Ming-Xing Ling

The genetic association of adakites and Cu–Au ore deposits

Adakites may form by partial melting of either the subducting oceanic lithosphere or the lower part of the continental crust. These two magma types can be discriminated geochemically using a combination of La/Yb, Sr/Y ratios, MgO and Na2O contents, and Sr–Nd isotopes. Given that the basaltic crust has Cu concentrations more than two times higher than the lower continental crust and the mantle wedge, ‘primitive’ adakites produced by oceanic slab melting should contain significantly higher Cu contents than adakites derived from the continental crust, as well as normal arc andesites. A globally compiled dataset shows that Cu concentrations in adakites are generally lower than that in normal arc rocks. We attribute this low copper content to loss of magmatic fluids as a result of sulphate reduction during adakitic magma differentiation, in turn induced by the crystallization of Fe–Ti oxides, essential to mineralization. Therefore, the underflow of oceanic-slab-derived adakites that can release larger amounts of Cu (presumably Au as well) by crystal fractionation leads to higher potential for Cu–Au mineralization along convergent margins, usually associated with ridge subduction. Such basaltic slab melts initially have considerably higher Cu contents and thus play a crucial role particularly in the relatively closed magma system responsible for generating porphyry Cu deposits.

Mesozoic large magmatic events and mineralization in SE China: oblique subduction of the Pacific plate

SE China is well known for its Mesozoic large-scale granitoid plutons and ore deposits. In SE China, igneous rocks with intrusion ages between 180 and 125 Ma generally become progressively younger towards the NE. More specifically, 180–160 Ma igneous rocks are distributed throughout a broad area, with mineralization ranging from Cu–Au and Pb–Zn–Ag to W–Sn; 160–150 Ma plutons are present mainly in the Nanling region and are associated with the large-scale W–Sn mineralization; younger igneous rocks occur in the NE area that has many fewer deposits. These can be plausibly interpreted as reflecting a southwestward subduction followed by a northeastward rollback of a subducted oceanic slab, in rough agreement with contemporaneous drift of the Pacific plate. Consistent with this scenario, SE China contains three Jurassic metallogenic belts distributed systematically from NE to SW: (1) a Cu–(Au) metallogenic belt in the NE corner of the South China Block, represented by the Dexing porphyry Cu deposits; (2) a Pb–Zn–Ag metallogenic belt in the middle, represented by the Lengshuikeng Ag and Shuikoushan Pb–Zn deposits; and (3) the famous Nanling W–Sn metallogenic belt in the SW. The distribution of these metallogenic belts is analogous to those in South America where Fe deposits are distributed close to the subduction zone, followed by porphyry Cu–Au deposits and Pb–Zn–Ag deposits in a medial zone, and Sn–W deposits distant from the trench. Inasmuch as quite a few late Mesozoic Fe deposits occur in the Lower Yangtze River Belt to the NE of the Cu–Au deposits in SE China, the distribution of late Mesozoic deposit belts in SE China is identical to that in South America. Therefore, southwestward subduction of the Pacific plate and the corresponding slab rollback are proposed here to explain the distributions of the late Mesozoic (180–125 Ma) magmatism and the associated metallogenic belts in SE China.

Homogeneous magnesium isotopic composition of seawater: an excellent geostandard for Mg isotope analysis

The magnesium (Mg) isotopic compositions of 40 seawater samples from the Gulf of Mexico and of one seawater sample from the southwest Hawaii area were determined by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) to investigate the homogeneity of Mg isotopes in seawater. The results indicate that the Mg isotopic composition of seawater from the Gulf of Mexico is homogeneous, both vertically and horizontally, with average values for δ(26)Mg = -0.832 ± 0.068 and δ(25)Mg = -0.432 ± 0.053 (n = 40, 2SD)--identical to those of seawater from Hawaii (average δ(26)Mg = -0.829 ± 0.037 and δ(25)Mg = -0.427 ± 0.033) and to the average literature values of seawater worldwide (δ(26)Mg = -0.83 ± 0.11 and δ(25)Mg = -0.43 ± 0.06, n = 49, 2SD). Collectively, global seawater has a homogeneous Mg isotopic composition with δ(26)Mg = -0.83 ± 0.09 and δ(25) Mg = -0.43 ± 0.06 (2SD, n = 90). The magnesium isotopic composition of seawater is principally controlled by river water input, carbonate precipitation and oceanic hydrothermal interactions. The homogeneous Mg isotopic composition of seawater indicates a steady-state budget in terms of Mg isotopes in oceans, consistent with a long Mg residence time (~13 Ma). Considering that seawater is homogeneous, readily available in large amounts, can be easily accessed and processed for isotopic analysis, and has an isotopic composition near the middle of the natural range of variation, it is an excellent geostandard for accuracy assessment to rule out analytical artifacts during high-precision Mg isotopic analysis.

