Paul L. Younger

Mine Water Hydrology

Hydrology is a relatively young science, which has developed gradually out of the hydraulic expedients which underpin much of civil engineering practice. Indeed, the emergence of truly scientific hydrology is such a recent development that major textbooks and learned journals have until recently devoted many pages to discussing its scientific credentials (Bras, 1990; Wilby, 1997). Until the 1980s most hydrological analysis was concerned with purely physical processes and practices of engineering interest, such as rainfall-runoff modelling and flow-net analysis of seepage pathways. By the start of the 21st Century, the scope of hydrology has expanded to such an extent that it now embraces relevant areas of chemistry and ecology. Sub-disciplines such as hydrogeochemistry (e.g. Appelo and Postma, 1994) and hydroecology (or ecohydrology; Baird and Wilby, 1999) are now firmly established, and account for a large proportion of the innovation in hydrological science (see, for instance, Wilby, 1997, and Wheater and Kirby, 1998). The “scientification” of hydrology has now proceeded to such an extent that Wilby (1997) could claim that hydrology provides the most logical basis for ‘holistic environmental science’, since water is a prominent medium in all of the earth and life sciences which deal with the natural environment. In the light of these trends, a contemporary definition of hydrology might be given as follows: “Hydrology is the science which deals with the nature, movement and environmental functions of terrestrial natural waters”

Mining Impacts on the Fresh Water Environment: Technical and Managerial Guidelines for Catchment Scale Management

Hydrological drainage/river basins constitute highly heterogeneous systems of coupled natural and anthropogenic water and pollutant flows across political, national and international boundaries. These flows need to be appropriately understood, quantified and communicated to stakeholders, in order to appropriately guide environmental water system management. In this thesis, various uncertainties about water and pollutant flows in drainage/river basins and their implications for effective and efficient water pollution abatement are investigated, in particular for mine-related heavy metal loadings in the Swedish Dalalven River basin and for nitrogen loadings in the Swedish Norrstrom drainage basin. Economic cost-minimization modeling is used to investigate the implications of pollutant load uncertainties for the cost-efficiency of catchment-scale abatement of water pollution. Results indicate that effective and efficient pollution abatement requires explicit consideration of uncertainties about pollution sources, diffuse contributions of the subsurface water system to downstream pollutant observations in surface waters, and downstream effects of different possible measures to reduce water pollution. In many cases, downstream load abatement measures must be used, in addition to source abatement, in order to reduce not only expected, but also uncertainties around expected pollutant loads. Effective and efficient environmental management of water systems must generally also consider the entire catchments of these systems, rather than focusing only on discrete pollutant sources. The thesis presents some relatively simple, catchment-scale pollutant flow analysis tools that may be used to decrease uncertainties about unmonitored water and pollutant flows and subsurface pollutant accumulation-depletion and diffuse loading to downstream waters.

Mine water pollution in Scotland: nature, extent and preventative strategies.

Scotland was one of the worlds first industrialised countries, and has therefore also been one of the first countries to experience wholesale post-industrial dereliction. Water pollution arising from abandoned mines, particularly abandoned coal mines, is second only to sewage as a source of freshwater pollution nation-wide, and in many coalfield catchments it is the pre-eminent source. Most of the pollution is due to net-alkaline ferruginous waters emerging from deep mines. Scrutiny of records from 80 deep mine discharges reveals that iron concentrations in these waters are only likely to exceed 20 mg/l, and the pH to be below 6.5, where the discharge emerges within 0.5 km of the outcrop of the shallowest mined seam. The bulk of mature near-outcrop mine water discharges in Scotland have < 50 mg/l total Fe, and concentrations > 100 mg/l are only likely where a marine bed lies within 25 m of the worked seam. Where the nearest marine bed is more than 80 m above or below the seam, then the total iron will be less than 4 mg/l, and in most cases less than 1 mg/l. Net-acidic mine waters are far more rare than net-alkaline waters in Scotland, and are most commonly associated with unreclaimed spoil heaps (bings). Both net-alkaline and net-acidic discharges have detrimental effects on the hydrochemistry and biological integrity of receiving waters. Scotland has recently pioneered the use of pre-emptive pump-and-treat solutions to prevent mine water pollution, and has also experienced the successful introduction of passive treatment technology for both abandoned and active workings.

