Theodore P. Snow

Overview of the Far Ultraviolet Spectroscopic Explorer Mission

The Far Ultraviolet Spectroscopic Explorer satellite observes light in the far-ultraviolet spectral region, 905-1187 Angstrom, with a high spectral resolution. The instrument consists of four co-aligned prime-focus telescopes and Rowland spectrographs with microchannel plate detectors. Two of the telescope channels use Al :LiF coatings for optimum reflectivity between approximately 1000 and 1187 Angstrom, and the other two channels use SiC coatings for optimized throughput between 905 and 1105 Angstrom. The gratings are holographically ruled to correct largely for astigmatism and to minimize scattered light. The microchannel plate detectors have KBr photocathodes and use photon counting to achieve good quantum efficiency with low background signal. The sensitivity is sufficient to examine reddened lines of sight within the Milky Way and also sufficient to use as active galactic nuclei and QSOs for absorption-line studies of both Milky Way and extragalactic gas clouds. This spectral region contains a number of key scientific diagnostics, including O VI, H I, D I, and the strong electronic transitions of H-2 and HD.

A Far Ultraviolet Spectroscopic Explorer Survey of Interstellar Molecular Hydrogen in Translucent Clouds

We report the first ensemble results from the Far Ultraviolet Spectroscopic Explorer survey of molecular hydrogen in lines of sight with AV e1 mag. We have developed techniques for fitting computed profiles to the low-J lines of H2, and thus determining column densities for J ¼ 0 and J ¼ 1, which contain e99% of the total H2. From these column densities and ancillary data we have derived the total H2 column densities, hydrogen molecular fractions, and kinetic temperatures for 23 lines of sight. This is the first significant sample of molecular hydrogen column densities of � 10 21 cm � 2 , measured through UV absorption bands. We have also compiled a set of extinction data for these lines of sight, which sample a wide range of environments. We have searched for correlations of our H2-related quantities with previously published column densities of other molecules and extinction parameters. We find strong correlations between H2 and molecules such as CH, CN, and CO, in general agreement with predictions of chemical models. We also find the expected correlations between hydrogen molecular fraction and various density indicators such as kinetic temperature, CN

THE COSMIC ORIGINS SPECTROGRAPH

The Cosmic Origins Spectrograph (COS) is a moderate-resolution spectrograph with unprecedented sensitivity that was installed into the Hubble Space Telescope (HST) in 2009 May, during HST Servicing Mission 4 (STS-125). We present the design philosophy and summarize the key characteristics of the instrument that will be of interest to potential observers. For faint targets, with flux F ? 1.0 ? 10?14?erg?cm?2?s?1 ??1, COS can achieve comparable signal to noise (when compared to Space Telescope Imaging Spectrograph echelle modes) in 1%-2% of the observing time. This has led to a significant increase in the total data volume and data quality available to the community. For example, in the first 20 months of science operation (2009 September-2011 June) the cumulative redshift pathlength of extragalactic sight lines sampled by COS is nine times than sampled at moderate resolution in 19 previous years of Hubble observations. COS programs have observed 214 distinct lines of sight suitable for study of the intergalactic medium as of 2011 June. COS has measured, for the first time with high reliability, broad Ly? absorbers and Ne VIII in the intergalactic medium, and observed the He II reionization epoch along multiple sightlines. COS has detected the first CO emission and absorption in the UV spectra of low-mass circumstellar disks at the epoch of giant planet formation, and detected multiple ionization states of metals in extra-solar planetary atmospheres. In the coming years, COS will continue its census of intergalactic gas, probe galactic and cosmic structure, and explore physics in our solar system and Galaxy.

Interstellar Depletions Updated: Where All the Atoms Went

Measures of the depletion of interstellar elements from the gas phase are usually derived by assuming that the general composition of the interstellar medium is identical to that of the Sun. A compilation of stellar composition data, including B stars as well as field F and G stars, however, calls this assumption into question. In this Letter we consider the impact on derived depletions if the reference abundances are derived from stars in the solar neighborhood rather than from the Sun, and we discuss the implications for current models of the interstellar dust. Using recent, accurate gas-phase column densities for ζ Ophiuchi, we show that the systematically lower depletions resulting from our revised cosmic abundances are in conflict with most dust models because insufficient quantities of raw materials are available to explain the observed extinction. A Kramers-Kronig analysis for the ζ Oph line of sight shows that the revised depletions are consistent with the required opacity of interstellar dust only if the density of the grain material is near 1 g cm-3, suggesting that the grain structure must be open (i.e., the grains must by fluffy, porous, or fractal in structure).

