Philippe Jacquod

Scanning tunnelling microscopy and spectroscopy of ultra-flat graphene on hexagonal boron nitride

Graphene has demonstrated great promise for future electronics technology as well as fundamental physics applications because of its linear energy-momentum dispersion relations which cross at the Dirac point. However, accessing the physics of the low-density region at the Dirac point has been difficult because of disorder that leaves the graphene with local microscopic electron and hole puddles. Efforts have been made to reduce the disorder by suspending graphene, leading to fabrication challenges and delicate devices which make local spectroscopic measurements difficult. Recently, it has been shown that placing graphene on hexagonal boron nitride (hBN) yields improved device performance. Here we use scanning tunnelling microscopy to show that graphene conforms to hBN, as evidenced by the presence of Moiré patterns. However, contrary to predictions, this conformation does not lead to a sizeable band gap because of the misalignment of the lattices. Moreover, local spectroscopy measurements demonstrate that the electron-hole charge fluctuations are reduced by two orders of magnitude as compared with those on silicon oxide. This leads to charge fluctuations that are as small as in suspended graphene, opening up Dirac point physics to more diverse experiments.Graphene has demonstrated great promise for future electronics technology as well as fundamental physics applications because of its linear energy-momentum dispersion relations which cross at the Dirac point[1, 2]. However, accessing the physics of the low density region at the Dirac point has been difficult because of the presence of disorder which leaves the graphene with local microscopic electron and hole puddles[3–5], resulting in a finite density of carriers even at the charge neutrality point. Efforts have been made to reduce the disorder by suspending graphene, leading to fabrication challenges and delicate devices which make local spectroscopic measurements difficult[6, 7]. Recently, it has been shown that placing graphene on hexagonal boron nitride (hBN) yields improved device performance[8]. In this letter, we use scanning tunneling microscopy to show that graphene conforms to hBN, as evidenced by the presence of Moiré patterns in the topographic images. However, contrary to recent predictions[9, 10], this conformation does not lead to a sizable band gap due to the misalignment of the lattices. Moreover, local spectroscopy measurements demonstrate that the electron-hole charge fluctuations are reduced by two orders of magnitude as compared to those on silicon oxide. This leads to charge fluctuations which are as small as in suspended graphene[6], opening up Dirac point physics to more diverse experiments than are possible on freestanding devices. ∗Electronic address: leroy@physics.arizona.edu

Emergence of superlattice Dirac points in graphene on hexagonal boron nitride

It is well known that graphene deposited on hexagonal boron nitride produces moire patterns in scanning tunnelling microscopy images. The interaction that produces this pattern also produces a commensurate periodic potential that generates a set of Dirac points that are different from those of the graphene lattice itself.

Chapter 2 - Modes of wave-chaotic dielectric resonators

Dielectric optical micro-resonators and micro-lasers represent a realization of a wave-chaotic system, where the lack of symmetry in the resonator shape leads to non-integrable ray dynamics. Modes of such resonators display a rich spatial structure, and cannot be classified through mode indices which would require additional constants of motion in the ray dynamics. Understanding and controlling the emission properties of such resonators requires the investigation of the correspondence between classical phase space structures of the ray motion inside the resonator and resonant solutions of the wave equations. We first discuss the breakdown of the conventional eikonal approximation in the short wavelength limit, and motivate the use of phase-space ray tracing and phase space distributions. Next, we introduce an efficient numerical method to calculate the quasi-bound modes of dielectric resonators, which requires only two diagonalizations per N states, where N is approximately equal to the number of half-wavelengths along the perimeter. The relationship between classical phase space structures and modes is displayed via the Husimi projection technique. Observables related to the emission pattern of the resonator are calculated with high efficiency.

Electric field control of soliton motion and stacking in trilayer graphene

The crystal structure of a material plays an important role in determining its electronic properties. Changing from one crystal structure to another involves a phase transition that is usually controlled by a state variable such as temperature or pressure. In the case of trilayer graphene, there are two common stacking configurations (Bernal and rhombohedral) that exhibit very different electronic properties. In graphene flakes with both stacking configurations, the region between them consists of a localized strain soliton where the carbon atoms of one graphene layer shift by the carbon-carbon bond distance. Here we show the ability to move this strain soliton with a perpendicular electric field and hence control the stacking configuration of trilayer graphene with only an external voltage. Moreover, we find that the free-energy difference between the two stacking configurations scales quadratically with electric field, and thus rhombohedral stacking is favoured as the electric field increases. This ability to control the stacking order in graphene opens the way to new devices that combine structural and electrical properties.

