Philip S. H. Chen

Germanium ALD/CVD Precursors for Deposition of Ge/GeTe Films

In order to deposit conformal films in the high aspect ratio trench and via structures in future high-density phase-change memory devices, suitable ALD/CVD precursors are needed. We report on the development of novel germanium(II) metal-organic ALD/CVD precursors containing amide, cyclopentadienyl, and amidinate ligands. The physical properties, volatility, and thermal behavior of the precursors were evaluated by simultaneous thermal analysis (STA) and vapor pressure measurements. Stability studies were conducted to investigate the suitability of the precursors for use as ALD/CVD precursors for device manufacturing.

Selective co growth on Cu for void-free via fill

We report for the first time a highly selective CVD Co deposition on Cu to fill a 45nm diameter 3:1 aspect ratio via in a Cu dual damascene structure. We have achieved void-free Co fill of the via, demonstrating that a selective bottom-up via fill with Co is a potentially viable approach. Defect formation and control in the process and device integration are discussed. This selective process provides an opportunity to reduce via resistance and shrink the minimum metal 1 (M1) area for aggressive standard cell size scaling as needed for 7nm technology.