Nermeen W. Aboelella | Researchain

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Chemical Communications | 2004

Mixed metal bis(-oxo) complexes with [CuM(-O)2]n+ (M = Ni(iii) or Pd(ii)) coresElectronic supplementary information (ESI) available: experimental and calculation details. See http://www.rsc.org/suppdata/cc/b4/b404640d/

Nermeen W. Aboelella; John T. York; Anne M. Reynolds; Koyu Fujita; Christopher R. Kinsinger; Christopher J. Cramer; Charles G. Riordan; William B. Tolman

Two highly reactive heterodinuclear bis(μ-oxo) complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at −80 °C and were identified by UV-vis, EPR/NMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional calculations.

Journal of the American Chemical Society | 2004

Dioxygen Activation at a Single Copper Site: Structure, Bonding, and Mechanism of Formation of 1:1 Cu-O2 Adducts

Nermeen W. Aboelella; Sergey V. Kryatov; Benjamin F. Gherman; William W. Brennessel; Victor G. Young; Ritimukta Sarangi; Elena V. Rybak-Akimova; Keith O. Hodgson; Britt Hedman; Edward I. Solomon; Christopher J. Cramer; William B. Tolman

Journal of the American Chemical Society | 2002

β-Diketiminate Ligand Backbone Structural Effects on Cu(I)/O2 Reactivity: Unique Copper−Superoxo and Bis(μ-oxo) Complexes

Douglas J. E. Spencer; Nermeen W. Aboelella; Anne M. Reynolds; Patrick L. Holland; William B. Tolman

Journal of the American Chemical Society | 2002

Snapshots of Dioxygen Activation by Copper: The Structure of a 1:1 Cu/O2 Adduct and Its Use in Syntheses of Asymmetric Bis(μ-oxo) Complexes

Nermeen W. Aboelella; Elizabeth A. Lewis; Anne M. Reynolds; William W. Brennessel; Christopher J. Cramer; William B. Tolman

Journal of the American Chemical Society | 2006

X-ray absorption edge spectroscopy and computational studies on LCuO2 species : Superoxide-CuII versus peroxide-CuIII bonding

Ritimukta Sarangi; Nermeen W. Aboelella; Kiyoshi Fujisawa; William B. Tolman; Britt Hedman; Keith O. Hodgson; Edward I. Solomon

Journal of the American Chemical Society | 2006

Effects of Thioether Substituents on the O2 Reactivity of β-Diketiminate-Cu(I) Complexes: Probing the Role of the Methionine Ligand in Copper Monooxygenases

Nermeen W. Aboelella; Benjamin F. Gherman; Lyndal M. R. Hill; John T. York; Nicole Holm; Victor G. Young; Christopher J. Cramer; William B. Tolman

Inorganic Chemistry | 2007

Ligand structural effects on Cu2S2 bonding and reactivity in side-on disulfido-bridged dicopper complexes

Eric C. Brown; Itsik Bar-Nahum; John T. York; Nermeen W. Aboelella; William B. Tolman

Inorganic Chemistry | 2004

A New Class of (μ-η2:η2-Disulfido)dicopper Complexes: Synthesis, Characterization, and Disulfido Exchange

Eric C. Brown; Nermeen W. Aboelella; Anne M. Reynolds; Gabriel Aullón; Santiago Alvarez; William B. Tolman

Chemical Communications | 2004

Mixed metal bis(μ-oxo) complexes with [CuM(μ-O)2]n+(M = Ni(III) or Pd(II)) cores

Nermeen W. Aboelella; John T. York; Anne M. Reynolds; Koyu Fujita; Christopher R. Kinsinger; Christopher J. Cramer; Charles G. Riordan; William B. Tolman

Science | 2004