Peter D. Warwick

Coupled hydrology and biogeochemistry of Paleocene–Eocene coal beds, northern Gulf of Mexico

Thirty-six formation waters, gas, and microbial samples were collected and analyzed from natural gas and oil wells producing from the Paleocene to Eocene Wilcox Group coal beds and adjacent sandstones in north-central Louisiana, USA, to investigate the role hydrology plays on the generation and distribution of microbial methane. Major ion chemistry and Cl−Br relations of Wilcox Group formation waters suggest mixing of freshwater with halite-derived brines. High alkalinities (up to 47.8 meq/L), no detectable SO4, and elevated δ13C values of dissolved inorganic carbon (up to 20.5‰ Vienna Peedee belemnite [VPDB]) and CO2 (up to 17.67‰ VPDB) in the Wilcox Group coals and adjacent sandstones indicate the dominance of microbial methanogenesis. The δ13C and δD values of CH4, and carbon isotope fractionation of CO2 and CH4, suggest CO2 reduction is the major methanogenic pathway. Geochemical indicators for methanogenesis drop off significantly at chloride concentrations above ∼1.7 mol/L, suggesting that high salinities inhibit microbial activity at depths greater than ∼1.6 km. Formation waters in the Wilcox Group contain up to 1.6% modern carbon (A14C) to at least 1690 m depth; the covariance of δD values of co-produced H2O and CH4 indicate that the microbial methane was generated in situ with these Late Pleistocene or younger waters. The most enriched carbon isotope values for dissolved inorganic carbon (DIC) and CO2, and highest alkalinities, were detected in Wilcox Group sandstone reservoirs that were CO2 flooded in the 1980s for enhanced oil recovery, leading to the intriguing hypothesis that CO2 sequestration may actually enhance methanogenesis in organic-rich formations.

Depositional models for two Tertiary coal-bearing sequences in the Powder River Basin, Wyoming, USA

Depositional controls on peat-forming environments which produce thick (>10m) coal beds can be inferred from relationships between coal bed geometry, maceral composition and associated lithologies. Study of these relationships within sedimentary sequences associated with the Wyodak-Anderson (Palaeocene) and the Felix (Eocene) sub-bituminous coal beds in the Powder River Basin, Wyoming, USA suggests two modes of fluvially controlled peat accumulation. The Wyodak-Anderson peat is interpreted to have formed in restricted parts of the floodplain that were separated by deposits of contemporaneous, anastomosed channels. The channels and associated sediments maintained their position through time because they were confined by thick deposits of raised Wyodak-Anderson peat. In contrast, the Felix coal bed is interpreted to have formed as a raised but widespread peat on an abandoned platform of meander-belt sands. The purpose of this paper is to compare and contrast two different fluvial depositional settings that produced anomalously thick (>10m) coal deposits in the intermontane Powder River Basin of Wyoming, USA. These models may be useful as predictive tools for coal exploration and production.

Petrographic characteristics of the Wyodak-Anderson coal bed (Paleocene), Powder River Basin, Wyoming, U.S.A.

Abstract Six lithofacies of the thick ( > 30 m) Wyodak-Anderson subbituminous coal bed of the Fort Union Formation (Paleocene), Powder River Basin, Wyoming, can be delimited using megascopic and petrographic data. Previous lithofacies analysis of the rock types associated with the Wyodak-Anderson bed suggested that raised peat accumulated in restricted parts of an inland flood plain. The peat bodies were separated by deposits of contemporaneous, possibly anastomosed channels. In this study, megascopic descriptions from four mine highwalls of the Wyodak-Anderson coal bed were found to be similar to facies defined by microscopic data from core and highwall samples. The data indicate that the upper and lower parts of the coal bed are rich in preserved wood remains (for instance, humotelinite), whereas the middle part of the bed contains comparatively larger amounts of material that resulted from degradation and comminution of the peat (e.g. eugelinite). The facies are interpreted to be the result of different chemical and biological environments at the time of peat formation.

