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N. I. Sadova

Moscow State University

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Journal of Molecular Structure | 1983

Electron diffraction study of meta-dinitrobenzene and meta-chloronitrobenzene in gas phase

O. G. Batyukhnova; N. I. Sadova; L. V. Vilkov; Yu. A. Pankrushev

Abstract The following geometric parameters were determined on the basis of the sM(s) curves: 1. 1) for m-C6H4(NO2)2 rg(C … C)av = 1.382(2), rg(C-N) = 1.461(6), rg(N=O) = 1.225(2)A, / ONO = 125.3(0.7)o, / CCNO2C= 121.8(1.0),o,φ(CN) = 23o(3)o, / CNO2CCNO2 = 118.5(1.5)o 2. 2) for m-ClC6H4NO2 rg(C … C)av = 1.388(3), rg(CN) = 1.442(10), rg(NO) = 1.243(3) rg(CCl) = 1.746(6)A, / ONO = 122.6(1.0), / CCNO2C = 123.0(1.5)o, / CCClC = 121.5(1.2)o, / CClCCNO2 = 118.3(1.5)o, φ(CN) = 13(6)o. Amplitudes of vibrations were calculated from estimated force fields. Comparison with structures of other nitro aromatic derivatives showed that they agree in general but the CCl bond in m-ClC6H4NO2 is longer than in p-ClC6H4NO2.

Journal of Structural Chemistry | 1984

An electron-diffraction study of the molecular structure of nitrobenzene in the vapor state

Igor F. Shishkov; N. I. Sadova; V. P. Novikov; L. V. Vilkov

Journal of Structural Chemistry | 1979

An electron diffraction study of the structure of the molecules of chlorobenzene in the gaseous phase

N. P. Penionzhkevich; N. I. Sadova; L. V. Vilkov

Journal of Structural Chemistry | 1976

Electron-diffraction investigation of the structure of the HC(NO2)3, ClC(NO2)3, and BrC(NO2)3 molecules in the gas phase

N. I. Sadova; N. I. Popik; L. V. Vilkov

Journal of Structural Chemistry | 1980

An electron diffraction study of the structure of the molecules of o-dinitrobenzene, p-dinitrobenzene, and sym-trinitrobenzene in the gaseous phase

N. P. Penionzhkevich; N. I. Sadova; N. I. Popik; L. V. Vilkov; Yu. A. Pankrushev

Journal of Structural Chemistry | 1983

Geometrical structure of dimethylnitromethane and trimethylnitromethane molecules in gaseous phase

Igor F. Shishkov; N. I. Sadova; L. V. Vilkov; Yu. A. Pankrushev

Journal of Structural Chemistry | 1977

Electron diffraction study of dichlorodinitromethane in the gaseous phase

N. I. Sadova; G. E. Slepnev; L. V. Vilkov

Journal of Structural Chemistry | 1975

Molecular structure of some aliphatic and aromatic nitro compounds in the gas phase

N. I. Sadova; N. I. Popik; L. V. Vilkov; Yu. A. Pankrushev; V. A. Shlyapochnikov

ChemInform | 2010

Certain Questions of Stereochemistry of Nitrogen Compounds in the Gaseous Phase

N. I. Sadova; L. S. Khaikin; L. V. Vilkov

Journal of Structural Chemistry | 1989

Electron-diffraction investigation of the structure of o-bromonitrobenzene, m-bromonitrobenzene, and 2,6-dinitrobromobenzene molecules in the gas phase

O. G. Batyukhnova; N. I. Sadova; Yu. N. Syshchikov; L. V. Vilkov; Yu. A. Pankrushev

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L. V. Vilkov

Moscow State University

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Yu. A. Pankrushev

Moscow State University

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Igor F. Shishkov

Moscow State University

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O. G. Batyukhnova

Moscow State University

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A. V. Golubinskii

Moscow State University

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M. E. Nipan

Moscow State University

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V. P. Ivshin

Moscow State University

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E. A. Chernyshev

Moscow State University

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G. E. Slepnev

Moscow State University

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L. S. Khaikin

Moscow State University

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