Geochemical Constraints on Adakites of Different Origins and Copper Mineralization

The petrogenesis of adakites holds important clues to the formation of the continental crust and copper ± gold porphyry mineralization. However, it remains highly debated as to whether adakites form by slab melting, by partial melting of the lower continental crust, or by fractional crystallization of normal arc magmas. Here, we show that to form adakitic signature, partial melting of a subducting oceanic slab would require high pressure at depths of >50 km, whereas partial melting of the lower continental crust would require the presence of plagioclase and thus shallower depths and additional water. These two types of adakites can be discriminated using geochemical indexes. Compiled data show that adakites from circum-Pacific regions, which have close affinity to subduction of young hot oceanic plate, can be clearly discriminated from adakites from the Dabie Mountains and the Tibetan Plateau, which have been attributed to partial melting of continental crust, in Sr/Y-versus-La/Yb diagram. Given that oceanic crust has copper concentrations about two times higher than those in the continental crust, whereas the high oxygen fugacity in the subduction environment promotes the release of copper during partial melting, slab melting provides the most efficient mechanism to concentrate copper and gold; slab melts would be more than two times greater in copper (and also gold) concentrations than lower continental crust melts and normal arc magmas. Thus, identification of slab melt adakites is important for predicting exploration targets for copper- and gold-porphyry ore deposits. This explains the close association of ridge subduction with large porphyry copper deposits because ridge subduction is the most favorable place for slab melting.

Different origins of adakites from the Dabie Mountains and the Lower Yangtze River Belt, eastern China: geochemical constraints

Cretaceous adakites are widely distributed in the Lower Yangtze River Belt (LYRB) and the Dabie Mountains, east-central China. Adakites from the LYRB in general are closely associated with Cu–Au deposits, whereas Dabie adakites lack any mineralization. Based on geochemical characteristics, we show that these adakites have different origins; for example, adakites from the Dabie Mountains have more variable Sr/Y (6.47–1303) and systematically higher La/Yb (20.8–402), Th/U (2.28–50.6), and Nb/Ta (5.07–65.2) compared to adakites from the LYRB, Sr/Y (28.8–185), La/Yb (14.1–49), Th/U (0.33–8), and Nb/Ta (7.5–23). The systematically higher La/Yb of Dabie adakites supports their continental origin, because the La/Yb of the lower continental crust is more than 10 times higher than that of mid-ocean ridge basalt (MORB). Moreover, the lower continental crust is also highly enriched in Sr, with Sr/Y > 10 times that of MORB. Interestingly, with the exception of those from Fuziling, most Dabie adakites have Sr/Y comparable to normal adakites, suggesting the presence of residual plagioclase. Because Th and U do not fractionate significantly from each other during magmatism, the high but variable Th/U suggests that the protolith of Dabie adakites underwent subduction. The LYRB adakites can be plausibly interpreted as being a result of Early Cretaceous partial melting of a young, hot, descending oceanic slab during ridge subduction. By contrast, Dabie adakites were likely formed by partial melting of the lower continental crust attending ridge subduction.

