Paule Sonnentrucker

A Far Ultraviolet Spectroscopic Explorer Survey of Interstellar Molecular Hydrogen in Translucent Clouds

We report the first ensemble results from the Far Ultraviolet Spectroscopic Explorer survey of molecular hydrogen in lines of sight with AV e1 mag. We have developed techniques for fitting computed profiles to the low-J lines of H2, and thus determining column densities for J ¼ 0 and J ¼ 1, which contain e99% of the total H2. From these column densities and ancillary data we have derived the total H2 column densities, hydrogen molecular fractions, and kinetic temperatures for 23 lines of sight. This is the first significant sample of molecular hydrogen column densities of � 10 21 cm � 2 , measured through UV absorption bands. We have also compiled a set of extinction data for these lines of sight, which sample a wide range of environments. We have searched for correlations of our H2-related quantities with previously published column densities of other molecules and extinction parameters. We find strong correlations between H2 and molecules such as CH, CN, and CO, in general agreement with predictions of chemical models. We also find the expected correlations between hydrogen molecular fraction and various density indicators such as kinetic temperature, CN

STUDIES OF THE DIFFUSE INTERSTELLAR BANDS. III. HD 183143

Echelle spectra of HD 183143 [B7Iae, E(B − V) = 1.27] were obtained on three nights, at a resolving power R = 38,000 and with a signal-to-noise ratio ≈ 1000 at 6400 A in the final, combined spectrum. A catalog is presented of 414 diffuse interstellar bands (DIBs) measured between 3900 and 8100 A in this spectrum. The central wavelengths, the widths (FWHM), and the equivalent widths of nearly all of the bands are tabulated, along with the minimum uncertainties in the latter. Among the 414 bands, 135 (or 33%) were not reported in four previous, modern surveys of the DIBs in the spectra of various stars, including HD 183143. The principal result of this study is that the great majority of the bands in the catalog are very weak and fairly narrow. Typical equivalent widths amount to a few mA, and the bandwidths (FWHM) are most often near 0.7 A. No preferred wavenumber spacings among the 414 bands are identified which could provide clues to the identities of the large molecules thought to cause the DIBs. At generally comparable detection limits in both spectra, the population of DIBs observed toward HD 183143 is systematically redder, broader, and stronger than that seen toward HD 204827 (Paper II). In addition, interstellar lines of C2 molecules have not been detected toward HD 183143, while a very high value of N(C2)/E(B − V )i s observed toward HD 204827. Therefore, either the abundances of the large molecules presumed to give rise to the DIBs, or the physical conditions in the absorbing clouds, or both, must differ significantly between the two cases.

STUDIES OF DIFFUSE INTERSTELLAR BANDS V. PAIRWISE CORRELATIONS OF EIGHT STRONG DIBs AND NEUTRAL HYDROGEN, MOLECULAR HYDROGEN, AND COLOR EXCESS

We establish correlations between equivalent widths of eight diffuse interstellar bands (DIBs), and examine their correlations with atomic hydrogen, molecular hydrogen, and E B?V . The DIBs are centered at ?? 5780.5, 6204.5, 6283.8, 6196.0, 6613.6, 5705.1, 5797.1, and 5487.7, in decreasing order of Pearsons correlation coefficient with N(H) (here defined as the column density of neutral hydrogen), ranging from 0.96 to 0.82. We find the equivalent width (EW) of ?5780.5 is better correlated with column densities of H than with E B?V or H2, confirming earlier results based on smaller data sets. We show that the same is true for six of the seven other DIBs presented here. Despite this similarity, the eight strong DIBs chosen are not correlated well enough with each other to suggest they come from the same carrier. We further conclude that these eight DIBs are more likely to be associated with H than with H2, and hence are not preferentially located in the densest, most UV shielded parts of interstellar clouds. We suggest that they arise from different molecules found in diffuse H regions with very little H2 (molecular fraction f < 0.01). Of the 133 stars with available data in our study, there are three with significantly weaker ?5780.5 than our mean H-?5780.5 relationship, all of which are in regions of high radiation fields, as previously noted by Herbig. The correlations will be useful in deriving interstellar parameters when direct methods are not available. For instance, with care, the value of N(H) can be derived from W ?(5780.5).

