Michel Ferriol
University of Lorraine
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Publication
Featured researches published by Michel Ferriol.
International Journal of Spectroscopy | 2013
Richard Jumeau; Patrice Bourson; Michel Ferriol; François Lahure; Marc Ponçot; Abdesselam Dahoun
The possibilities of applications of vibrational spectroscopy techniques (Raman spectroscopy) in the analysis and characterization of polymers are more and more used and accurate. In this paper, our purpose is to characterize Low Density Poly(Ethylene) (LDPE) grades by Raman spectroscopy and in particular with CH2 Raman vibration modes. With temperature measurements, we determine different amorphous and crystalline Raman assignments. From these results and on the basis of the evolution of CH2 bending Raman vibration modes, we develop a phenomenological model in correlation with Differential Scanning Calorimetry and in particular with crystalline lamella thickness determination.
International Journal of Spectroscopy | 2014
Marie Veitmann; Richard Jumeau; Patrice Bourson; Michel Ferriol; François Lahure
Studies of high temperature oxidation of polyethylene are not much present in the literature though it can really be a problem especially in polymer production and processing. This study aims to detect oxidation flaws in polyethylene and to determine their impact on polymer structure and properties. Besides, we suggest a method via PLS-regression to determine the degree of flaws that can occur during polymer processing due to oxidation. Several kinds of oxidation flaws were reproduced in laboratory at 150°C in an oven operating in air and Raman spectroscopy analysis was performed on each sample. Using statistical tools as chemometrics on these spectra, we have built a Partial Least Square (PLS) model able to predict the oxidation degree of flaws. Interpretation of the model construction and further characterization tests show that oxidation can be followed with the evolution of the crystalline carbon group and of the created carbonyl functions. Finally we suggest possible mechanisms which can explain the high temperature oxidation process in LPDE, and we link them to the modification of the material properties.
Journal of Physics: Conference Series | 2017
F. Assi; Michel Ferriol; Michel Aillerie; Marianne Cochez
Borate-based materials are of high interest to generate an UV laser light from a crystal. Fiber-shaped crystals combining the advantages of fiber lasers and crystalline lasers, we have investigated the growing conditions required to obtain usable fibers of Bi2ZnB2O7 (BZBO) and LaBGeO5 (LBGO). For BZBO, the major drawback was the pronounced color of the fibers and for LBGO, it was the high viscosity of its melt leading to use a flux. This paper presents our state of the art to obtain good quality BZBO and LBGO crystal fibers.
Journal of Thermal Analysis and Calorimetry | 2013
Michel Ferriol; Marianne Cochez
During several years, we have been involved in the growth and characterization of non-linear optical crystals by the two most common techniques for growing single-crystal fibers from the melt: laser-heated pedestal growth and micro-pulling down. Their specific features are presented in this study and their versatility is demonstrated through two typical examples of incongruently melting materials: K3Li2−xNb5+xO15+2x (solid solution of the ternary system K2O–Li2O–Nb2O5) and Ca5(BO3)3F which can only be grown from a flux.
Progress in Polymer Science | 2016
N. Burger; A. Laachachi; Michel Ferriol; M. Lutz; V. Toniazzo; D. Ruch
International Journal of Heat and Mass Transfer | 2015
N. Burger; A. Laachachi; Bohayra Mortazavi; Michel Ferriol; M. Lutz; V. Toniazzo; D. Ruch
Polymer Degradation and Stability | 2015
Abdelghani Laachachi; Nicolas Burger; Kadir Apaydin; Rodolphe Sonnier; Michel Ferriol
Polymer Degradation and Stability | 2012
Blandine Friederich; Abdelghani Laachachi; Michel Ferriol; Marianne Cochez; Rodolphe Sonnier; Valérie Toniazzo; David S. Ruch
Journal of Crystal Growth | 2013
N. Kozhaya; Michel Ferriol; Marianne Cochez; Michel Aillerie
Polymer Degradation and Stability | 2016
Henri Vahabi; Q. Lin; Christelle Vagner; Marianne Cochez; Michel Ferriol; Pascal Laheurte