Pauli Kehayias

Cavity-enhanced room-temperature magnetometry using absorption by nitrogen-vacancy centers in diamond.

We demonstrate a cavity-enhanced room-temperature magnetic field sensor based on nitrogen-vacancy centers in diamond. Magnetic resonance is detected using absorption of light resonant with the 1042 nm spin-singlet transition. The diamond is placed in an external optical cavity to enhance the absorption, and significant absorption is observed even at room temperature. We demonstrate a magnetic field sensitivity of 2.5  nT/Hz, and project a photon shot-noise-limited sensitivity of 70  pT/Hz for a few mW of infrared light, and a quantum projection-noise-limited sensitivity of 250  fT/Hz for the sensing volume of ∼90  μm×90  μm×200  μm.

Magnetometry with nitrogen-vacancy ensembles in diamond based on infrared absorption in a doubly resonant optical cavity

We propose using an optical cavity to enhance the sensitivity of a magnetometer relying on the detection of the spin state of a high-density nitrogen-vacancy ensemble in diamond using infrared optical absorption. The role of the cavity is to obtain a contrast in the absorption-detected magnetic resonance approaching unity at room temperature. We project an increase in the photon shot-noise limited sensitivity of two orders of magnitude in comparison with a single-pass approach. Optical losses can limit the enhancement to one order of magnitude, which could still enable room-temperature operation. Finally, the optical cavity also allows us to use less pumping power when the cavity is resonant at both the pump and the infrared probe wavelength.

Optical polarization of nuclear ensembles in diamond

We report polarization of a dense nuclear-spin ensemble in diamond and its dependence on magnetic field and temperature. The polarization method is based on the transfer of electron spin polarization of negatively charged nitrogen vacancy color centers to the nuclear spins via the excited-state level anti-crossing of the center. We polarize 90% of the 14N nuclear spins within the NV centers, and 70% of the proximal 13C nuclear spins with hyperfine interaction strength of 13-14 MHz. Magnetic-field dependence of the polarization reveals sharp decrease in polarization at specific field values corresponding to cross-relaxation with substitutional nitrogen centers, while temperature dependence of the polarization reveals that high polarization persists down to 50 K. This work enables polarization of the 13C in bulk diamond, which is of interest in applications of nuclear magnetic resonance, in quantum memories of hybrid quantum devices, and in sensing.

Detection of nanoscale electron spin resonance spectra demonstrated using nitrogen-vacancy centre probes in diamond

Electron spin resonance (ESR) describes a suite of techniques for characterizing electronic systems with applications in physics, chemistry, and biology. However, the requirement for large electron spin ensembles in conventional ESR techniques limits their spatial resolution. Here we present a method for measuring ESR spectra of nanoscale electronic environments by measuring the longitudinal relaxation time of a single-spin probe as it is systematically tuned into resonance with the target electronic system. As a proof of concept, we extracted the spectral distribution for the P1 electronic spin bath in diamond by using an ensemble of nitrogen-vacancy centres, and demonstrated excellent agreement with theoretical expectations. As the response of each nitrogen-vacancy spin in this experiment is dominated by a single P1 spin at a mean distance of 2.7 nm, the application of this technique to the single nitrogen-vacancy case will enable nanoscale ESR spectroscopy of atomic and molecular spin systems.

Infrared absorption band and vibronic structure of the nitrogen-vacancy center in diamond

Negatively charged nitrogen-vacancy (NV

Micrometer‐scale magnetic imaging of geological samples using a quantum diamond microscope

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Solution nuclear magnetic resonance spectroscopy on a nanostructured diamond chip

) color centers in diamond have generated much interest for use in quantum technology. Despite the progress made in developing their applications, many questions about the basic properties of NV

Coherent population oscillations with nitrogen-vacancy color centers in diamond

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Secondary magnetic inclusions in detrital zircons from the Jack Hills, Western Australia, and implications for the origin of the geodynamo

centers remain unresolved. Understanding these properties can validate theoretical models of NV

Diamond-Based Magnetic Imaging with Fourier Optical Processing

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