Scattering theory of nonlinear thermoelectricity in quantum coherent conductors

We construct a scattering theory of weakly nonlinear thermoelectric transport through sub-micron scale conductors. The theory incorporates the leading nonlinear contributions in temperature and voltage biases to the charge and heat currents. Because of the finite capacitances of sub-micron scale conducting circuits, fundamental conservation laws such as gauge invariance and current conservation require special care to be preserved. We do this by extending the approach of Christen and Büttiker (1996 Europhys. Lett. 35 523) to coupled charge and heat transport. In this way we write relations connecting nonlinear transport coefficients in a manner similar to Motts relation between the linear thermopower and the linear conductance. We derive sum rules that nonlinear transport coefficients must satisfy to preserve gauge invariance and current conservation. We illustrate our theory by calculating the efficiency of heat engines and the coefficient of performance of thermoelectric refrigerators based on quantum point contacts and resonant tunneling barriers. We identify, in particular, rectification effects that increase device performance.

Suppression of interactions in multimode random lasers in the Anderson localized regime

Random lasing in the presence of nonlinearities and disordered gain media is still poorly understood. Researchers now present a semiclassical theory for multimode random lasing in the strongly scattering regime. They show that Anderson localization — a wave-interference effect — is not affected by the presence of nonlinearities, but instead suppresses interactions between simultaneously lasing modes.

Onsager relations in coupled electric, thermoelectric, and spin transport: The tenfold way

Hamiltonian systems can be classified into ten classes, in terms of the presence or absence of time-reversal symmetry, particle-hole symmetry and sublattice/chiral symmetry. We construct a quantum coherent scattering theory of linear transport for coupled electric, heat and spin transport; including the effect of Andreev reflection from superconductors. We derive a complete list of the Onsager reciprocity relations between transport coefficients for coupled electric, spin, thermoelectric and spin caloritronic effects. We apply these to all ten symmetry classes, paying special attention to specific additional relations that follow from the combination of symmetries, beyond microreversibility. We discuss these relations in several illustrative situations. We show the reciprocity between spin-Hall and inverse spin-Hall effects, and the reciprocity between spin-injection and magnetoelectric spin currents. We discuss the symmetry and reciprocity relations of Seebeck, Peltier, spin-Seebeck and spin-Peltier effects in systems with and without coupling to superconductors.

Semiclassical Time Evolution of the Reduced Density Matrix and Dynamically Assisted Generation of Entanglement for Bipartite Quantum Systems

Two particles, initially in a product state, become entangled when they come together and start to interact. Using semiclassical methods, we calculate the time evolution of the corresponding reduced density matrix rho(1), obtained by integrating out the degrees of freedom of one of the particles. We find that entanglement generation sensitively depends (i) on the interaction potential, especially on its strength and range, and (ii) on the nature of the underlying classical dynamics. Under general statistical assumptions, and for short-ranged interaction potentials, we find that P(t) decays exponentially fast in a chaotic environment, whereas it decays only algebraically in a regular system. In the chaotic case, the decay rate is given by the golden rule spreading of one-particle states due to the two-particle coupling, but cannot exceed the systems Lyapunov exponent.

Suppression of ground-state magnetization in finite-size systems due to off-diagonal interaction fluctuations

We study a generic model of interacting fermions in a finite-size disordered system. We show that the off-diagonal interaction matrix elements induce density of state fluctuations which generically favor a minimum spin ground state at large interaction amplitude, U. This effect competes with the exchange effect which favors large magnetization at large U, and it suppresses this exchange magnetization in a large parameter range. When off-diagonal fluctuations dominate, the model predicts a spin gap which is larger for odd-spin ground states as for even spin, suggesting a simple experimental signature of this off-diagonal effect in Coulomb blockade transport measurements.

Shot noise in semiclassical chaotic cavities.

We construct a trajectory-based semiclassical theory of shot noise in clean chaotic cavities. In the universal regime of vanishing Ehrenfest time tau(E), we reproduce the random matrix theory result and show that the Fano factor is exponentially suppressed as tau(E) increases. We demonstrate how our theory preserves the unitarity of the scattering matrix even in the regime of finite tau(E). We discuss the range of validity of our semiclassical approach and point out subtleties relevant to the recent semiclassical treatment of shot noise in the universal regime by Braun et al. (cond-mat/0511292).