The US Geological Survey's national coal resource assessment: The results

Abstract The US Geological Survey and the State geological surveys of many coal-bearing States recently completed a new assessment of the top producing coal beds and coal zones in five major producing coal regions—the Appalachian Basin, Gulf Coast, Illinois Basin, Colorado Plateau, and Northern Rocky Mountains and Great Plains. The assessments, which focused on both coal quality and quantity, utilized geographic information system technology and large databases. Over 1,600,000 million short tons of coal remain in over 60 coal beds and coal zones that were assessed. Given current economic, environmental, and technological restrictions, the majority of US coal production will occur in that portion of the assessed coal resource that is lowest in sulfur content. These resources are concentrated in parts of the central Appalachian Basin, Colorado Plateau, and the Northern Rocky Mountains.

Collision-induced tectonism along the northwestern margin of the Indian subcontinent as recorded in the Upper Paleocene to Middle Eocene strata of central Pakistan (Kirthar and Sulaiman Ranges)

Abstract Outcrop data from the Upper Paleocene to Middle Eocene Ghazij Formation of central Pakistan provide information about the depositional environments, source areas, and paleogeographic and tectonic settings along the northwestern margin of the Indian subcontinent during the closing of the Tethys Ocean. In this region, in the lower part of the exposed stratigraphic sequence, are various marine carbonate-shelf deposits (Jurassic to Upper Paleocene). Overlying these strata is the Ghazij, which consists of marine mudstone (lower part), paralic sandstone and mudstone (middle part), and terrestrial mudstone and conglomerate (upper part). Petrographic examination of sandstone samples from the middle and upper parts reveals that rock fragments of the underlying carbonate-shelf deposits are dominant; also present are volcanic rock fragments and chromite grains. Paleocurrent measurements from the middle and upper parts suggest that source areas were located northwest of the study area. We postulate that the source areas were uplifted by the collision of the subcontinent with a landmass during the final stages of the closing of the Tethys Ocean. Middle Eocene carbonate-shelf deposits that overlie the Ghazij record a return to marine conditions prior to the Miocene to Pleistocene sediment influx denoting the main collision with Eurasia.

Petrography and geochemistry of selected lignite beds in the Gibbons Creek mine (Manning Formation, Jackson Group, Paleocene) of east-central Texas

This study examined the petrographic and geochemical characteristics of two lignite beds (3500 and 4500 beds, Manning Formation, Jackson Group, Eocene) that are mined at the Gibbons Creek mine in east-central Texas. The purpose of the study was to identify the relations among sample ash yield, coal petrography, and trace-element concentrations in lignite and adjoining rock layers of the Gibbons Creek mine. Particular interest was given to the distribution of 12 environmentally sensitive trace elements (As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, and U) that have been identified as potentially hazardous air pollutants (HAPs) in the United States Clean Air Act Amendments of 1990. Eleven lignite, floor, and rock parting samples were collected from incremental channel samples of the 3500 and 4500 beds that were exposed in a highwall of pit A3 at the Gibbons Creek mine. Short proximate and ultimate and forms of sulfur analyses were performed on all lignite samples, and lignite and rock samples were analyzed for 60 major, minor and trace elements. Representative splits of all lignite samples were ground and cast into pellets, and polished for petrographic analyses in blue-light fluorescence and reflected white light to determine liptinite, inertinite, and huminite maceral group percentages. The following observations summarize our results and conclusions about the geochemistry, petrography, and sedimentology of the 3500 and 4500 beds of the Gibbons Creek lignite deposit: (1) Weighted average dry (db) ash yield for the two beds is 29.7%, average total sulfur content is 2.6%, and average calorific value is 7832 Btu (18.22 MJ/kg). Ash yields are greatest in the lower bench (59.33% db) of the 3500 bed and in the upper bench of the 4500 bed (74.61% db). (2) For lignite samples (on a whole-coal basis), the distributions of two of the HAPs (Pb and Sb) are positively related to ash yield, probably indicating an inorganic affinity for these elements. By using cluster analysis we found that Be and Cd were poorly associated with ash yield, indicating a possible organic affinity, and that Ni, Se, Hg, U, and Pb cluster with most of the rare-earth elements. (3) The dominance of the crypto-eugelinite maceral subgroup over the crypto-humotelinite subgroup suggests that all Gibbons Creek lignites were subjected to peat-forming conditions (either biogenic or chemical) conducive to the degradation of wood cellular material into matrix gels, or that original plant material was not very woody and was prone to formation of matrix gels. The latter idea is supported by pollen studies of Gibbons Creek lignite beds; results indicate that the peat was derived in part from marsh plants low in wood tissue. (4) The occurrence of siliceous sponge spicules in the lower benches of the 3500 bed suggests the original peat in this part of the bed was deposited in standing, fresh water. (5) The petrographic data indicate that the upper sample interval of the 3500 bed contains more inertinite (3%) than the other samples studied. Increases in inertinite content in the upper part of the 3500 bed may have been associated with alteration of the peat by acids derived from the volcanic ash or could have been caused by fire, oxidation and drying, or biologic alteration of the peat in the paleo-mire.

