P. Mahaffy

MAVEN observations of the response of Mars to an interplanetary coronal mass ejection

Coupling between the lower and upper atmosphere, combined with loss of gas from the upper atmosphere to space, likely contributed to the thin, cold, dry atmosphere of modern Mars. To help understand ongoing ion loss to space, the Mars Atmosphere and Volatile Evolution (MAVEN) spacecraft made comprehensive measurements of the Mars upper atmosphere, ionosphere, and interactions with the Sun and solar wind during an interplanetary coronal mass ejection impact in March 2015. Responses include changes in the bow shock and magnetosheath, formation of widespread diffuse aurora, and enhancement of pick-up ions. Observations and models both show an enhancement in escape rate of ions to space during the event. Ion loss during solar events early in Mars history may have been a major contributor to the long-term evolution of the Mars atmosphere.

First measurements of composition and dynamics of the Martian ionosphere by MAVEN's Neutral Gas and Ion Mass Spectrometer

We report the results of the observations of the ionosphere of Mars by the Neutral Gas and Ion Mass Spectrometer. These observations were conducted during the first 8 months of the Mars Atmosphere and Volatile EvolutioN mission (MAVEN). These observations revealed the spatial and temporal structures in the density distributions of 22 ions: H2+, H3+, He+, O2+, C+, CH+, N+, NH+, O+, OH+, H2O+, H3O+, N2+/CO+, HCO+/HOC+/N2H+, NO+, HNO+, O2+, HO2+, Ar+, ArH+, CO2+, and OCOH+. Dusk/dawn and day/night asymmetries in the density distributions were observed for nearly all ion species. Additionally, high-density fluctuations were detected on the nightside and may reflect the effect of the partial screening of the atmosphere of Mars by the weak intrinsic magnetic field of the planet. The two first MAVEN “deep dip” campaigns were used to investigate the location of the primary ion peak. This peak was detected at 190 km near the terminator but was below the spacecraft altitude of 130 km near the subsolar point.

Early MAVEN Deep Dip campaign reveals thermosphere and ionosphere variability

The Mars Atmosphere and Volatile Evolution (MAVEN) mission, during the second of its Deep Dip campaigns, made comprehensive measurements of martian thermosphere and ionosphere composition, structure, and variability at altitudes down to ~130 kilometers in the subsolar region. This altitude range contains the diffusively separated upper atmosphere just above the well-mixed atmosphere, the layer of peak extreme ultraviolet heating and primary reservoir for atmospheric escape. In situ measurements of the upper atmosphere reveal previously unmeasured populations of neutral and charged particles, the homopause altitude at approximately 130 kilometers, and an unexpected level of variability both on an orbit-to-orbit basis and within individual orbits. These observations help constrain volatile escape processes controlled by thermosphere and ionosphere structure and variability.

Did life exist on Mars? Search for organic and inorganic signatures, one of the goals for “SAM” (sample analysis at Mars)

Observation of Mars shows signs of a past Earth-like climate, and, in that case, there is no objection to the possible development of life, in the underground or at the surface, as in the terrestrial primitive biosphere. Sample analysis at Mars (SAM) is an experiment which may be proposed for atmospheric, ground and underground in situ measurements. One of its goals is to bring direct or indirect information on the possibility for life to have developed on Mars, and to detect traces of past or present biological activity. With this aim, it focuses on the detection of organic molecules: volatile organics are extracted from the sample by simple heating, whereas refractory molecules are made analyzable (i.e. volatile), using derivatization technique or fragmentation by pyrolysis. Gaseous mixtures thus obtained are analyzed by gas chromatography associated to mass spectrometry. Beyond organics, carbonates and other salts are associated to the dense and moist atmosphere necessary to the development of life, and might have formed and accumulated in some places on Mars. They represent another target for SAM. Heating of the samples allows the analysis of structural gases of these minerals (CO2 from carbonates, etc.), enabling to identify them. We also show, in this paper, that it may be possible to discriminate between abiotic minerals, and minerals (shells, etc.) created by living organisms.

