Nicolas Devau

Managed Aquifer Recharge: An Overview of Issues and Options

As covered in Chap. 2, many of the world’s aquifers are rapidly being depleted. Nearly one quarter of the world’s population – 1.7 billion people – live in regions where more water is being consumed than nature can renew (Gleeson et al. 2012). Over-exploitation occurs when groundwater abstraction is too intensive, for example for irrigation or for direct industrial water-supply like extracting fossil fuels (Pettenati et al. 2013; Foster et al. 2013). When groundwater is continuously over-pumped, year after year, the volume withdrawn from the aquifer cannot be replaced by recharge. Eventually, the groundwater level is much lower than its initial level and even when pumping stops, the aquifer has trouble rising once again to its original level. In continental zones, over-exploitation can lead to groundwater drawdown and, ultimately, to subsidence through development of sinkholes when underground caverns or channels collapse. In coastal areas, the decrease in groundwater recharge results in saltwater intrusion into the aquifer formation (Petalas and Lambrakis 2006; De Montety et al. 2008). Preserving local groundwater resources is an environmental and economic issue in coastal zones and is vital in an island context. The increasing demand for water caused by a growing population can lead to the salinization of groundwater resources if these are systematically over-exploited. Limiting the salinization of coastal aquifers is consistent with the groundwater objective of the European Union Water Framework Directive, which is to achieve a good qualitative and quantitative status by 2015. The economic advantage of preserving these threatened water resources is that, when there is a growing demand, a local water resource is sustained and there is no need to import water. Transporting water can cost 2–10 times more than limiting the intrusion of saltwater into a coastal aquifer.

Natural attenuation of TiO2 nanoparticles in a fractured hard-rock

Successive transport experiments of TiO2 nanoparticles (NP) suspension through fractured hard-rock column were done in laboratory. A low ionic strength (IS) water (0.8-1.3 10-3 M) at pH ∼4.5 was used, corresponding to the chemical composition of groundwater where the rock was collected (Naizin, France). The surface charge of TiO2 NP was positive while that of rock was negative favoring NP deposition. SEM/EDX reveals that NP were retained on a broad distribution of mineral collectors along the preferential flow pathways (i.e., fractures). However, a non-negligible amount of NP (∼10%) was transferred through the rock. Divalent cation (Ca2+) was responsible for the reduction of the negative charge of the rock and thus contributed to limit the NP deposition as attested by DLVO model. Blocking of rock surfaces by NP favored NP transfer while the ripening process and the size exclusion of aggregates decreased NP mobility. Decrease of water flow favored the exchange of solutes from the immobile to the mobile water in the porous medium, which in turn favored the aggregation of the NP and led to their natural attenuation. The result evidences how slight modifications of the environmental conditions can strongly influence the fate of NP in groundwater.