Interstellar OH+, H2O+ and H3O+ along the sight-line to G10.6–0.4

We report the detection of absorption lines by the reactive ions OH + ,H 2O + and H3O + along the line of sight to the submillimeter continuum source G10.6−0.4 (W31C). We used the Herschel HIFI instrument in dual beam switch mode to observe the ground state rotational transitions of OH + at 971 GHz, H2O + at 1115 and 607 GHz, and H3O + at 984 GHz. The resultant spectra show deep absorption over a broad velocity range that originates in the interstellar matter along the line of sight to G10.6−0.4 as well as in the molecular gas directly associated with that source. The OH + spectrum reaches saturation over most velocities corresponding to the foreground gas, while the opacity of the H2O + lines remains lower than 1 in the same velocity range, and the H3O + line shows only weak absorption. For LSR velocities between 7 and 50 kms −1 we estimate total column densities of N(OH + ) ≥ 2.5 × 10 14 cm −2 , N(H2O + ) ∼6 × 10 13 cm −2 and N(H3O + ) ∼4.0 × 10 13 cm −2 . These detections confirm the role of O + and OH + in initiating the oxygen chemistry in diffuse molecular gas and strengthen our understanding of the gas phase production of water. The high ratio of the OH + by the H2O + column density implies that these species predominantly trace low-density gas with a small fraction of

Herschel/HIFI observations of interstellar OH+ and H2O+ towards W49N: a probe of diffuse clouds with a small molecular fraction

We report the detection of absorption by interstellar hydroxyl cations and water cations, along the sight-line to the bright continuum source W49N. We have used Herschels HIFI instrument, in dual beam switch mode, to observe the 972 GHz N = 1-0 transition of OH+ and the 1115 GHz 1(11)-0(00) transition of ortho-H2O+. The resultant spectra show absorption by ortho-H2O+, and strong absorption by OH+, in foreground material at velocities in the range 0 to 70 km s(-1) with respect to the local standard of rest. The inferred OH+/H2O+ abundance ratio ranges from similar to 3 to similar to 15, implying that the observed OH+ arises in clouds of small molecular fraction, in the 2-8% range. This conclusion is confirmed by the distribution of OH+ and H2O+ in Doppler velocity space, which is similar to that of atomic hydrogen, as observed by means of 21 cm absorption measurements, and dissimilar from that typical of other molecular tracers. The observed OH+/H abundance ratio of a few x10(-8) suggests a cosmic ray ionization rate for atomic hydrogen of 0.6-2.4 x 10(-16) s(-1), in good agreement with estimates inferred previously for diffuse clouds in the Galactic disk from observations of interstellar H-3(+) and other species.

Spitzer Observations of HH 54 and HH 7-11: Mapping the H2 Ortho-to-Para Ratio in Shocked Molecular Gas

We report the results of spectroscopic mapping observations carried out toward the Herbig-Haro objects HH 7-11 and HH 54 over the 5.2-37 μm region using the Infrared Spectrograph on the Spitzer Space Telescope. These observations have led to the detection and mapping of the S(0)-S(7) pure rotational lines of molecular hydrogen, together with emissions in fine-structure transitions of Ne+, Si+, S, and Fe+. The H2 rotational emissions indicate the presence of warm gas with a mixture of temperatures in the range 400-1200 K—consistent with the expected temperature behind nondissociative shocks of velocity ~10-20 km s-1—while the fine-structure emissions originate in faster shocks of velocity ~35-90 km s-1 that are dissociative and ionizing. The H2 ortho-to-para ratio is quite variable, typically falling substantially below the equilibrium value of 3 attained at the measured gas temperatures. The nonequilibrium ortho-to-para ratios are characteristic of temperatures as low as ~50 K, and are a remnant of an earlier epoch, before the gas temperature was elevated by the passage of a shock. Correlations between the gas temperature and H2 ortho-to-para ratio show that ortho-to-para ratios <0.8 are attained only at gas temperatures below ~900 K; this behavior is consistent with theoretical models in which the conversion of para- to ortho-H2 behind the shock is driven by reactive collisions with atomic hydrogen, a process that possesses a substantial activation energy barrier (EA/k ~ 4000 K) and is therefore very inefficient at low temperature. The lowest observed ortho-to-para ratios of only ~0.25 suggest that the shocks in HH 54 and HH 7 are propagating into cold clouds of temperature 50 K in which the H2 ortho-to-para ratio is close to equilibrium.