A Far Ultraviolet Spectroscopic Explorer Survey of Interstellar Molecular Hydrogen in the Small and Large Magellanic Clouds

We describe a moderate-resolution Far Ultraviolet Spectroscopic Explorer (FUSE) survey of H2 along 70 sight lines to the Small and Large Magellanic Clouds, using hot stars as background sources. FUSE spectra of 67% of observed Magellanic Cloud sources (52% of LMC and 92% of SMC) exhibit absorption lines from the H2 Lyman and Werner bands between 912 and 1120 A. Our survey is sensitive to N(H2) ≥ 1014 cm-2; the highest column densities are log N(H2) = 19.9 in the LMC and 20.6 in the SMC. We find reduced H2 abundances in the Magellanic Clouds relative to the Milky Way, with average molecular fractions = 0.010 for the SMC and = 0.012 for the LMC, compared with = 0.095 for the Galactic disk over a similar range of reddening. The dominant uncertainty in this measurement results from the systematic differences between 21 cm radio emission and Lyα in pencil beam sight lines as measures of N(H I). These results imply that the diffuse H2 masses of the LMC and SMC are 8 × 106 and 2 × 106 M☉, respectively, 2% and 0.5% of the H I masses derived from 21 cm emission measurements. The LMC and SMC abundance patterns can be reproduced in ensembles of model clouds with a reduced H2 formation rate coefficient, R ~ 3 × 10-18 cm3 s-1, and incident radiation fields ranging from 10-100 times the Galactic mean value. We find that these high-radiation, low formation rate models can also explain the enhanced N(4)/N(2) and N(5)/N(3) rotational excitation ratios in the Clouds. We use H2 column densities in low rotational states (J = 0 and 1) to derive kinetic and/or rotational temperatures of diffuse interstellar gas, and we find that the distribution of rotational temperatures is similar to Galactic gas, with T01 = 82 ± 21 K for clouds with N(H2) ≥ 1016.5 cm-2. There is only a weak correlation between detected H2 and far-infrared fluxes as determined by IRAS, perhaps as a result of differences in the survey techniques. We find that the surface density of H2 probed by our pencil beam sight lines is far lower than that predicted from the surface brightness of dust in IRAS maps. We discuss the implications of this work for theories of star formation in low-metallicity environments.

STUDIES OF THE DIFFUSE INTERSTELLAR BANDS. III. HD 183143

Echelle spectra of HD 183143 [B7Iae, E(B − V) = 1.27] were obtained on three nights, at a resolving power R = 38,000 and with a signal-to-noise ratio ≈ 1000 at 6400 A in the final, combined spectrum. A catalog is presented of 414 diffuse interstellar bands (DIBs) measured between 3900 and 8100 A in this spectrum. The central wavelengths, the widths (FWHM), and the equivalent widths of nearly all of the bands are tabulated, along with the minimum uncertainties in the latter. Among the 414 bands, 135 (or 33%) were not reported in four previous, modern surveys of the DIBs in the spectra of various stars, including HD 183143. The principal result of this study is that the great majority of the bands in the catalog are very weak and fairly narrow. Typical equivalent widths amount to a few mA, and the bandwidths (FWHM) are most often near 0.7 A. No preferred wavenumber spacings among the 414 bands are identified which could provide clues to the identities of the large molecules thought to cause the DIBs. At generally comparable detection limits in both spectra, the population of DIBs observed toward HD 183143 is systematically redder, broader, and stronger than that seen toward HD 204827 (Paper II). In addition, interstellar lines of C2 molecules have not been detected toward HD 183143, while a very high value of N(C2)/E(B − V )i s observed toward HD 204827. Therefore, either the abundances of the large molecules presumed to give rise to the DIBs, or the physical conditions in the absorbing clouds, or both, must differ significantly between the two cases.

The interstellar chemistry of PAH cations

Diffuse interstellar bands (DIBs) are mysterious absorption lines in the optical spectra of stars, and have been known for 75 years. Although it is widely believed that they arise from gas-phase organic molecules (rather than from dust grains) in the interstellar medium, no consensus has been reached regarding their precise cause. The realization that many emission features in astronomical infrared spectra probably arise from polycyclic aromatic hydrocarbons (PAHs), which may themselves be very abundant in the interstellar medium, has led to the suggestion that ionized PAHs might be the source of the DIBs. Laboratory investigations have revealed that small, positively charged PAHs in matrices have absorption features that bear some resemblance to DIBs, but no clear identification of any DIB with any specific PAH cation has yet been made. Here we report a laboratory study of the chemical reactivity of PAH cations (C6H6+, C10H8+and C16H10+) in the gas phase. We find that these PAH cations are very reactive, and are therefore unlikely to survive in high abundances in the interstellar medium. Rather, such molecules will react rapidly with hydrogen, and we therefore suggest that the resulting protonated PAH cations (and species derived from them) should become the focus of future searches for a correspondence between molecular absorption features and the DIBs.