Cassini orbiter ion and neutral mass spectrometer instrument

The Cassini Orbiter Ion and Neutral Mass Spectrometer (INMS) is designed to measure the composition and density variations of low energy ions and neutral species in the upper atmosphere of Titan, in the vicinity of the icy satellites and in the inner magnetosphere of Saturn where densities are sufficiently high for measurement. The sensor utilizes a dual radio frequency quadrupole mass analyzer with a mass range of 1-99 amu, two electron multipliers operated in pulse-counting mode to cover the dynamic range required and two separate ion sources. A closed ion source measures non-surface reactive neutral species which have thermally accommodated to the inlet walls such as N2 and CH4. An open ion source allows direct beaming ions or chemically active neutral species such as N and HCN to be measured without surface interaction. The instrument can alternate between these three different modes. Characterization and calibration of each of these three modes is done using a low energy ion beam, a neutral molecular beam and a neutral thermal gas source. An onboard flight computer is used to control instrument operating parameters in accordance with pre-programmed sequences and to package the telemetry data. The sensor is sealed and maintained in a vacuum prior to launch to provide a clean environment for measurement of neutral species when it is opened to the ambient atmosphere after orbit insertion. The instrument is provided by NASA/Goddard Spaceflight Center, Code 915. Operation of the instrument and data analysis will be carried out by a Science Team.

In situ inorganic and organic analysis (Pyr/CD-GC/MS) of the Martian soil, on the Mars 2005 mission

In order to obtain mineralogical information, the Mars Sample Return mission, in 2003 and 2005, will include sub-surface sampling. One expects that the e/ects of UV radiations and oxidizingag ents are attenuated at depths correspondingto the bottom of the drilled cavity. In this case, such samplingwill also allow to determine if life is or has been present at the surface of Mars. We propose to perform a preliminary in situ analysis of Martian samples: SAM (Sample Analysis on Mars) on MSR 2005 lander. Such an analysis, performed on some parts of dedicated samples, will have the advantage of producing a ground-truth for the Earth-based analysis. Indeed, MSR 2003=2005 samples will be delivered to Earth laboratories in 2008, or 2009, dependingon the duration of the quarantine, and it is not stated that some of their properties will remain unaltered duringthese three to 6 years. Moreover, there is a possibility that Martian sub-surface drillingdelivers redundant samples: SAM could help to select, among st the samples, which ones deserve to be sent to Earth, and, should the occasion arise, what are their unexpected peculiarities. To analyze inorganics and organics sampled at various depths, we propose to use the pyrolysis=chemical derivatization/gas chromatography/mass spectrometry technique. This experiment may be performed usingtechniques already developed in the frame of other planetary (ACP =HUYGENS) or cometary (COSAC=ROSETTA) missions, which can easily be adapted to the proposed mission objective, accordingto the three followingtopics: search for org anics, search for inorganics and isotope characterization. c

Photoelectrons and solar ionizing radiation at Mars: Predictions versus MAVEN observations

Understanding the evolution of the Martian atmosphere requires knowledge of processes transforming solar irradiance into thermal energy well enough to model them accurately. Here we compare Martian photoelectron energy spectra measured at periapsis by Mars Atmosphere and Volatile Evolution MissioN (MAVEN) with calculations made using three photoelectron production codes and three solar irradiance models as well as modeled and measured CO2 densities. We restricted our comparisons to regions where the contribution from solar wind electrons and ions were negligible. The two intervals examined on 19 October 2014 have different observed incident solar irradiance spectra. In spite of the differences in photoionization cross sections and irradiance spectra used, we find the agreement between models to be within the combined uncertainties associated with the observations from the MAVEN neutral density, electron flux, and solar irradiance instruments.

Ion Densities in the Nightside Ionosphere of Mars: Effects of Electron Impact Ionization

We use observations from the Mars Atmosphere and Volatile EvolutioN(MAVEN) mission to show how superthermal electron fluxes and crustal magnetic fields affect ion densities in the nightside ionosphere of Mars. We find that, due to electron impact ionization, high electron fluxes significantly increase the CO2+ , O+, and O2+ densities below 200 km, but only modestly increase the NO+ density. High electron fluxes also produce distinct peaks in the CO2+ , O+, and O2+ altitude profiles. We also find that superthermal electron fluxes are smaller near strong crustal magnetic fields. Consequently, nightside ion densities are also smaller near strong crustal fields because they decay without being replenished by electron impact ionization. Furthermore, the NO+/O2+ ratio is enhanced near strong crustal fields because, in the absence of electron impact ionization, O2+ is converted into NO+ and not replenished. Our results show that electron impact ionization is a significant source of CO2+ , O+, and O2+ in the nightside ionosphere of Mars.