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Yu. A. Pankrushev

Moscow State University

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Journal of Molecular Structure | 1983

Electron diffraction study of meta-dinitrobenzene and meta-chloronitrobenzene in gas phase

O. G. Batyukhnova; N. I. Sadova; L. V. Vilkov; Yu. A. Pankrushev

Abstract The following geometric parameters were determined on the basis of the sM(s) curves: 1. 1) for m-C6H4(NO2)2 rg(C … C)av = 1.382(2), rg(C-N) = 1.461(6), rg(N=O) = 1.225(2)A, / ONO = 125.3(0.7)o, / CCNO2C= 121.8(1.0),o,φ(CN) = 23o(3)o, / CNO2CCNO2 = 118.5(1.5)o 2. 2) for m-ClC6H4NO2 rg(C … C)av = 1.388(3), rg(CN) = 1.442(10), rg(NO) = 1.243(3) rg(CCl) = 1.746(6)A, / ONO = 122.6(1.0), / CCNO2C = 123.0(1.5)o, / CCClC = 121.5(1.2)o, / CClCCNO2 = 118.3(1.5)o, φ(CN) = 13(6)o. Amplitudes of vibrations were calculated from estimated force fields. Comparison with structures of other nitro aromatic derivatives showed that they agree in general but the CCl bond in m-ClC6H4NO2 is longer than in p-ClC6H4NO2.

Journal of Structural Chemistry | 1980

An electron diffraction study of the structure of the molecules of o-dinitrobenzene, p-dinitrobenzene, and sym-trinitrobenzene in the gaseous phase

N. P. Penionzhkevich; N. I. Sadova; N. I. Popik; L. V. Vilkov; Yu. A. Pankrushev

Journal of Structural Chemistry | 1983

Geometrical structure of dimethylnitromethane and trimethylnitromethane molecules in gaseous phase

Igor F. Shishkov; N. I. Sadova; L. V. Vilkov; Yu. A. Pankrushev

Journal of Structural Chemistry | 1978

Electron diffraction study of the structure of the methyldinitramine molecule

N. A. Tarasenko; L. V. Vilkov; G. E. Slepnev; Yu. A. Pankrushev

Journal of Structural Chemistry | 1975

Molecular structure of some aliphatic and aromatic nitro compounds in the gas phase

N. I. Sadova; N. I. Popik; L. V. Vilkov; Yu. A. Pankrushev; V. A. Shlyapochnikov

Journal of Structural Chemistry | 1989

Electron-diffraction investigation of the structure of o-bromonitrobenzene, m-bromonitrobenzene, and 2,6-dinitrobromobenzene molecules in the gas phase

O. G. Batyukhnova; N. I. Sadova; Yu. N. Syshchikov; L. V. Vilkov; Yu. A. Pankrushev

Journal of Structural Chemistry | 1986

Electronographic study of structure of molecule of o-chloronitrobenzene in gaseous phase

O. G. Batyukhnova; N. I. Sadova; L. V. Vilkov; Yu. A. Pankrushev

Journal of Structural Chemistry | 1983

An electron diffraction study of the structure of the dimethyldinitromethane molecule in the gas phase

Igor F. Shishkov; N. I. Sadova; L. V. Vilkov; Yu. A. Pankrushev

Journal of Structural Chemistry | 1978

Geometric structure of the N-methylnitramine and N-chloro-N-methylnitramine molecules in the gaseous phase

N. I. Sadova; G. E. Slepnev; N. A. Tarasenko; A. A. Zenkin; L. V. Vilkov; Igor F. Shishkov; Yu. A. Pankrushev

Journal of Structural Chemistry | 1989

Electron-diffraction investigation of the structure of the 2-methyl-5-vinyltetrazole molecule in the gaseous phase

N. I. Sadova; A. A. Ivanov; Mikhail V. Popik; Igor F. Shishkov; L. V. Vilkov; Yu. A. Pankrushev

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L. V. Vilkov

Moscow State University

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N. I. Sadova

Moscow State University

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Igor F. Shishkov

Moscow State University

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O. G. Batyukhnova

Moscow State University

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O. C. Batyukhnova

Moscow State University

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V. P. Ivshin

Moscow State University

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