Noboru Nakamura

Determination of REE, Ba, Fe, Mg, Na and K in carbonaceous and ordinary chondrites

Abstract Precise determination of REE and Ba abundances in three carbonaceous (Orgueil Cl, Murchison C2 and Allende C3) and seven olivine-bronzite chondrites were carried out by mass spectrometric isotope dilution technique. Replicate analyses of standard rock and the three carbonaceous chondrites demonstrated the high quality of the analyses (accuracies for REE are ±1–2 per cent). Certain carbonaceous chondrite specimens showed small positive irregularities in Yb abundance. The Yb ‘anomaly’ (approximately + 5 per cent relative to the average of 10 ordinary chondrites) in Orgueil may relate to high temperature components. The REE pattern of Guarena (H6) exhibits comparatively extensive fractionation (about factor 2) with a negative anomaly for Eu (17 ± 1 percent) compared to the average H chondrite. This could be interpreted in terms of extensive thermal metamorphism leading to melting. Apart from absolute abundance differences, there appears to be small but recognizable fractionation among the average relative REE abundances of Cl, E, H and L chondrites. However, individual chondrites within these groups showed more or less fractionated REE patterns relative to each other. The distinction between H and L chondrites was well demonstrated in Eu-Sm correlation curves and absolute abundance differences of REE and major elements. Si-normalized atomic ratios of the REE abundances in different kinds of chondrites to those in Orgueil (Cl) chondrite were 0.58 (E), 0.75 (H), 0.81 (L), 1.07 (C2) and 1.32 (C3).

Fine structures of mutually normalized rare-earth patterns of chondrites

Abstract REE abundances in ten chondrites (nine falls and one find) were determined very accurately by mass-spectrometric stable isotope dilution techniques. All of the chondrites have different relative and absolute REE patterns. Except for Eu and, rarely, for Ce, the REE abundances in chondrites are smoothly fractionated from sample to sample. Notwithstanding differences in the abundances of common REE, four of five L6 chondrites have very similar absolute Eu abundances; their mutually-normalized REE patterns are not curved, but are composed of two rectilinear segments. The Leedey-normalized REE pattern for St. Severin (LL6) is composed of two concave curves. Yonozus (H4,5) pattern shows negligibly concave curvature on both sides of Eu. Kesens (H4) pattern is unusual in its overall pattern but also in irregularities for particular elements. The irregularity may be connected with the unusually high vapor pressure of metallic Yb. The REE pattern for the Allende bulk sample shows a discontinuity, presumably reflecting its considerable heterogeneity of composition and structure. It is evident that any pattern of ordinary chondrites cannot be produced from the Allende bulk pattern. A comparison is also made with the results on the chondrite composites previously investigated.

Chondrites with peculiar rare-earth patterns

Abstract Rare-earth elements and Ba in Khohar, Abee, Indarch, Atlanta, Jajh deh Kot Lalu, and Nakhla were determined accurately by isotope dilution technique; for Atlanta only, Fe (total), Mg and Ca were also determined. Khohar shows in two aliquants a strikingly large, positive anomaly for Ce. A fragment of Abee is outstanding in having a large positive Yb anomaly and a zigzag RE pattern. It is considered that the Yb anomaly is not necessarily associated with the zigzaggedness in question. Anyway, these facts corroborate our previous observations that abundances of Ce and/or Yb could be sometimes anomalous in meteoritic and lunar materials. Atlanta also has a significant negative Eu anomaly, similar to the Eu depletions observed in lunar basalts and Ca-poor achondrites by other workers. Besides, this enstatite chondrite has a RE pattern which indicates that this meteorite is cumulate-type (solid-type) material separated perhaps from a considerably fractionated melt. Accordingly, it is suggested that it is not always appropriate to classify this type II enstatite chondrite as “chondrite”. Two fragments from Abee and Atlanta show different RE patterns. It is also observed that Ba abundances are sometimes sporadically and irregularly high.

Rare earth elements in metagabbros from the Mid-Atlantic Ridge and their possible implications for the genesis of alkali olivine basalts as well as the lizard peridotite

Two foliated metagabbros from the Mid-Atlantic Ridge near 30° N were analyzed for rare earth elements. The chondrite-normalized rare earth pattern for one of them is quite similar to those for abyssal tholeiites. The pattern for another sample, however, is somewhat different from the above one. A new set of bulk partition coefficients for rare earth elements has been estimated correspondingly. This set throws a new light on the interpretation that many alkali olivine basalts were produced by a zone melting or partial melting of primary-liquid-type material. Also the same partition coefficients lead us to an inference that the high-temperature peridotite intrusion in the Lizard area, Cornwall, England, is a secondary-solid-type material which was once in equilibrium with a primary-solid-type material, whereas the pyroxenite, Canyon Mountain, Oregon, is a primary-solid-type material.Both of the metagabbros studied show positive europium anomaly.

Evolution of lunar materials in light of the abundance variation of oxyphile trace elements

Based on the lunar data on lanthanides, U, Th, Ba, and Sr, the partition coefficients for fractional solidification were estimated for these elements. The resultant values suggest the removal of solids with perhaps pyroxenic composition. The partition coefficient for europium can be judged to be normal as divalent europium dominantly present in the melt. When we go back following the trend of fractionation of abundances, we can reach the stage where there is no europium anomaly and where the thorium concentration level is chondritic. It can be imagined that the material corresponding to this stage was the directly original lunar material system. As a possibility, a zone melting is thought to be a possible process for the derivation of that material from chondritic material. The chondrite-normalized lanthanide patterns for silicate materials of two stony-irons appear to provide us with an intriguing clue to this problem.