Substrate characterisation for a subsurface reactive barrier to treat colliery spoil leachate

Subsurface permeable reactive barriers (PRB) have been used to successfully treat acidic mine drainage in Canada and offer great potential for doing the same in the United Kingdom. A PRB for the treatment of colliery spoil leachate from a site near Newcastle upon Tyne, UK, has been designed. The selection of the reactive media to be used is of paramount importance, with particular reference to permeability and reactivity. A number of reactive media mixtures containing varying proportions of cattle slurry screenings, green waste compost, calcite limestone chips and pea gravel were prepared and their respective permeabilities and reactivities were investigated. Media mixtures containing 50% 10 mm grade calcite limestone chips showed better alkalinity addition and metals removal than a blank containing 50% pea gravel. A media mixture containing 50% limestone chips and 50% green waste compost showed a 24 h period to achieve maximum addition of alkalinity and maximum removal of acidity and metals. Mixtures containing 25% green waste compost and 25% slurry screenings achieved maximum addition/removal in 4 h. The likely presence of iron sulphide in samples drawn from test vessels during both test runs indicates that bacterial sulphate reduction is occurring in this composite.

Wetland treatment at extremes of pH: A review

Constructed wetlands are an established treatment technology for a diverse range of polluted effluents. There is a long history of using wetlands as a unit process in treating acid mine drainage, while recent research has highlighted the potential for wetlands to buffer highly alkaline (pH>12) drainage. This paper reviews recent evidence on this topic, looking at wetlands treating acidic mine drainage, and highly alkaline leachates associated with drainage from lime-rich industrial by-products or where such residues are used as filter media in constructed wetlands for wastewater treatment. The limiting factors to the success of wetlands treating highly acidic waters are discussed with regard to design practice for the emerging application of wetlands to treat highly alkaline industrial discharges. While empirically derived guidelines (with area-adjusted contaminant removal rates typically quoted at 10 g Fe m(2)/day for influent waters pH>5.5; and 3.5-7 g acidity/m(2)/day for pH>4 to <5.5) for informing sizing of mine drainage treatment wetlands have generally been proved robust (probably due to conservatism), such data exhibit large variability within and between sites. Key areas highlighted for future research efforts include: (1) wider collation of mine drainage wetland performance data in regionalised datasets to improve empirically-derived design guidelines and (2) obtaining an improved understanding of nature of the extremophile microbial communities, microbially-mediated pollutant attenuation and rhizospheral processes in wetlands at extremes of pH. An enhanced knowledge of these (through multi-scale laboratory and field studies), will inform engineering design of treatment wetlands and assist in the move from the empirically-derived conservative sizing estimates that currently prevail to process-based optimal design guidance that could reduce costs and enhance the performance and longevity of wetlands for treating acidic and highly alkaline drainage waters.

Predicting temporal changes in total iron concentrations in groundwaters flowing from abandoned deep mines: a first approximation

Abstract Discharges of contaminated groundwater from abandoned deep mines are a major environmental problem in many parts of the world. While process-based models of pollutant generation have been successfully developed for certain surface mines and waste rock piles of relatively simple geometry and limited areal extent, such models are not readily applicable to large systems of laterally extensive, interconnected, abandoned deep mines. As a first approximation for such systems, hydrological and lithological factors, which can reasonably be expected to influence pollutant release, have been assessed by empirically assessing data from 81 abandoned deep coal mine discharges in the UK. These data demonstrate that after flooding of a deep mine is complete and groundwater begins to migrate from the mine voids into surface waters or adjoining aquifers, flushing of the mine voids by fresh recharge results in a gradual improvement in the quality of groundwater (principally manifested as decreasing Fe concentrations and stabilisation of pH around 7). Alternative representations of the flushing process have been examined. While elegant analytical solutions of the advection–dispersion equation can be made to mimic the changes in iron concentration, parameterisation is tendentious in practice. Scrutiny of the UK data suggest that to a first approximation, the duration of the main period of flushing can be predicted to endure around four times as long as the foregoing process of mine flooding. Short- and long-term iron concentrations (i.e. at the start of the main period of flushing and after its completion, respectively) can be estimated from the sulphur content of the worked strata. If strata composition data are unavailable, some indication of pollution potential can be obtained from considerations of the proximity of worked strata to marine beds (which typically have high pyrite contents). The long-term concentrations of iron in a particular discharge can also be approximated on the basis of the proximity of the discharge location to the outcrop of the most closely associated coal seam (MCACS) and, thus, to zones of possible ongoing pyrite oxidation. The practical application of these simple predictive techniques is facilitated by means of a flowchart.

