Paul C. Simon

Atmospheric Chemistry Experiment (ACE): Mission overview

SCISAT-1, also known as the Atmospheric Chemistry Experiment (ACE), is a Canadian satellite mission for remote sensing of the Earths atmosphere. It was launched into low Earth circular orbit (altitude 650 km, inclination 74°) on 12 Aug. 2003. The primary ACE instrument is a high spectral resolution (0.02 cm-1) Fourier Transform Spectrometer (FTS) operating from 2.2 to 13.3 μm (750-4400 cm-1). The satellite also features a dual spectrophotometer known as MAESTRO with wavelength coverage of 285-1030 nm and spectral resolution of 1-2 nm. A pair of filtered CMOS detector arrays records images of the Sun at 0.525 and 1.02 μm. Working primarily in solar occultation, the satellite provides altitude profile information (typically 10-100 km) for temperature, pressure, and the volume mixing ratios for several dozen molecules of atmospheric interest, as well as atmospheric extinction profiles over the latitudes 85°N to 85°S. This paper presents a mission overview and some of the first scientific results. Copyright 2005 by the American Geophysical Union.

Measurements of the NO2 absorption cross-section from 42 000 cm−1 to 10 000 cm−1 (238–1000 nm) at 220 K and 294 K

Abstract The NO2 absorption cross-section has been measured from 42 000 to 10 000 cm−1 (238–1000 nm) with a Fourier transform spectrometer (at the resolution of 2 cm−1, 0.01 nm at 240 nm to 0.2 nm at 1000 nm) and a 5 m temperature controlled multiple reflection cell. The uncertainty on the cross-section is estimated to be less than 3% below 40 000 cm−1 (λ > 250 nm) at 294 K, 3% below 30 000 cm−1 (λ > 333 nm) at 220 K, but reaches 10% for higher wavenumbers. Temperature and pressure effects have been observed. Comparison with data from the literature generally shows a good agreement for wavenumbers between 37 500 and 20 000 cm−1 (267–500 nm). Outside these limits, the difference can reach several percent.

Chemistry of the 1991–1992 stratospheric winter: Three-dimensional model simulations

A three-dimensional chemistry-transport model of the stratosphere is used to simulate the evolution of trace constituents during the 1991–1992 Arctic winter. It is shown that heterogeneous reactions on polar stratospheric clouds led in early January to almost complete activation of atmospheric chlorine inside the polar vortex, in remarkable coincidence with observations by the ER-2 aircraft (Toohey et al., 1993) and the microwave limb sounder on the Upper Atmosphere Research Satellite (Waters et al., 1993). Sulfate aerosols resulting from the eruption of Mount Pinatubo also produced a significant increase in chlorine monoxide (ClO) concentrations at middle and high latitudes. The net chemical destruction of ozone found in the vortex at the end of the simulation (25% at 50 hPa and 25 DU), although substantial, was limited by available sunlight and the short period during which stratospheric clouds occurred.

SO2 Absorption Cross-section Measurement in the UV using a Fourier Transform Spectrometer

Absorption cross sections of SO2 have been recorded at 295 K at the resolutions of 2 and 16 cm−1. The 27000- to 40000-cm−1 spectral region has been investigated. The comparison with data available from the literature shows a good agreement between the different data sets (less than 5%). However, local discrepancies, for example at the peaks of absorption, can reach 20%.

Fourier transform measurement of NO2 absorption cross-section in the visible range at room temperature

New laboratory measurements of NO2 absorption cross-section were performed using a Fourier transform spectrometer at 2 and 16 cm-1 (0.03 and 0.26 nm at 400 nm) in the visible range (380–830 nm) and at room temperature. The use of a Fourier transform spectrometer leads to a very accurate wavenumber scale (0.005 cm-1, 8×10-5 nm at 400 nm). The uncertainty on the new measurements is better than 4%. Absolute and differential cross-sections are compared with published data, giving an agreement ranging from 2 to 5% for the absolute values. The discrepancies in the differential cross-sections can however reach 18%. The influence of the cross-sections on the ground-based measurement of the stratospheric NO2 total amount is also investigated.

Infrared cross sections and global warming potentials of 10 alternative hydrohalocarbons

Absorption cross sections have been obtained in the infrared atmospheric window, between 600 and 1500 cm−1, for 10 alternative hydrohalocarbons: HCFC22, HCFC123, HCFC124, HCFC141b, HCFC142b, HCFC225ca, HCFC225cb, HFC125, HFCl34a and HFCl52a. The measurements were made at three temperatures (287 K, 270 K and 253 K) with a Fourier transform spectrometer operating at 0.03 cm−1 apodized resolution. Integrated cross sections have been introduced into a two-dimensional radiative-chemical-dynamical model in order to calculate the global warming potential (GWP) of each gas.