The Interstellar Carbon Budget and the Role of Carbon in Dust and Large Molecules

Published data on stellar composition show that carbon in the sun is substantially more abundant than in other stars. A carbon abundance of 225 carbon atoms per 106 hydrogen atoms is representative of galactic stars, whereas published values for the sun range from 350 to 470 carbon atoms per 106 hydrogen atoms. Other elements are also present in enhanced quantities in the solar system, consistent with suggestions that a supernova event was closely associated with the formation of the solar system. The overabundance of carbon in the solar system has many important implications, including new constraints on nucleosynthesis models for supernovae and substantial modification of the so-called “cosmic” composition normally adopted in discussions of galactic and interstellar abundances. A reduction in the galactic carbon budget, as suggested by the stellar composition data, strongly constrains the quantity of carbon that is available for the formation of interstellar dust, and some dust models now appear implausible because they require more carbon than is available.

STUDIES OF DIFFUSE INTERSTELLAR BANDS V. PAIRWISE CORRELATIONS OF EIGHT STRONG DIBs AND NEUTRAL HYDROGEN, MOLECULAR HYDROGEN, AND COLOR EXCESS

We establish correlations between equivalent widths of eight diffuse interstellar bands (DIBs), and examine their correlations with atomic hydrogen, molecular hydrogen, and E B?V . The DIBs are centered at ?? 5780.5, 6204.5, 6283.8, 6196.0, 6613.6, 5705.1, 5797.1, and 5487.7, in decreasing order of Pearsons correlation coefficient with N(H) (here defined as the column density of neutral hydrogen), ranging from 0.96 to 0.82. We find the equivalent width (EW) of ?5780.5 is better correlated with column densities of H than with E B?V or H2, confirming earlier results based on smaller data sets. We show that the same is true for six of the seven other DIBs presented here. Despite this similarity, the eight strong DIBs chosen are not correlated well enough with each other to suggest they come from the same carrier. We further conclude that these eight DIBs are more likely to be associated with H than with H2, and hence are not preferentially located in the densest, most UV shielded parts of interstellar clouds. We suggest that they arise from different molecules found in diffuse H regions with very little H2 (molecular fraction f < 0.01). Of the 133 stars with available data in our study, there are three with significantly weaker ?5780.5 than our mean H-?5780.5 relationship, all of which are in regions of high radiation fields, as previously noted by Herbig. The correlations will be useful in deriving interstellar parameters when direct methods are not available. For instance, with care, the value of N(H) can be derived from W ?(5780.5).

Hydrogenation and Charge States of Polycyclic Aromatic Hydrocarbons in Diffuse Clouds. II. Results

We have modeled the states of hydrogenation and charge of polycyclic aromatic hydrocarbons (PAHs) in diffuse clouds for molecules ranging from benzene up to species containing 200 carbon atoms. It is found that the hydrogenation state of PAHs strongly depends on the size of the molecule. Small PAHs with fewer than about 15-20 carbon atoms are destroyed in most environments. Intermediate-size PAHs in the range of 20-30 carbon atoms are stripped of most of their peripheral hydrogen atoms, but may be able to survive in the interstellar medium because of the relative stability of their carbon skeleton upon UV photon absorption. Larger PAHs primarily have normal hydrogen coverage (i.e., with each peripheral carbon atom bearing a single hydrogen), with competition between this form and PAHs containing an additional hydrogen. Very large PAHs may be fully hydrogenated, with every peripheral carbon atom bearing two hydrogen atoms. Our finding that extremely dehydrogenated PAH neutrals or positively charged CmH, with m ranging from 15 to 30 and n ≤ 2, can survive in the interstellar medium contrasts with previous work, where it was generally assumed that PAHs losing their hydrogen coverage were quickly destroyed. A mechanism is proposed for the selective growth of these small dehydrogenated PAHs in diffuse clouds with respect to larger PAHs. Finally, our results are compared to previous studies on the hydrogenation and charge states of PAHs.