The origin and distribution of HAPs elements in relation to maceral composition of the A1 lignite bed (Paleocene, Calvert Bluff Formation, Wilcox Group), Calvert mine area, east-central Texas

Abstract The origin and distribution of twelve potentially Hazardous Air Pollutants (HAPs; As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, and U) identified in the 1990 Clean Air Act Amendments were examined in relation to the maceral composition of the A1 bed (Paleocene, Calvert Bluff Formation, Wilcox Group) of the Calvert mine in east-central Texas. The 3.2 m-thick A1 bed was divided into nine incremental channel samples (7 lignite samples and 2 shaley coal samples) on the basis of megascopic characteristics. Results indicate that As, Cd, Cr, Ni, Pb, Sb, and U are strongly correlated with ash yield and are enriched in the shaley coal samples. We infer that these elements are associated with inorganic constituents in the coal bed and may be derived from a penecontemporaneous stream channel located several kilometers southeast of the mining block. Of the HAPs elements studied, Mn and Hg are the most poorly correlated to ash yield. We infer an organic association for Mn; Hg may be associated with pyrite. The rest of the trace elements (Be, Co, and Se) are weakly correlated with ash yield. Further analytical work is necessary to determine the mode of occurrence for these elements. Overall, concentrations of the HAPs elements are generally similar to or less than those reported in previous studies of lignites of the Wilcox Group, east-central region, Texas. Petrographic analysis indicates the following ranges in composition for the seven lignite samples: liptinites (5–8%), huminites (88–95%), and inertinites (trace amounts to 7%). Samples from the middle portion of the A1 bed contain abundant crypto-eugelinite compared to the rest of the samples; this relationship suggests that the degradation of plant material was an important process during the development of the peat mire. With the exception of Hg and Mn, relatively low levels of the HAPs elements studied are found in the samples containing abundant crypto-eugelinite. We infer that the peat-forming environment for this portion of the coal bed was very wet with minimal detrital input. Relatively high concentrations of crypto-humotelinite were found in samples from the top and base of the coal bed. The presence of abundant crypto-humotefinite in this part of the coal bed suggests the accumulation of wood-rich peat under conditions conducive to a high degree of tissue preservation in the peat mire. Although several of the trace elements (Be, Co, Ni, and Sb) exhibit enrichment in these samples, they are not necessarily chemically associated with humotelinite. We infer that these elements, with the exception of Be, are possibly associated with deposition of the roof and floor rock of the coal bed; however, further analytical work would be necessary to confirm this hypothesis. Beryllium may have an organic origin.

Environmental Drivers of Differences in Microbial Community Structure in Crude Oil Reservoirs across a Methanogenic Gradient