Long-term changes in the quality of polluted minewater discharges from abandoned underground coal workings in Scotland

Abstract Long-term trends of changes in the quality of water discharging from abandoned coal mines have been studied for 32 long-established discharges in the Midland Valley of Scotland. Six discharges have been studied in greater detail, providing insights into discharge quality evolution over more than a century. It has been found that minewater pollution is most severe in the first few decades after a discharge begins (the ‘first flush’), and that even the largest systems settle down to a lower level of pollution (particularly in terms of iron concentration) within 40 years. Long-term iron concentrations of less than 30 mg/1 are typical, and many are less than 10 mg/1. Low pH values (which might justify the over-used term ‘acid mine drainage’) do not generally persist, due to the rapid buffering of localized acidic waters by carbonates (both natural carbonates, and those introduced as rock powder for fire precautions during mining). This is corroborated by alkalinity concentrations, which tend to be highest in the early years of a discharge. While the pyrite content of the worked sequence strongly influences initial water quality (in terms of pH, iron and sulphate) during the ‘first flush’, there appears to be no correlation between long-term iron concentrations of discharges and pyrite content of local strata. Rather, higher levels are found in any sequence where there is scope for fluctuations of the water table in worked ground near to the discharge. A scientific approach to minewater remediation should allow for active treatment of discharges for the first decade or two, followed by long-term passive treatment after asymptotic pollutant concentrations are attained.

Broadening the scope of mine water environmental impact assessment: a UK perspective

Abstract Mine water pollution is one of the most severe forms of aquatic pollution in the UK, and it is a widespread problem internationally. The impacts of mine waters and current methodologies for quantifying these impacts are detailed. Current EIA methods take little account of the socioeconomic effects of these discharges, which can be severe. Local public interest and concern may constitute a major driving force towards remedial action. A number of benefits are associated with involving local communities in mine water EIA and remediation. Thus, some provision for incorporating these issues into mine water EIA is recommended. There is also a pressing need to develop predictive EIA strategies for future mine water discharges. While predictions of the pollution risks associated with a cessation of deep mining are now possible, the accuracy and precision of the latest techniques still falls short of what is needed to allow rational cost–benefit analysis of future environmental management options for redundant mine workings.

The adoption and adaptation of passive treatment technologies for mine waters in the United Kingdom

AbstractDuring the 1990s, passive treatment technology was introduced to the United Kingdom (UK). Early hesitancy on the part of regulators and practitioners was rapidly overcome, at least for net-alkaline mine waters, so that passive treatment is now the technology of choice for the long-term remediation of such discharges, wherever land availability is not unduly limiting. Six types of passive systems are now being used in the UK for mine water treatment:♦ aerobic, surface flow wetlands (reed-beds);♦ anaerobic, compost wetlands with significant surface flow;♦ mixed compost/limestone systems, with predominatly subsurface flow (so-calledReducing andAlkalinityProducingSystems (RAPS));♦ subsurface reactive barriers to treat acidic, metalliferous ground waters;♦ closed-system limestone dissolution systems for zinc removal from alkaline waters;♦ roughing filters for treating ferruginous mine waters where land availability is limited. Each of these technologies is appropriate for a different kind of mine water, or for specific hydraulic circumstances. The degree to which each type of system can be considered “proven technology” corresponds to the order in which they are listed above. Many of these passive systems have become foci for detailed scientific research, as part of a

Hydrogeochemistry of minewaters flowing from abandoned coal workings in County Durham

1.5M European Commission project running from 2000 to 2003.