Intercomparison of UV/visible spectrometers for measurements of stratospheric NO2 for the Network for the Detection of Stratospheric Change

During the period May 12–23, 1992, seven groups from seven countries met in Lauder, New Zealand, to intercompare their remote sensing instruments for the measurement of atmospheric column NO2 from the surface. The purpose of the intercomparison was to determine the degree of intercomparability and to qualify instruments for use in the Network for the Detection of Stratospheric Change (NDSC). Three of the instruments which took part in the intercomparison are slated for deployment at primary NDSC sites. All instruments were successful in obtaining slant column NO2 amounts at sunrise and sunset on most of the 12 days of the intercomparison. The group as a whole was able to make measurements of the 90° solar zenith angle slant path NO2 column amount that agreed to about ±10% most of the time; however, the sensitivity of the individual measurements varied considerably. Part of the sensitivity problem for these measurements is the result of instrumentation, and part is related to the data analysis algorithms used. All groups learned a great deal from the intercomparison and improved their results considerably as a result of this exercise.

The Visible Solar Spectral Irradiance from 350 to 850 nm as Measured by the Solspec Spectrometer During the Atlas I Mission

The SOLSPEC instrument has been built to carry out solar spectral irradiance measurements from 200 to 3000 nm. It consists of three spectrometers designed to measure the solar spectral irradiance in ultraviolet, visible, and infrared domains. It flew with the ATLAS I mission in March 1992. This paper is dedicated to the visible part of the solar spectrum. Comparisons with recent data are shown and differences below 450 nm are discussed.

Ultraviolet solar irradiance measurement from 200 to 358 nm during spacelab 1 mission

The paper presents the results obtained from the UV-spectrometer of the ‘Solar Spectrum Experiment’ during the Spacelab 1 mission in December 1983. The irradiance data concern 492 passbands, which are located between 200 and 358 nm at almost equidistant wavelengths separated by about 0.3 nm. The passbands have a well-defined, bell-shaped profile with a full width at half maximum of about 1.3 nm. The data, which have an error budget between 4 and 5%, agree closely with the spectral distributions observed by Heath (1980) and Mentall et al. (1981) and confirm that the solar irradiance and the fluxes of Sun-like stars show about the same spectral distribution down to at least 240 nm.

The study of the martian atmosphere from top to bottom with SPICAM light on mars express

Abstract SPICAM Light is a small UV-IR instrument selected for Mars Express to recover most of the science that was lost with the demise of Mars 96, where the SPICAM set of sensors was dedicated to the study of the atmosphere of Mars (Spectroscopy for the investigation of the characteristics of the atmosphere of mars). The new configuration of SPICAM Light includes optical sensors and an electronics block. A UV spectrometer (118–320 nm, resolution 0.8 nm) is dedicated to Nadir viewing, limb viewing and vertical profiling by stellar occultation (3.8 kg). It addresses key issues about ozone, its coupling with H2O, aerosols, atmospheric vertical temperature structure and ionospheric studies. An IR spectrometer (1.2– 4.8 μm , resolution 0.4–1 nm) is dedicated to vertical profiling during solar occultation of H2O, CO2, CO, aerosols and exploration of carbon compounds (3.5 kg). A nadir looking sensor for H2O abundances (1.0– 1.7 μm , resolution 0.8 nm) is recently included in the package (0.8 kg). A simple data processing unit (DPU, 0.9 kg) provides the interface of these sensors with the spacecraft. In nadir orientation, SPICAM UV is essentially an ozone detector, measuring the strongest O3 absorption band at 250 nm in the spectrum of the solar light scattered back from the ground. In the stellar occultation mode the UV Sensor will measure the vertical profiles of CO2, temperature, O3, clouds and aerosols. The density/temperature profiles obtained with SPICAM Light will constrain and aid in the development of the meteorological and dynamical atmospheric models, from the surface to 160 km in the atmosphere. This is essential for future missions that will rely on aerocapture and aerobraking. UV observations of the upper atmosphere will allow study of the ionosphere through the emissions of CO, CO+, and CO2+, and its direct interaction with the solar wind. Also, it will allow a better understanding of escape mechanisms and estimates of their magnitude, crucial for insight into the long-term evolution of the atmosphere. The SPICAM Light IR sensor is inherited from the IR solar part of the SPICAM solar occultation instrument of Mars 96. Its main scientific objective is the global mapping of the vertical structure of H2O, CO2, CO, HDO, aerosols, atmospheric density, and temperature by the solar occultation. The wide spectral range of the IR spectrometer and its high spectral resolution allow an exploratory investigation addressing fundamental question of the possible presence of carbon compounds in the Martian atmosphere. Because of severe mass constraints this channel is still optional. An additional nadir near IR channel that employs a pioneering technology acousto-optical tuneable filter (AOTF) is dedicated to the measurement of water vapour column abundance in the IR simultaneously with ozone measured in the UV. It will be done at much lower telemetry budget compared to the other instrument of the mission, planetary fourier spectrometer (PFS).