High Oxygen Fugacity and Slab Melting Linked to Cu Mineralization: Evidence from Dexing Porphyry Copper Deposits, Southeastern China

The Dexing porphyry Cu deposit is the largest Cu deposit in eastern China, with total reserves of 8.4 Mt Cu. The Dexing porphyries have geochemical characteristics typical of adakites: they are similar to examples in the Circum-Pacific Belt and in the Lower Yangtze River Belt but different from adakites from the Dabie Mountains and the Tibetan Plateau. Ce4+/Ce3+ and values calculated from zircon trace-element compositions vary from 495 to 1922 and from 0.51 to 0.82, respectively, and reflect high oxygen fugacity similar to that measured in or inferred for porphyry Cu-Au deposits in the South America. The high oxygen fugacity is consistent with abundant anhydrite and magnetite-hematite intergrowths in the porphyry, which indicate that the highest oxygen fugacity of Dexing porphyry reached the hematite-magnetite buffer. Based on the geochemical characteristics and the drifting history of the Pacific Plate, we propose that the Dexing adakitic porphyries formed through slab melting, most likely during subduction of an aseismic ridge in the Pacific Plate in the Mid-Jurassic.

Geochemical and zircon U–Pb study of the Huangmeijian A-type granite: implications for geological evolution of the Lower Yangtze River belt

The Early Cretaceous Huangmeijian Pluton is an A-type granite located on the northern bank of the Lower Yangtze River in Anhui Province, east-central China. It intruded the SE edge of the Early Cretaceous Luzong volcanic basin. The moderate- to coarse-grained granite is mainly composed of alkali feldspar, plagioclase, and quartz and has a typical A-type geochemical signature. LA-ICP-MS zircon dating yielded a weighted mean 206Pb/238U age of 127.1 ± 1.4 Ma, similar to other A-type granites in the Lower Yangtze River belt, indicating an Early Cretaceous extensional environment. Temperatures calculated using the Ti-in-zircon thermometer suggest that the magma formed under high-temperature conditions (720–880°C). The low calculated Ce(IV)/Ce(III) ratio based on zircon rare earth element patterns indicates low oxygen fugacity for this A-type magma. Previous studies suggested that eastern China was an active plate margin related to the Early Cretaceous subduction of the Pacific and Izanagi plates. The ridge between these two plates probably passed under the Lower Yangtze River belt, forming A-type granites and adakites. The Huangmeijian Pluton is roughly the same age within error but is marginally older than the Baijuhuajian A-type granite in the eastern part of the Lower Yangtze River belt. A-type granite genesis in the Lower Yangtze River belt only lasted for 2–3 million years and slightly predates the transition from regional extension to compression. All these can be plausibly interpreted by the ridge subduction model, that is, A-type granites formed because of mantle upwelling through the slab window during subduction of the ridge separating the Pacific and Izanagi plates.

Destruction of the North China Craton Induced by Ridge Subductions

The destruction of the North China Craton (NCC) mainly occurred in the Cretaceous and has been attributed to a “top-down” rapid delamination, “bottom-up” long-term thermal/chemical erosions, or hydration by subduction-released fluids. On the basis of the distribution of one Jurassic and two Early Cretaceous adakite belts and the drifting history of the paleo-Pacific Plate, we propose that three ridge subduction events dominated the large-scale decratonization in the NCC. Both physical erosion and magmatism induced by ridge subduction contributed to the destruction of the NCC; the last ridge subduction, at Ma, was the key driving force in the final destruction. We present mineralogical, geochemical, and isotopic data in support of the ridge subduction model: flat subduction of a spreading ridge resulted in stronger physical erosion on the thick lithosphere mantle of the NCC. Consequently, slab melting occurred during ridge subduction, forming adakites with mantle Mg isotope compositions, followed by A-type granites as a result of asthenosphere upwelling. Delaminated lower continental crust was also partially melted after reacting with hydrous magmas, as indicated by eclogite xenoliths, resulting in a zircon age spectrum similar to that of the NCC and some adakitic samples with chemical characteristics similar to those of the Dabie adakites. The final decratonization was triggered by the last ridge subduction, with both physical erosion (flat subduction) and thermal erosion (adakitic and A-type magmatisms). Given that ridge subduction has occurred throughout Earth’s history, the associated decratonization processes are presumably a common phenomenon that modified the chemical compositions of the continental crust.

