Quentin Dubois-Dauphin

Neodymium isotopic composition in foraminifera and authigenic phases of the South China Sea sediments: Implications for the hydrology of the North Pacific Ocean over the past 25 kyr

epsilon Nd and normalized Rare Earth Elements (REE) patterns of benthic and planktonic foraminifera and Fe-Mn coatings precipitated on sediments have been investigated for the South China Sea (SCS) to (1) assess the reliability of the extraction of past seawater epsilon Nd in the SCS and to (2) reconstruct past hydrological changes during the last 25 kyr. Reductively cleaned mono-specific planktonic foraminifera (Globigerinoides ruber) and mixed benthic foraminifera in core-top sediments from 1500 to 2400 m display similar epsilon Nd values to those of the modern Pacific Deep Water (PDW) (epsilon Nd of -3.9 to -4.4). Furthermore, the epsilon Nd of the reductive cleaning solutions shows similar epsilon Nd values to ones obtained on cleaned foraminifera. Combined with PAAS-normalized REE patterns, these results confirm that the oxidative and reductive cleaning procedure applied to foraminifera does not totally remove all of the Fe-Mn coatings and that epsilon Nd values yielded by cleaned planktonic foraminifera retain the epsilon Nd imprint of the bottom and/or pore water. epsilon Nd values obtained from a leaching procedure carried out on the bulk non-decarbonated sediments are comparable to the epsilon Nd values of the modern PDW, whereas a similar leaching procedure applied to decarbonated sediments reveals a bias due to contamination with Nd deriving from lithogenic particles. In core MD052904, seawater epsilon Nd, reconstructed from planktonic foraminifera, indicates that the last glacial period is characterized by lower epsilon Nd (-5.2 +/- 0.2 to -6.4 +/- 0.3) than the late Holocene (-4.1 +/- 0.2). Assuming that Nd input from river does not change strongly the epsilon Nd of the PDW of the northern SCS, these epsilon Nd variations suggest a higher relative proportions of southern-sourced water in the deep water of the western subtropical Pacific Ocean during the last glacial period.

South Atlantic intermediate water advances into the North‐east Atlantic with reduced Atlantic meridional overturning circulation during the last glacial period

The Nd isotopic composition (eNd) of seawater and cold-water coral (CWC) samples from the Gulf of Cadiz and the Alboran Sea, at a depth of 280–827 m were investigated in order to constrain middepth water mass dynamics within the Gulf of Cadiz over the past 40 ka. eNd of glacial and Holocene CWC from the Alboran Sea and the northern Gulf of Cadiz reveals relatively constant values (−8.6 to −9.0 and −9.5 to −10.4, respectively). Such values are similar to those of the surrounding present-day middepth waters from the Mediterranean Outflow Water (MOW; eNd ∼ −9.4) and Mediterranean Sea Water (MSW; eNd ∼ −9.9). In contrast, glacial eNd values for CWC collected at thermocline depth (550–827 m) in the southern Gulf of Cadiz display a higher average value (−8.9 ± 0.4) compared to the present-day value (−11.7 ± 0.3). This implies a higher relative contribution of water masses of Mediterranean (MSW) or South Atlantic origin (East Antarctic Intermediate Water, EAAIW). Our study has produced the first evidence of significant radiogenic eNd values (∼ −8) at 19, 23–24, and 27 ka, which are coeval with increasing iceberg discharges and a weakening of Atlantic Meridional Overturning Circulation (AMOC). Since MOW eNd values remained stable during the last glacial period, it is suggested that these radiogenic eNd values most likely reflect an enhanced northward propagation of glacial EAAIW into the eastern Atlantic Basin.