Moon Kyong Na

Properties of Nano-Hybrid Sol-Gel Coating Films Synthesized with Colloidal Silica and Organoalkoxy Silanes

Three kinds of colloidal silica (CS)/silane sol were prepared. Sols are involved with the kinds of silane with different organic group. Methyltrimethoxysilane (MTMS) has the three methoxy groups and a methyl group. γ-Glycidoxypropyltrimethoxysilane (GTMS) has the three methoxy groups and a bulky epoxy group. GTMS was added to two sols with different amount. When sol reacted for 10 days, viscosity increased dramatically. Trasnmittance of sols reacted for 10 days decreased rapidly, too. It indicated the stability of sol degraded. Sol-gel coating films were formed on glass substrate using spin coating procedure with reaction time for 10 days. Coating films were flat and transparent without cracking. CS/MTMS coating films showed high contact angle. When large amount of GTMS was added, contact angle decreased due to its epoxy group. No thermal degradation of CS/MTMS coating film occurred up to 600 oC. CS/MTMS/GTMS coating film degraded at 400 oC for decomposition of epoxy group which has long organic chain which easily degraded by the thermal shock.

Properties of Nano-Hybrid Sol-Gel Materials Synthesized from Colloidal Silica-Silane Containing Epoxy Silane

Three kinds of colloidal silica (CS)/silane sol solutions were synthesized in variation with parameters such as different acidity and reaction time. Sol solutions were prepared from HSA CS/ methyltrimethoxysilane (MTMS), LS CS/MTMS and LS CS/MTMS/γ -Glycidoxypropyltri methoxysilane (ES) solutions. In order to understand their physical and chemical properties, sol-gel coating films were fabricated on glass. Coating films on glass, obtained from LS/MTMS sol, had high contact angle, also, much enhanced flat surface in the case of LS/MTMS sol was observed in comparison with HSA/ MTMS sol. From all sol-gel solutions, seasoning effect of for enhancing properties of sol-gel coating layer on glass was observed while such sol-gel solutions were left for 7days. In initial stage of sol-gel reaction, all most of sol solutions used in this work seem to be unstable, formation of coating films was a little hazy and rough. However, improved coating films as observed in 4days later. LS/MTMS/ES sol solutions were synthesized with ES, adding to LS/MTMS sol. Contact angle of LS/MTMS/ES sol-gel coating films decreased, since ES played a role in forming hydrophilic hydroxyl sol. The elastic portion of coating films prepared from LS/MTMS/ES sol increased with addition of ES, but thermal stability decreased a little.

Erratum to: Branch length similarity entropy-based descriptors for shape representation (Journal of the Korean Physical Society, (2017), 71, 10, (727-732), 10.3938/jkps.71.593)

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Characteristics of Thin Films Synthesized from Colloidal Silica-Silane Sols

Three kinds of colloidal silica (CS)/silane sol solutions were synthesized by using three kinds of CS at different reaction time. Sol solutions were prepared from 1034A CS/methyltrimethoxysilane (MTMS), HSA CS/MTMS and LS CS/MTMS materials. In order to understand their physical and chemical properties, sol-gel coating films were fabricated on glass. Coating film on glass, obtained from 1034A/MTMS sol, had high contact angle and much enhanced flat surface in comparison with those of HSA/MTMS and LS/MTMS sols. Enhanced surface properties were observed in the case of sol solutions left for 7 days. With increasing reaction time in sol solutions, surface free energy and roughness in coating films decreased. Good thermal stability was observed in all used films, i.e., no thermal degradation up to 550°C. In the case of 1034A/MTMS coating film, thermal degradation did not occur up to 600°C. In addition, microhardness of 1034/MTMS coating film was higher than those of HSA/MTMS and LS/MTMS due to active networking and surface treatment reactions between 1034A and MTMS.

Properties of Sol-Gel Coating Film from Colloidal Silica-Silane Sol

Two kinds of colloidal silica(CS)/silane sol solutions were prepared. Two sol solutions are involved with the kinds of silane such as methyltrimethoxysilane(MTMS) and -Glycidoxypropyl trimethoxysilane(ETMS) using LS CS. MTMS was added to two sol solutions. Whether ETMS was added or not, two kinds of sol solutions were synthesized. Using two kinds of sol solutions, sol-gel coating films were formed on glass substrates via dip-coating process. Here, seasoning effect of for enhancing properties of sol-gel coating layer on glass was investigated while such sol-gel solutions were left for 7days. Also, their properties such as surface free energy, roughness, thermal property, potential hardness and elastic portion were characterized in order to understand the effect of addition of ETMS. In this case of LS/MTMS sol, the coating film had low surface free energy and more enhanced flat surface than that of the case of LS/MTMS/ETMS sol. ETMS forms hydrophilic hydroxyl group in sol solution, then surface free energy of LS/MTMS/ETMS coating film increased. In the beginning of reaction sol solution seemed to be unstable, but 4days later their coating film properties such as surface free energy and roughness enhanced. The elastic portion of coating films obtained from LS/MTMS/ETMS sol increased with addition of ETMS, but thermal stability decreased.

Properties of Coating Films Synthesized from Colloidal Silica and Methyltrimethoxysilane

Colloidal silica/methyltrimethoxysilane (MTMS) sol solutions were prepared in variation with the ratio of MTMS to colloidal silica. Sol solutions were prepared by sol-gel reaction. To understand their physical and chemical properties, dip coating of sol solutions was performed on the glass substrates. The state of coating films was investigated in variation with the amount of MTMS and reaction time. The contact angle and thickness of coating films increased with an increasing amount of MTMS. The surface roughness of coating films decreased with an increasing amount of MTMS. Coating films were stable until 550°C. Thermal degradation temperature of coating films decreased with an increasing amount of MTMS.

The Effect of Fiber Winding Angles on the Bending Strength of Fiber-Reinforced Plastic Rods

Fiber-reinforced plastics consist of fibers of high strength and modulus embedded in, or bonded to a matrix with distinct interfaces between them. Because fiber configuration plays a key role in determining mechanical strength of fiber-reinforced plastic rods, especially bending strength of fiber-reinforced plastic rods was measured and simulated numerically in variation with winding angles. Also, stress distribution in fiber-reinforced plastic rods was simulated numerically under the condition of constant bending load to fiber-reinforced plastic rods. The measured bending strength of fiber-reinforced plastic rods in variation with winding angles was different from that of simulated. The difference between measured and simulated results was due to the effect of shear stresses on the strength of fiber-reinforced plastic rods.

Characteristics of thin film of nano-hybrid synthesized from acrylic resin and colloidal silca-silane sol

Organic-inorganic hybrid blends were prepared in variation with the ratio of sol solution to urethaneacrylic resin. Such sol solutions were synthesized from colloidal silica (CS)/ methyltrimethoxysilane(MTMS)/vinyltrimethoxysilane(VTMS) by sol-gel reaction through two step reactions. Thin films of organic-inorganic hybrid blends were prepared using spin coater on the glass and aluminum sheets. In order to understand surface properties of thin films, contact angle and roughness were measured. Surface contact angle and roughness of thin films increased as the amount of sol solution increased. Thermal dissociation temperature of thin films was observed using TGA. Thin films were stable until 270 oC. Thermal dissociation temperature of thin films improved with increasing sol solution. In order to observe insulation property of thin films, electrical resistance measurements were performed. Surface and volume resistance of thin films increased as the amount of sol solution increased.