Large-scale gold mineralization in eastern China induced by an Early Cretaceous clockwise change in Pacific plate motions

Orogenic gold (Au) deposits are the most important type, accounting for more than half of the worlds proven Au reserves. They are mainly controlled by three key factors: (1) abundant andesitic rocks (SiO2 of 55–60 wt.%) at depth, which have systematically higher Au contents than other rock types; (2) a pervasive transition from greenschist facies to amphibolite facies metamorphism within a short period, which releases S2−-rich fluids that may scavenge Au from host rocks; and (3) deformation and fracturing under a compressive/transpressive tectonic regime. Orogenic belts at convergent margins are the best places for such mineralization because convergent margins are rich in andesites; the transition from greenschist to amphibolite facies recrystallization commonly occurs as a result of collision, compression, and thickening at convergent margins, forming large amounts of Au-rich fluids within a short period of time; and strong deformation and fracturing during orogenic processes provide channels for fluid transportation. Moreover, the overlying plate is injected and enriched by auriferous fluids released during amphibolite facies metamorphism of the subducting plate. The Pacific plate changed course by ∼80° (from SW to NW) at approximately 125–122 Ma, reflecting an altered thermal structure and the elevation of the South Pacific plate attending the appearance of the plume head that formed the Ontong Java large igneous province. Consequently, the tectonic regime changed from extension to compressive/transpressive in eastern China, causing deformation, thickening, and metamorphism of the overriding plate, especially along weak crustal belts (e.g. overlying plates of palaeosutures), which resulted in world-class mineralization of orogenic Au deposits. During this process, pyrite changed to pyrrhotite during the transition from greenschist to amphibolite facies, releasing sulphur. Sulphur mobilized and scavenged Au and other chalcophile elements into metamorphic ore-forming fluids. A series of NE-trending compressive faults were formed at ˜120 Ma as a result of continuous compression of the subducting Pacific plate, releasing these ore-forming fluids. Auriferous carbonate-rich quartz veins and/or metasomatized Au-bearing wall rocks were formed due to the decompression of the ascending ore-forming fluids. Orogenic belts along the margins of the North China craton and the Jiangnan block were the most favourable regions for mineralization. Compared with the former, the latter has much smaller proven Au reserves. However, more exploration is needed along the margins of the Jiangnan block. Promising targets include accessory faults and kink points of large, NE-trending Cretaceous faults that transect greenschist facies metamorphic rocks of the Niuwu and Jingtan Groups, etc.

Formation of the world's largest molybdenum metallogenic belt: a plate-tectonic perspective on the Qinling molybdenum deposits

Qinling ore belt is the largest known molybdenum belt in the world with a total reserve of >5 Mt of Mo metal. Based on the geochemical behaviour of Mo, the structural settings of the Qinling orogenic belt, and geological events in eastern China, we propose that tectonic settings are of critical importance to the formation of these ore deposits. Molybdenum is very rare in the earth with an abundance of ∼0.8 ppm in the continental crust. Both surface- and magmatic-hydrothermal enrichment processes are required for Mo mineralization. It can be easily oxidized to form water-soluble MoO4 – in the surface environment, especially in the Phanaerozoic, and then precipitated under anoxic conditions. Therefore, closed or semi-closed water bodies with large catchment areas and high chemical erosion rates are the most favourable locations for Mo-enriched sediments. The Qinling orogenic belt was located in the tropics during crustal collisions, such that the chemical erosion was presumably intense, whereas the Erlangping back-arc basin was probably a closed or semi-closed water body as a result of plate convergence. More than 90% of the Mo reserves so far discovered in the Qinling molybdenum belt are associated with the Palaeozoic Erlangping back-arc basin. Compiled Re–Os isotopic ages for porphyry deposits (including several carbonate vein deposits) that have been dated show peaks during 220 million years (>0.32 Mt), 145 million years (> 3.5 Mt), and 115 million years (> 0.84 Mt), which correlate well with the three major episodes of granitoid magmatism since the Triassic. The ∼220 million year episode of mineralization, represented by the Huanglongpu carbonate vein-type deposit and the Wenquan porphyry deposit, coincided with the formation of the South Qinling syn-orogenic granites as well as the Dabie ultrahigh-pressure metamorphic rocks, suggests a genetic relationship with the collision between South and North China Blocks. The ∼145 Ma porphyry Mo deposits, representing the main mineralization, are attributed to reactivation by ridge subduction along the lower Yangtze River belt to the east of the Qinling orogen ∼150–140 Ma. The ∼115 Ma Mo deposits likely reflect slab rollback of the northwestwards subducting Pacific plate ∼125–110 Ma.