an oxygenated water column. This decoupling between water column oxygenation and benthic P dynamics is of great importance to understand the evolution of nutrient dynamics in marine systems in response to increasing nutrient loadings. In addition, the findings show that the relationship between P burial efficiency and bottom water oxygenation depends on local conditions; sediment properties rather than oxygen availability may control benthic P recycling. Overall, our results illustrate the complex response of an estuary to environmental change because of interacting physical and biogeochemical processes.

Longitudinal correlation of late Quaternary terrace sequences of Widden Brook, southeastern Australia

Terrace remnants on Widden Brook, southeastern Australia, were examined and correlated longitudinally to establish their evolutionary history. Three discontinuous terrace sequences, the Baramul, Widden and Kewarra, were identified in a 26 km reach using sedimentology, topography and chronology. Each terrace sequence occurred within a geomorphically distinct valley setting: an upstream constriction, a valley expansion and a highly constricted downstream section. Radiocarbon and optically stimulated luminescence ages indicated that each terrace sequence was formed during the Late Pleistocene and Holocene (16.7–0.5 ka cal BP). However, their sedimentology and topography were shown to differ significantly. We present evidence that both climate and the exceedance of intrinsic geomorphic thresholds were major contributing factors responsible for the formation of these terrace sequences.

Mobilisation, alteration, and redistribution of monosulfidic sediments in inland river systems

The accumulation of monosulfidic sediments in inland waterways is emerging as a major environmental issue. Mobilisation and suspension of monosulfidic sediments can result in deoxygenation, acidification of the water column and mobilisation of trace metals. The controls on monosulfidic sediment mobilisation and the critical thresholds for its scour and entrainment have not been established. This study examines the effect of a minor flood event (average return interval of 5 years) on sulfidic sediment scour in the Wakool River in southern NSW, Australia. Five profiles were sampled within a small (~300 m) reach before and after a minor flood event to determine the degree of sediment scour and transport. The results indicate substantial scour of both monosulfidic sediments and underlying bed sediments (approximately 2100 m(3)). Changes in the sediment geochemistry suggest large concentrations of monosulfidic sediments had been suspended in the water column, partially-oxidised and redeposited. This is supported by (210)Pb results from one of the profiles. These results suggest that these monosulfidic sediments can move as bed load during minor flood events.

Accumulation of sulfidic sediments in a channelised inland river system, southern Australia

Accumulation of sulfidic sediments in freshwater environments is a relatively recent phenomenon and an emerging environmental issue. In the present study, benthic sediments along short (~250m) reaches of an inland freshwater river in south-eastern Australia were examined to determine the abundance and vertical distribution of fine-grained organic sulfidic sediments, identified by acid volatile sulfide (AVS) and chromium-reducible sulfur (SCR) contents. Sulfidic sediments (up to 404mmolkg–1 SCR) preferentially accumulated in zones immediately overlying coarse sandy bed material. Conversely, where bed material was clay or silt dominated, comparatively limited sulfidic sediment had accumulated (where AVS and SCR were not detected). This suggests that the hydraulic conductivity of the underlying bed material could play a role in the formation of sulfidic sediments and that the overlying water column is not the sole source of SO42–. Evidence suggests that accumulation of sulfidic materials occurred preferentially downstream of channel obstructions, such as submerged logs or in scour pools. However, sediment accumulation was not limited to lower-energy parts of the channel, as would be expected for fine-grained organic sediments. Evidence of reworking, burial or sulfide formation at depth highlights the dynamism of the system and its differences to many coastal systems where these sediments are commonly found.