Stimulating in situ microbial communities in oil reservoirs to produce natural gas is a potentially viable strategy for recovering additional fossil fuel resources following traditional recovery operations. Little is known about what geochemical parameters drive microbial population dynamics in biodegraded, methanogenic oil reservoirs. We investigated if microbial community structure was significantly impacted by the extent of crude oil biodegradation, extent of biogenic methane production, and formation water chemistry. Twenty-two oil production wells from north central Louisiana, USA, were sampled for analysis of microbial community structure and fluid geochemistry. Archaea were the dominant microbial community in the majority of the wells sampled. Methanogens, including hydrogenotrophic and methylotrophic organisms, were numerically dominant in every well, accounting for, on average, over 98% of the total Archaea present. The dominant Bacteria groups were Pseudomonas, Acinetobacter, Enterobacteriaceae, and Clostridiales, which have also been identified in other microbially-altered oil reservoirs. Comparing microbial community structure to fluid (gas, water, and oil) geochemistry revealed that the relative extent of biodegradation, salinity, and spatial location were the major drivers of microbial diversity. Archaeal relative abundance was independent of the extent of methanogenesis, but closely correlated to the extent of crude oil biodegradation; therefore, microbial community structure is likely not a good sole predictor of methanogenic activity, but may predict the extent of crude oil biodegradation. However, when the shallow, highly biodegraded, low salinity wells were excluded from the statistical analysis, no environmental parameters could explain the differences in microbial community structure. This suggests that the microbial community structure of the 5 shallow, up-dip wells was different than the 17 deeper, down-dip wells. Also, the 17 down-dip wells had statistically similar microbial communities despite significant changes in environmental parameters between oil fields. Together, this implies that no single microbial population is a reliable indicator of a reservoirs ability to degrade crude oil to methane, and that geochemistry may be a more important indicator for selecting a reservoir suitable for microbial enhancement of natural gas generation.

Petrography, geochemistry, and depositional setting of the San Pedro and Santo Tomas coal zones : anomalous algae-rich coals in the middle part of the Claiborne Group (Eocene) of Webb County, Texas

Two coal zones, the San Pedro and the overlying Santo Tomas, are present for nearly 35 km in outcrop, surface and underground mines, and shallow drill holes along the strike of the middle part of the Claiborne Group (Eocene) in Webb County, Texas. A sandstone-dominated interval of 25 to 35 m separates the two coal zones, which range up to 3 m in thickness. Each coal zone contains carbonaceous shales, thin (<0.75 m) impure coal beds, and thin (<0.85 m) but commercially significant nonbanded coal beds. The nonbanded coals are different from other Tertiary coals of the Gulf of Mexico Coastal Plain: unlike lignites that are typical of the older Wilcox Group (Paleocene-Eocene) and younger Jackson Group (Eocene), nonbanded coals of the Claiborne Group have high vitrinite-reflectance values (0.53 Rmax) and high calorific yields (average 6670 kcal/kg or 12,000 Btu, dry basis). The coals are weakly agglomerating (free-swelling index is 1.5–2.0) and have an apparent rank of high-volatile bituminous. The coal-bearing portion of the middle Claiborne Group in the Rio Grande area represents a fining-upward transition from sandstone-dominated, marine-influenced, lower delta plain depositional environments to more inland, mudstone-rich, predominantly freshwater deltaic settings. Discontinuities within the San Pedro coal zone are attributed mainly to the influence of contemporaneous deposition of distributary mouth-bar sand bodies. The less variable nature of the Santo Tomas coal zone reflects its origin in the upper part of an interlobe basin that received only minor clastic influx. Petrographic attributes of the nonbanded coals indicate that they formed subaqueously in fresh to possibly brackish waters. A highly degraded groundmass composed of eugelinite is the main petrographic component (approximately 71%, mineral-matter-free basis). An enriched liptinite fraction (approximately 23%) probably accounts for unusually high calorific values. There is negligible inertinite. Petrographic study of polished blocks indicates that approximately 10 percent of the nonbanded coal from both coal zones is composed of green algae fructifications, which also occur in clastic rocks of the coal-bearing interval. Such algal material cannot be identified or quantified by conventional coal petrographic techniques that utilize particle pellets or by palynological analyses that include acid preparation.

New insights into the nation's carbon storage potential

Carbon sequestration is a method of securing carbon dioxide (CO2) to prevent its release into the atmosphere, where it contributes to global warming as a greenhouse gas. Geologic storage of CO2 in porous and permeable rocks involves injecting high-pressure CO2 into a subsurface rock unit that has available pore space. Biologic carbon sequestration refers to both natural and anthropogenic processes by which CO2 is removed from the atmosphere and stored as carbon in vegetation, soils, and sediments.