Abundances and Behavior of 12CO, 13CO, and C2 in Translucent Sight Lines*

Using UV spectra obtained with FUSE, HST, and/or IUE together with higher resolution optical spectra, we determine interstellar column densities of 12 CO, 13 CO, and/or C2 for 10 Galactic sight lines with E(BV ) ranging from 0.37 to 0.72. The N(CO)/N(H2) ratio varies over a factor of 100 in this sample, due primarily to differences in N(CO). For a given N(H2), published models of diffuse and translucent clouds predict less CO than is observed. The J ¼ 1Y3 rotational levels of 12 CO are subthermally populated in these sight lines, with Tex typically between 3 and 7 K. In general, there appears to be no significant difference between the excitation temperatures of 12 CO and 13 CO. Fits to the higher resolution CO line profiles suggest that CO (like CN) is concentrated in relatively cold, dense gas. WeobtainC2columndensitiesfrom theFYX(0Y0)bandat13418(threesight lines;J ¼ 0Y12), theFYX(1Y0)band at1314 8(one sight line;J ¼ 0Y12), theDYX(0Y0) band at 2313 8(four sight lines; J ¼ 0Y18), and the AYX(3Y0) and (2Y0) bands at 7719 and 8757 8 (seven sight lines; J ¼ 0Y12). Comparisons among those column densities yield a set of mutually consistent band f-values for the UV and optical C2 bands, but also reveal some apparent anomalies within the FYX (0Y0) band. Both the kinetic temperature Tk inferred from the C2 rotational populations and the excitation temperature T02(C2) are generally smaller than the corresponding T01(H2)—suggesting that C2 is concentratedincolder,densergasthanH2.IncorporatingadditionalcolumndensitydataforKi,HD,CH,C2,C3,CN, andCOfromtheliterature(foratotalsampleof 74sightlines),wefindthat(1)COismosttightlycorrelatedwithCN; (2) the ratios 12 CO/H2 and 13 CO/H2 both are fairly tightly correlated with the density indicator CN/CH (but C2/H2 is not);and(3)theratio 12 CO/ 13 COissomewhatanticorrelatedwithbothCN/CHandN(CO).Sightlineswith 12 CO/ 13 CO below the average local Galactic value of 12 C/ 13 C appear to sample colder, denser gas in which isotope exchange re- actions have enhanced 13 CO, relative to 12 CO. Subject headingg ISM: clouds — ISM: molecules — ultraviolet: ISM

CallFUSE Version 3: A Data Reduction Pipeline for the Far Ultraviolet Spectroscopic Explorer

Since its launch in 1999, the Far Ultraviolet Spectroscopic Explorer (FUSE) has made over 4900 observations of some 2500 individual targets. The data are reduced by the principal investigator team at the Johns Hopkins University and archived at the Multimission Archive at STScI (MAST). The data reduction software package, called CalFUSE, has evolved considerably over the lifetime of the mission. The entire FUSE data set has recently been reprocessed with CalFUSE version 3.2, the latest version of this software. This paper describes CalFUSE version 3.2, the instrument calibrations on which it is based, and the format of the resulting calibrated data files.

Detection of hydrogen fluoride absorption in diffuse molecular clouds with Herschel/HIFI: an ubiquitous tracer of molecular gas

We discuss the detection of absorption by interstellar hydrogen fluoride (HF) along the sight line to the submillimeter continuum sources W49N and W51. We have used Herschels HIFI instrument in dual beam switch mode to observe the 1232.4762 GHz J = 1-0 HF transition in the upper sideband of the band 5a receiver. We detected foreground absorption by HF toward both sources over a wide range of velocities. Optically thin absorption components were detected on both sight lines, allowing us to measure - as opposed to obtain a lower limit on - the column density of HF for the first time. As in previous observations of HF toward the source G10.6-0.4, the derived HF column density is typically comparable to that of water vapor, even though the elemental abundance of oxygen is greater than that of fluorine by four orders of magnitude. We used the rather uncertain N(CH) - N(H-2) relationship derived previously toward diffuse molecular clouds to infer the molecular hydrogen column density in the clouds exhibiting HF absorption. Within the uncertainties, we find that the abundance of HF with respect to H-2 is consistent with the theoretical prediction that HF is the main reservoir of gas-phase fluorine for these clouds. Thus, hydrogen fluoride has the potential to become an excellent tracer of molecular hydrogen, and provides a sensitive probe of clouds of small H-2 column density. Indeed, the observations of hydrogen fluoride reported here reveal the presence of a low column density diffuse molecular cloud along the W51 sight line, at an LSR velocity of similar to 24 km s(-1), that had not been identified in molecular absorption line studies prior to the launch of Herschel.

Interstellar CH absorption in the diffuse interstellar medium along the sight-lines to G10.6-0.4 (W31C), W49N, and W51

We report the detection of the ground state N, J = 1, 3/2 → 1, 1/2 doublet of the methylidyne radical CH at ∼532 GHz and ∼536 GHz with the Herschel/HIFI instrument along the sight-line to the massive star-forming regions G10.6–0.4 (W31C), W49N, and W51. While the molecular cores associated with these massive star-forming regions show emission lines, clouds in the diffuse interstellar medium are detected in absorption against the strong submillimeter background. The combination of hyperfine structure with emission and absorption results in complex profiles, with overlap of the different hyperfine components. The opacities of most of the CH absorption features are linearly correlated with those of CCH, CN, and HCO + in the same velocity intervals. In specific narrow velocity intervals, the opacities of CN and HCO + deviate from the mean trends, giving rise to more opaque absorption features. We propose that CCH can be used as another tracer of the molecular gas in the absence of better tracers, with [CCH]/[H2] ∼3.2 ± 1.1 × 10 −8 . The observed [CN]/[CH], [CCH]/[CH] abundance ratios suggest that the bulk of the diffuse matter along the lines of sight has gas densities nH = n(H) + 2n(H2) ranging between 100 and 1000 cm −3 .